1-Trinitromethyl-3,5-dinitro-4-nitroaminopyrazole: Intramolecular Full Nitration and Strong Intermolecular H-Bonds toward Highly Dense Energetic Materials

Ning Ding; Qi Sun; Xudong Xu; Wenjin Zhang; Chaofeng Zhao; Shenghua Li; Siping Pang

doi:10.1021/acs.joc.4c00590

1-Trinitromethyl-3,5-dinitro-4-nitroaminopyrazole: Intramolecular Full Nitration and Strong Intermolecular H-Bonds toward Highly Dense Energetic Materials

Ning Ding, Qi Sun^*, Xudong Xu, Wenjin Zhang, Chaofeng Zhao, Shenghua Li^*, Siping Pang^*

^*此作品的通讯作者

材料学院

Beijing Institute of Technology

科研成果: 期刊稿件 › 文章 › 同行评审

6 引用（Scopus）

摘要

Full nitration is one of the most effective strategies used in synthesizing high-density energetic materials, but this strategy has reached its limit because the resultant compounds cannot be further functionalized. To overcome this limitation, we present the synergistic action of full nitration and strong intermolecular H-bonding in designing and synthesizing 1-trinitromethyl-3,5-dinitro-4-nitroaminopyrazole (DNTP) with a density that exceeds those of the reported monocyclic CHON compounds. The detonation velocity and specific impulse of DNTP exceed those of 1-trinitromethyl-3,4,5-trinitropyrazole (TTP), HMX, and ADN.

源语言	英语
页（从-至）	10467-10471
页数	5
期刊	Journal of Organic Chemistry
卷	89
期	15
DOI	https://doi.org/10.1021/acs.joc.4c00590
出版状态	已出版 - 2 8月 2024

访问文件

10.1021/acs.joc.4c00590

其它文件与链接

链接到 Scopus 的出版物

引用此

Ding, N., Sun, Q., Xu, X., Zhang, W., Zhao, C., Li, S., & Pang, S. (2024). 1-Trinitromethyl-3,5-dinitro-4-nitroaminopyrazole: Intramolecular Full Nitration and Strong Intermolecular H-Bonds toward Highly Dense Energetic Materials. Journal of Organic Chemistry, 89(15), 10467-10471. https://doi.org/10.1021/acs.joc.4c00590

@article{04b8f0e519514e458b9b63719f7d8bb9,

title = "1-Trinitromethyl-3,5-dinitro-4-nitroaminopyrazole: Intramolecular Full Nitration and Strong Intermolecular H-Bonds toward Highly Dense Energetic Materials",

abstract = "Full nitration is one of the most effective strategies used in synthesizing high-density energetic materials, but this strategy has reached its limit because the resultant compounds cannot be further functionalized. To overcome this limitation, we present the synergistic action of full nitration and strong intermolecular H-bonding in designing and synthesizing 1-trinitromethyl-3,5-dinitro-4-nitroaminopyrazole (DNTP) with a density that exceeds those of the reported monocyclic CHON compounds. The detonation velocity and specific impulse of DNTP exceed those of 1-trinitromethyl-3,4,5-trinitropyrazole (TTP), HMX, and ADN.",

author = "Ning Ding and Qi Sun and Xudong Xu and Wenjin Zhang and Chaofeng Zhao and Shenghua Li and Siping Pang",

note = "Publisher Copyright: {\textcopyright} 2024 American Chemical Society.",

year = "2024",

month = aug,

day = "2",

doi = "10.1021/acs.joc.4c00590",

language = "English",

volume = "89",

pages = "10467--10471",

journal = "Journal of Organic Chemistry",

issn = "0022-3263",

publisher = "American Chemical Society",

number = "15",

}

TY - JOUR

T1 - 1-Trinitromethyl-3,5-dinitro-4-nitroaminopyrazole

T2 - Intramolecular Full Nitration and Strong Intermolecular H-Bonds toward Highly Dense Energetic Materials

AU - Ding, Ning

AU - Sun, Qi

AU - Xu, Xudong

AU - Zhang, Wenjin

AU - Zhao, Chaofeng

AU - Li, Shenghua

AU - Pang, Siping

PY - 2024/8/2

Y1 - 2024/8/2

N2 - Full nitration is one of the most effective strategies used in synthesizing high-density energetic materials, but this strategy has reached its limit because the resultant compounds cannot be further functionalized. To overcome this limitation, we present the synergistic action of full nitration and strong intermolecular H-bonding in designing and synthesizing 1-trinitromethyl-3,5-dinitro-4-nitroaminopyrazole (DNTP) with a density that exceeds those of the reported monocyclic CHON compounds. The detonation velocity and specific impulse of DNTP exceed those of 1-trinitromethyl-3,4,5-trinitropyrazole (TTP), HMX, and ADN.

AB - Full nitration is one of the most effective strategies used in synthesizing high-density energetic materials, but this strategy has reached its limit because the resultant compounds cannot be further functionalized. To overcome this limitation, we present the synergistic action of full nitration and strong intermolecular H-bonding in designing and synthesizing 1-trinitromethyl-3,5-dinitro-4-nitroaminopyrazole (DNTP) with a density that exceeds those of the reported monocyclic CHON compounds. The detonation velocity and specific impulse of DNTP exceed those of 1-trinitromethyl-3,4,5-trinitropyrazole (TTP), HMX, and ADN.

UR - http://www.scopus.com/inward/record.url?scp=85199037714&partnerID=8YFLogxK

U2 - 10.1021/acs.joc.4c00590

DO - 10.1021/acs.joc.4c00590

M3 - Article

AN - SCOPUS:85199037714

SN - 0022-3263

VL - 89

SP - 10467

EP - 10471

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 15

ER -

1-Trinitromethyl-3,5-dinitro-4-nitroaminopyrazole: Intramolecular Full Nitration and Strong Intermolecular H-Bonds toward Highly Dense Energetic Materials

摘要

访问文件

其它文件与链接

指纹

引用此