2-(2-Hydr-oxy-1-naphthyl-diazen-yl)-pyridinium [1-(2-pyridyldiazen-yl)-2- naphtholato-3 N,N′,O]tris-(thio-cyanato-N)chromium(III) methanol solvate

Tian Fu Liu; Hong Yan Lv; Bang Tun Zhao; Jian Ge Wang

doi:10.1107/S1600536807040688

2-(2-Hydr-oxy-1-naphthyl-diazen-yl)-pyridinium [1-(2-pyridyldiazen-yl)-2- naphtholato-³ N,N′,O]tris-(thio-cyanato-N)chromium(III) methanol solvate

Tian Fu Liu^*, Hong Yan Lv, Bang Tun Zhao, Jian Ge Wang

^*此作品的通讯作者

化学与化工学院

科研成果: 期刊稿件 › 文章 › 同行评审

4 引用（Scopus）

摘要

In the title compound, (C15H12N3O)[Cr(C15H10N3O)(NCS)3]·CH4O, the Cr^III atom is coordinated by two N atoms and one O atom from the tridentate 1-(2-pyridyldiazen-yl)-2-naphthol-ate (PAN) ligand and three N atoms from thio-cyanate ions in a distorted octa-hedral arrangement. Another uncoordinated and protonated PAN mol-ecule and a methanol solvent mol-ecule are present in the asymmetric unit. The crystal packing is stabilized by π-π inter-actions [centroid-centroid separation 3.594 (4) Å] and O - H⋯N and O - H⋯S hydrogen bonds.

源语言	英语
页（从-至）	m2406
期刊	Acta Crystallographica Section E: Structure Reports Online
卷	63
期	9
DOI	https://doi.org/10.1107/S1600536807040688
出版状态	已出版 - 29 8月 2007

访问文件

10.1107/S1600536807040688

其它文件与链接

链接到 Scopus 的出版物

引用此

@article{aa329b80006a4190a9692f01a1fdf4e4,

title = "2-(2-Hydr-oxy-1-naphthyl-diazen-yl)-pyridinium [1-(2-pyridyldiazen-yl)-2- naphtholato-3 N,N′,O]tris-(thio-cyanato-N)chromium(III) methanol solvate",

abstract = "In the title compound, (C15H12N3O)[Cr(C15H10N3O)(NCS)3]·CH4O, the CrIII atom is coordinated by two N atoms and one O atom from the tridentate 1-(2-pyridyldiazen-yl)-2-naphthol-ate (PAN) ligand and three N atoms from thio-cyanate ions in a distorted octa-hedral arrangement. Another uncoordinated and protonated PAN mol-ecule and a methanol solvent mol-ecule are present in the asymmetric unit. The crystal packing is stabilized by π-π inter-actions [centroid-centroid separation 3.594 (4) {\AA}] and O - H⋯N and O - H⋯S hydrogen bonds.",

author = "Liu, {Tian Fu} and Lv, {Hong Yan} and Zhao, {Bang Tun} and Wang, {Jian Ge}",

year = "2007",

month = aug,

day = "29",

doi = "10.1107/S1600536807040688",

language = "English",

volume = "63",

pages = "m2406",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "9",

}

TY - JOUR

T1 - 2-(2-Hydr-oxy-1-naphthyl-diazen-yl)-pyridinium [1-(2-pyridyldiazen-yl)-2- naphtholato-3 N,N′,O]tris-(thio-cyanato-N)chromium(III) methanol solvate

AU - Liu, Tian Fu

AU - Lv, Hong Yan

AU - Zhao, Bang Tun

AU - Wang, Jian Ge

PY - 2007/8/29

Y1 - 2007/8/29

N2 - In the title compound, (C15H12N3O)[Cr(C15H10N3O)(NCS)3]·CH4O, the CrIII atom is coordinated by two N atoms and one O atom from the tridentate 1-(2-pyridyldiazen-yl)-2-naphthol-ate (PAN) ligand and three N atoms from thio-cyanate ions in a distorted octa-hedral arrangement. Another uncoordinated and protonated PAN mol-ecule and a methanol solvent mol-ecule are present in the asymmetric unit. The crystal packing is stabilized by π-π inter-actions [centroid-centroid separation 3.594 (4) Å] and O - H⋯N and O - H⋯S hydrogen bonds.

AB - In the title compound, (C15H12N3O)[Cr(C15H10N3O)(NCS)3]·CH4O, the CrIII atom is coordinated by two N atoms and one O atom from the tridentate 1-(2-pyridyldiazen-yl)-2-naphthol-ate (PAN) ligand and three N atoms from thio-cyanate ions in a distorted octa-hedral arrangement. Another uncoordinated and protonated PAN mol-ecule and a methanol solvent mol-ecule are present in the asymmetric unit. The crystal packing is stabilized by π-π inter-actions [centroid-centroid separation 3.594 (4) Å] and O - H⋯N and O - H⋯S hydrogen bonds.

UR - http://www.scopus.com/inward/record.url?scp=34548417526&partnerID=8YFLogxK

U2 - 10.1107/S1600536807040688

DO - 10.1107/S1600536807040688

M3 - Article

AN - SCOPUS:34548417526

SN - 1600-5368

VL - 63

SP - m2406

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 9

ER -

2-(2-Hydr-oxy-1-naphthyl-diazen-yl)-pyridinium [1-(2-pyridyldiazen-yl)-2- naphtholato-3 N,N′,O]tris-(thio-cyanato-N)chromium(III) methanol solvate

摘要

访问文件

其它文件与链接

指纹

引用此

2-(2-Hydr-oxy-1-naphthyl-diazen-yl)-pyridinium [1-(2-pyridyldiazen-yl)-2- naphtholato-³ N,N′,O]tris-(thio-cyanato-N)chromium(III) methanol solvate