A gallogermanate zeolite constructed exclusively by three-ring building units

Yide Han; Yi Li; Jihong Yu; Ruren Xu

doi:10.1002/anie.201006500

A gallogermanate zeolite constructed exclusively by three-ring building units

Yide Han^*, Yi Li, Jihong Yu, Ruren Xu

^*Corresponding author for this work

Jilin University

Research output: Contribution to journal › Article › peer-review

52 Citations (Scopus)

Abstract

(Figure Presented) A new zeotype structure with 3D intersecting 10-ring channels is found in [Ni(en)₃][Ga₂Ge₄O ₁₂] (denoted GaGeO-CJ63, en=ethylenediamine). Its framework (see picture) is constructed exclusively by 3-rings, and the framework density is the second lowest among all known zeolite structures. One of the two kinds of cages in GaGeO-CJ63 is chiral and its chirality comes from the Δ and Λ enantiomers of occluded [Ni(en)₃]²⁺.

Original language	English
Pages (from-to)	3003-3005
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	50
Issue number	13
DOIs	https://doi.org/10.1002/anie.201006500
Publication status	Published - 21 Mar 2011
Externally published	Yes

Keywords

Chirality
Gallogermanates
Nickel
Solvothermal synthesis
Zeolite analogues

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10.1002/anie.201006500

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title = "A gallogermanate zeolite constructed exclusively by three-ring building units",

abstract = "(Figure Presented) A new zeotype structure with 3D intersecting 10-ring channels is found in [Ni(en)3][Ga2Ge4O 12] (denoted GaGeO-CJ63, en=ethylenediamine). Its framework (see picture) is constructed exclusively by 3-rings, and the framework density is the second lowest among all known zeolite structures. One of the two kinds of cages in GaGeO-CJ63 is chiral and its chirality comes from the Δ and Λ enantiomers of occluded [Ni(en)3]2+.",

keywords = "Chirality, Gallogermanates, Nickel, Solvothermal synthesis, Zeolite analogues",

author = "Yide Han and Yi Li and Jihong Yu and Ruren Xu",

year = "2011",

month = mar,

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doi = "10.1002/anie.201006500",

language = "English",

volume = "50",

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journal = "Angewandte Chemie - International Edition",

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T1 - A gallogermanate zeolite constructed exclusively by three-ring building units

AU - Han, Yide

AU - Li, Yi

AU - Yu, Jihong

AU - Xu, Ruren

PY - 2011/3/21

Y1 - 2011/3/21

N2 - (Figure Presented) A new zeotype structure with 3D intersecting 10-ring channels is found in [Ni(en)3][Ga2Ge4O 12] (denoted GaGeO-CJ63, en=ethylenediamine). Its framework (see picture) is constructed exclusively by 3-rings, and the framework density is the second lowest among all known zeolite structures. One of the two kinds of cages in GaGeO-CJ63 is chiral and its chirality comes from the Δ and Λ enantiomers of occluded [Ni(en)3]2+.

AB - (Figure Presented) A new zeotype structure with 3D intersecting 10-ring channels is found in [Ni(en)3][Ga2Ge4O 12] (denoted GaGeO-CJ63, en=ethylenediamine). Its framework (see picture) is constructed exclusively by 3-rings, and the framework density is the second lowest among all known zeolite structures. One of the two kinds of cages in GaGeO-CJ63 is chiral and its chirality comes from the Δ and Λ enantiomers of occluded [Ni(en)3]2+.

KW - Chirality

KW - Gallogermanates

KW - Nickel

KW - Solvothermal synthesis

KW - Zeolite analogues

UR - http://www.scopus.com/inward/record.url?scp=79952660177&partnerID=8YFLogxK

U2 - 10.1002/anie.201006500

DO - 10.1002/anie.201006500

M3 - Article

C2 - 21404385

AN - SCOPUS:79952660177

SN - 1433-7851

VL - 50

SP - 3003

EP - 3005

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 13

ER -

A gallogermanate zeolite constructed exclusively by three-ring building units

Abstract

Keywords

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