TY - JOUR
T1 - 1-Trinitromethyl-3,5-dinitro-4-nitroaminopyrazole
T2 - Intramolecular Full Nitration and Strong Intermolecular H-Bonds toward Highly Dense Energetic Materials
AU - Ding, Ning
AU - Sun, Qi
AU - Xu, Xudong
AU - Zhang, Wenjin
AU - Zhao, Chaofeng
AU - Li, Shenghua
AU - Pang, Siping
N1 - Publisher Copyright:
© 2024 American Chemical Society.
PY - 2024/8/2
Y1 - 2024/8/2
N2 - Full nitration is one of the most effective strategies used in synthesizing high-density energetic materials, but this strategy has reached its limit because the resultant compounds cannot be further functionalized. To overcome this limitation, we present the synergistic action of full nitration and strong intermolecular H-bonding in designing and synthesizing 1-trinitromethyl-3,5-dinitro-4-nitroaminopyrazole (DNTP) with a density that exceeds those of the reported monocyclic CHON compounds. The detonation velocity and specific impulse of DNTP exceed those of 1-trinitromethyl-3,4,5-trinitropyrazole (TTP), HMX, and ADN.
AB - Full nitration is one of the most effective strategies used in synthesizing high-density energetic materials, but this strategy has reached its limit because the resultant compounds cannot be further functionalized. To overcome this limitation, we present the synergistic action of full nitration and strong intermolecular H-bonding in designing and synthesizing 1-trinitromethyl-3,5-dinitro-4-nitroaminopyrazole (DNTP) with a density that exceeds those of the reported monocyclic CHON compounds. The detonation velocity and specific impulse of DNTP exceed those of 1-trinitromethyl-3,4,5-trinitropyrazole (TTP), HMX, and ADN.
UR - http://www.scopus.com/inward/record.url?scp=85199037714&partnerID=8YFLogxK
U2 - 10.1021/acs.joc.4c00590
DO - 10.1021/acs.joc.4c00590
M3 - Article
AN - SCOPUS:85199037714
SN - 0022-3263
VL - 89
SP - 10467
EP - 10471
JO - Journal of Organic Chemistry
JF - Journal of Organic Chemistry
IS - 15
ER -