A germanate compound constructed from dissymmetric Ge 7 chains and metal complexes

Xiaoyan Ren; Yi Li; Lang Shao; Jihong Yu; Ruren Xu

doi:10.1002/zaac.201200136

A germanate compound constructed from dissymmetric Ge ₇ chains and metal complexes

Xiaoyan Ren, Yi Li^*, Lang Shao, Jihong Yu, Ruren Xu

^*Corresponding author for this work

Jilin University

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

A novel germanate compound, |[Ni(dien) ₂] ₃(H ₂O) ₃|[Ge ₇O ₁₃F ₅] ₂(designated JU-85, dien = diethylenetriamine), was solvothermally synthesized. The structure of JU-85 was determined by single-crystal X-ray diffraction and further characterized by powder X-ray diffraction, inductively coupled plasma, infrared spectroscopy, elemental analysis, and thermogravimetric analysis. JU-85 has dissymmetric chains constructed from diagonally linked Ge ₇ building units and various Ni(dien) ₂ ²⁺ complexes formed in situ during the synthesis. Compared with its structural analogue, FJ-6, JU-85 contains less complex cations and different host-guest assembly. Besides the diagonal linkage in JU-85, other dissymmetric linkages of Ge ₇ building units were enumerated, which could be used as the stereogenic centers for the design of novel chiral germanate compounds.

Original language	English
Pages (from-to)	1345-1350
Number of pages	6
Journal	Zeitschrift fur Anorganische und Allgemeine Chemie
Volume	638
Issue number	9
DOIs	https://doi.org/10.1002/zaac.201200136
Publication status	Published - Jul 2012
Externally published	Yes

Keywords

Chain structures
Chirality
Germanium
Hydrogen bonds
Metal complexes

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10.1002/zaac.201200136

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@article{25a55dec98ca484d89f05e23721c5f8f,

title = "A germanate compound constructed from dissymmetric Ge 7 chains and metal complexes",

abstract = "A novel germanate compound, |[Ni(dien) 2] 3(H 2O) 3|[Ge 7O 13F 5] 2(designated JU-85, dien = diethylenetriamine), was solvothermally synthesized. The structure of JU-85 was determined by single-crystal X-ray diffraction and further characterized by powder X-ray diffraction, inductively coupled plasma, infrared spectroscopy, elemental analysis, and thermogravimetric analysis. JU-85 has dissymmetric chains constructed from diagonally linked Ge 7 building units and various Ni(dien) 2 2+ complexes formed in situ during the synthesis. Compared with its structural analogue, FJ-6, JU-85 contains less complex cations and different host-guest assembly. Besides the diagonal linkage in JU-85, other dissymmetric linkages of Ge 7 building units were enumerated, which could be used as the stereogenic centers for the design of novel chiral germanate compounds.",

keywords = "Chain structures, Chirality, Germanium, Hydrogen bonds, Metal complexes",

author = "Xiaoyan Ren and Yi Li and Lang Shao and Jihong Yu and Ruren Xu",

year = "2012",

month = jul,

doi = "10.1002/zaac.201200136",

language = "English",

volume = "638",

pages = "1345--1350",

journal = "Zeitschrift fur Anorganische und Allgemeine Chemie",

issn = "0044-2313",

publisher = "Wiley-VCH Verlag",

number = "9",

}

TY - JOUR

T1 - A germanate compound constructed from dissymmetric Ge 7 chains and metal complexes

AU - Ren, Xiaoyan

AU - Li, Yi

AU - Shao, Lang

AU - Yu, Jihong

AU - Xu, Ruren

PY - 2012/7

Y1 - 2012/7

N2 - A novel germanate compound, |[Ni(dien) 2] 3(H 2O) 3|[Ge 7O 13F 5] 2(designated JU-85, dien = diethylenetriamine), was solvothermally synthesized. The structure of JU-85 was determined by single-crystal X-ray diffraction and further characterized by powder X-ray diffraction, inductively coupled plasma, infrared spectroscopy, elemental analysis, and thermogravimetric analysis. JU-85 has dissymmetric chains constructed from diagonally linked Ge 7 building units and various Ni(dien) 2 2+ complexes formed in situ during the synthesis. Compared with its structural analogue, FJ-6, JU-85 contains less complex cations and different host-guest assembly. Besides the diagonal linkage in JU-85, other dissymmetric linkages of Ge 7 building units were enumerated, which could be used as the stereogenic centers for the design of novel chiral germanate compounds.

AB - A novel germanate compound, |[Ni(dien) 2] 3(H 2O) 3|[Ge 7O 13F 5] 2(designated JU-85, dien = diethylenetriamine), was solvothermally synthesized. The structure of JU-85 was determined by single-crystal X-ray diffraction and further characterized by powder X-ray diffraction, inductively coupled plasma, infrared spectroscopy, elemental analysis, and thermogravimetric analysis. JU-85 has dissymmetric chains constructed from diagonally linked Ge 7 building units and various Ni(dien) 2 2+ complexes formed in situ during the synthesis. Compared with its structural analogue, FJ-6, JU-85 contains less complex cations and different host-guest assembly. Besides the diagonal linkage in JU-85, other dissymmetric linkages of Ge 7 building units were enumerated, which could be used as the stereogenic centers for the design of novel chiral germanate compounds.

KW - Chain structures

KW - Chirality

KW - Germanium

KW - Hydrogen bonds

KW - Metal complexes

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U2 - 10.1002/zaac.201200136

DO - 10.1002/zaac.201200136

M3 - Article

AN - SCOPUS:84863974986

SN - 0044-2313

VL - 638

SP - 1345

EP - 1350

JO - Zeitschrift fur Anorganische und Allgemeine Chemie

JF - Zeitschrift fur Anorganische und Allgemeine Chemie

IS - 9

ER -

A germanate compound constructed from dissymmetric Ge ₇ chains and metal complexes

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Keywords

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