TY - JOUR
T1 - A germanate compound constructed from dissymmetric Ge 7 chains and metal complexes
AU - Ren, Xiaoyan
AU - Li, Yi
AU - Shao, Lang
AU - Yu, Jihong
AU - Xu, Ruren
PY - 2012/7
Y1 - 2012/7
N2 - A novel germanate compound, |[Ni(dien) 2] 3(H 2O) 3|[Ge 7O 13F 5] 2(designated JU-85, dien = diethylenetriamine), was solvothermally synthesized. The structure of JU-85 was determined by single-crystal X-ray diffraction and further characterized by powder X-ray diffraction, inductively coupled plasma, infrared spectroscopy, elemental analysis, and thermogravimetric analysis. JU-85 has dissymmetric chains constructed from diagonally linked Ge 7 building units and various Ni(dien) 2 2+ complexes formed in situ during the synthesis. Compared with its structural analogue, FJ-6, JU-85 contains less complex cations and different host-guest assembly. Besides the diagonal linkage in JU-85, other dissymmetric linkages of Ge 7 building units were enumerated, which could be used as the stereogenic centers for the design of novel chiral germanate compounds.
AB - A novel germanate compound, |[Ni(dien) 2] 3(H 2O) 3|[Ge 7O 13F 5] 2(designated JU-85, dien = diethylenetriamine), was solvothermally synthesized. The structure of JU-85 was determined by single-crystal X-ray diffraction and further characterized by powder X-ray diffraction, inductively coupled plasma, infrared spectroscopy, elemental analysis, and thermogravimetric analysis. JU-85 has dissymmetric chains constructed from diagonally linked Ge 7 building units and various Ni(dien) 2 2+ complexes formed in situ during the synthesis. Compared with its structural analogue, FJ-6, JU-85 contains less complex cations and different host-guest assembly. Besides the diagonal linkage in JU-85, other dissymmetric linkages of Ge 7 building units were enumerated, which could be used as the stereogenic centers for the design of novel chiral germanate compounds.
KW - Chain structures
KW - Chirality
KW - Germanium
KW - Hydrogen bonds
KW - Metal complexes
UR - http://www.scopus.com/inward/record.url?scp=84863974986&partnerID=8YFLogxK
U2 - 10.1002/zaac.201200136
DO - 10.1002/zaac.201200136
M3 - Article
AN - SCOPUS:84863974986
SN - 0044-2313
VL - 638
SP - 1345
EP - 1350
JO - Zeitschrift fur Anorganische und Allgemeine Chemie
JF - Zeitschrift fur Anorganische und Allgemeine Chemie
IS - 9
ER -
