摘要
(Figure Presented) A new zeotype structure with 3D intersecting 10-ring channels is found in [Ni(en)3][Ga2Ge4O 12] (denoted GaGeO-CJ63, en=ethylenediamine). Its framework (see picture) is constructed exclusively by 3-rings, and the framework density is the second lowest among all known zeolite structures. One of the two kinds of cages in GaGeO-CJ63 is chiral and its chirality comes from the Δ and Λ enantiomers of occluded [Ni(en)3]2+.
源语言 | 英语 |
---|---|
页(从-至) | 3003-3005 |
页数 | 3 |
期刊 | Angewandte Chemie - International Edition |
卷 | 50 |
期 | 13 |
DOI | |
出版状态 | 已出版 - 21 3月 2011 |
已对外发布 | 是 |