A metal-organic framework constructed by ferrocene and titanium clusters for CO2photoreduction under visible light

Xianqi Chen; Yaqiong Li; Zihao Wei; Shenghua Li; Siping Pang

doi:10.1088/1742-6596/2587/1/012100

A metal-organic framework constructed by ferrocene and titanium clusters for CO₂photoreduction under visible light

Xianqi Chen, Yaqiong Li, Zihao Wei^*, Shenghua Li^*, Siping Pang^*

^*Corresponding author for this work

School of Material Science and Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Conference article › peer-review

Abstract

As a promising photocatalyst, titanium-based metal organic framework (Ti-MOF) has been widely used for the photoreduction of CO2. In this paper, we developed a new Ti-MOF named Fe-Tc, constructed from titanium clusters and ferrocene. Fe-Tc had a wide absorbance range and a good response to visible light. Introducing ferrocene gave it good separation performance of photogenerated electrons and holes. What's more, Fe-Tc showed excellent photocatalytic activity of CO2 photoreduction. Its production rate of formate (HCOO-) reached 39.5 μmol g-1 h-1 under visible light, which was better than some classical Ti-MOFs.

Original language	English
Article number	012100
Journal	Journal of Physics: Conference Series
Volume	2587
Issue number	1
DOIs	https://doi.org/10.1088/1742-6596/2587/1/012100
Publication status	Published - 2023
Event	2023 9th International Conference on Applied Materials and Manufacturing Technology, ICAMMT 2023 - Hybrid, Qingyuan, China Duration: 24 Apr 2023 → 26 Apr 2023

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10.1088/1742-6596/2587/1/012100

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Chen, X., Li, Y., Wei, Z., Li, S., & Pang, S. (2023). A metal-organic framework constructed by ferrocene and titanium clusters for CO₂photoreduction under visible light. Journal of Physics: Conference Series, 2587(1), Article 012100. https://doi.org/10.1088/1742-6596/2587/1/012100

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title = "A metal-organic framework constructed by ferrocene and titanium clusters for CO2photoreduction under visible light",

abstract = "As a promising photocatalyst, titanium-based metal organic framework (Ti-MOF) has been widely used for the photoreduction of CO2. In this paper, we developed a new Ti-MOF named Fe-Tc, constructed from titanium clusters and ferrocene. Fe-Tc had a wide absorbance range and a good response to visible light. Introducing ferrocene gave it good separation performance of photogenerated electrons and holes. What's more, Fe-Tc showed excellent photocatalytic activity of CO2 photoreduction. Its production rate of formate (HCOO-) reached 39.5 μmol g-1 h-1 under visible light, which was better than some classical Ti-MOFs.",

author = "Xianqi Chen and Yaqiong Li and Zihao Wei and Shenghua Li and Siping Pang",

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AU - Chen, Xianqi

AU - Li, Yaqiong

AU - Wei, Zihao

AU - Li, Shenghua

AU - Pang, Siping

N1 - Publisher Copyright: © Published under licence by IOP Publishing Ltd.

PY - 2023

Y1 - 2023

N2 - As a promising photocatalyst, titanium-based metal organic framework (Ti-MOF) has been widely used for the photoreduction of CO2. In this paper, we developed a new Ti-MOF named Fe-Tc, constructed from titanium clusters and ferrocene. Fe-Tc had a wide absorbance range and a good response to visible light. Introducing ferrocene gave it good separation performance of photogenerated electrons and holes. What's more, Fe-Tc showed excellent photocatalytic activity of CO2 photoreduction. Its production rate of formate (HCOO-) reached 39.5 μmol g-1 h-1 under visible light, which was better than some classical Ti-MOFs.

AB - As a promising photocatalyst, titanium-based metal organic framework (Ti-MOF) has been widely used for the photoreduction of CO2. In this paper, we developed a new Ti-MOF named Fe-Tc, constructed from titanium clusters and ferrocene. Fe-Tc had a wide absorbance range and a good response to visible light. Introducing ferrocene gave it good separation performance of photogenerated electrons and holes. What's more, Fe-Tc showed excellent photocatalytic activity of CO2 photoreduction. Its production rate of formate (HCOO-) reached 39.5 μmol g-1 h-1 under visible light, which was better than some classical Ti-MOFs.

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DO - 10.1088/1742-6596/2587/1/012100

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SN - 1742-6588

VL - 2587

JO - Journal of Physics: Conference Series

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T2 - 2023 9th International Conference on Applied Materials and Manufacturing Technology, ICAMMT 2023

Y2 - 24 April 2023 through 26 April 2023

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A metal-organic framework constructed by ferrocene and titanium clusters for CO₂photoreduction under visible light

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