TY - JOUR
T1 - A metal-organic framework constructed by ferrocene and titanium clusters for CO2photoreduction under visible light
AU - Chen, Xianqi
AU - Li, Yaqiong
AU - Wei, Zihao
AU - Li, Shenghua
AU - Pang, Siping
N1 - Publisher Copyright:
© Published under licence by IOP Publishing Ltd.
PY - 2023
Y1 - 2023
N2 - As a promising photocatalyst, titanium-based metal organic framework (Ti-MOF) has been widely used for the photoreduction of CO2. In this paper, we developed a new Ti-MOF named Fe-Tc, constructed from titanium clusters and ferrocene. Fe-Tc had a wide absorbance range and a good response to visible light. Introducing ferrocene gave it good separation performance of photogenerated electrons and holes. What's more, Fe-Tc showed excellent photocatalytic activity of CO2 photoreduction. Its production rate of formate (HCOO-) reached 39.5 μmol g-1 h-1 under visible light, which was better than some classical Ti-MOFs.
AB - As a promising photocatalyst, titanium-based metal organic framework (Ti-MOF) has been widely used for the photoreduction of CO2. In this paper, we developed a new Ti-MOF named Fe-Tc, constructed from titanium clusters and ferrocene. Fe-Tc had a wide absorbance range and a good response to visible light. Introducing ferrocene gave it good separation performance of photogenerated electrons and holes. What's more, Fe-Tc showed excellent photocatalytic activity of CO2 photoreduction. Its production rate of formate (HCOO-) reached 39.5 μmol g-1 h-1 under visible light, which was better than some classical Ti-MOFs.
UR - http://www.scopus.com/inward/record.url?scp=85173568633&partnerID=8YFLogxK
U2 - 10.1088/1742-6596/2587/1/012100
DO - 10.1088/1742-6596/2587/1/012100
M3 - Conference article
AN - SCOPUS:85173568633
SN - 1742-6588
VL - 2587
JO - Journal of Physics: Conference Series
JF - Journal of Physics: Conference Series
IS - 1
M1 - 012100
T2 - 2023 9th International Conference on Applied Materials and Manufacturing Technology, ICAMMT 2023
Y2 - 24 April 2023 through 26 April 2023
ER -