摘要
In the title compound, (C15H12N3O)[Cr(C15H10N3O)(NCS)3]·CH4O, the CrIII atom is coordinated by two N atoms and one O atom from the tridentate 1-(2-pyridyldiazen-yl)-2-naphthol-ate (PAN) ligand and three N atoms from thio-cyanate ions in a distorted octa-hedral arrangement. Another uncoordinated and protonated PAN mol-ecule and a methanol solvent mol-ecule are present in the asymmetric unit. The crystal packing is stabilized by π-π inter-actions [centroid-centroid separation 3.594 (4) Å] and O - H⋯N and O - H⋯S hydrogen bonds.
源语言 | 英语 |
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页(从-至) | m2406 |
期刊 | Acta Crystallographica Section E: Structure Reports Online |
卷 | 63 |
期 | 9 |
DOI | |
出版状态 | 已出版 - 29 8月 2007 |
指纹
探究 '2-(2-Hydr-oxy-1-naphthyl-diazen-yl)-pyridinium [1-(2-pyridyldiazen-yl)-2- naphtholato-3 N,N′,O]tris-(thio-cyanato-N)chromium(III) methanol solvate' 的科研主题。它们共同构成独一无二的指纹。引用此
Liu, T. F., Lv, H. Y., Zhao, B. T., & Wang, J. G. (2007). 2-(2-Hydr-oxy-1-naphthyl-diazen-yl)-pyridinium [1-(2-pyridyldiazen-yl)-2- naphtholato-3 N,N′,O]tris-(thio-cyanato-N)chromium(III) methanol solvate. Acta Crystallographica Section E: Structure Reports Online, 63(9), m2406. https://doi.org/10.1107/S1600536807040688