Li, Y., Zhu, X., Wei, C., Fang, Y., Wang, X., Zhai, Y., Kang, W., Chen, L., Cao, D., Wang, M., Lu, Y., Huang, Q., Su, Y., Yuan, H., Li, N., & Wu, F. (2024). Unraveling the chemical and structural evolution of novel Li-rich layered/rocksalt intergrown cathode for Li-ion batteries. Chinese Chemical Letters, 35(12), Article 109536. https://doi.org/10.1016/j.cclet.2024.109536
Li, Yongjian ; Zhu, Xinyu ; Wei, Chenxi et al. / Unraveling the chemical and structural evolution of novel Li-rich layered/rocksalt intergrown cathode for Li-ion batteries. In: Chinese Chemical Letters. 2024 ; Vol. 35, No. 12.
@article{dd900695196b4535ba230866c41dbd53,
title = "Unraveling the chemical and structural evolution of novel Li-rich layered/rocksalt intergrown cathode for Li-ion batteries",
abstract = "The prototype material, Li1.23Ru0.41Ni0.36O2, is proposed to gain the deep and comprehensive understanding of chemical and structural changes of the novel layered/rocksalt intergrown cathodes. Synchrotron-based X-ray absorption spectra and resonant inelastic X-ray scattering reveal that both cationic and anionic redox evolves in the charge compensation process of the intergrown material, while synchrotron-based extended X-ray fine structure spectra and in situ X-ray diffraction measurements demonstrates that the intergrown material undergoes minimal local- and long-range structural variations at deep de/lithiation. This work highlights the great potential of the intergrown structure to inspire the design of advanced cathode materials for lithium-ion batteries.",
keywords = "Cathode materials, Cationic-anionic redox, Intergrown structure, Low strain, Synchrotron characterizations",
author = "Yongjian Li and Xinyu Zhu and Chenxi Wei and Youyou Fang and Xinyu Wang and Yizhi Zhai and Wenlong Kang and Lai Chen and Duanyun Cao and Meng Wang and Yun Lu and Qing Huang and Yuefeng Su and Hong Yuan and Ning Li and Feng Wu",
note = "Publisher Copyright: {\textcopyright} 2024",
year = "2024",
month = dec,
doi = "10.1016/j.cclet.2024.109536",
language = "English",
volume = "35",
journal = "Chinese Chemical Letters",
issn = "1001-8417",
publisher = "Elsevier B.V.",
number = "12",
}
Li, Y, Zhu, X, Wei, C, Fang, Y, Wang, X, Zhai, Y, Kang, W, Chen, L, Cao, D, Wang, M, Lu, Y, Huang, Q, Su, Y, Yuan, H, Li, N & Wu, F 2024, 'Unraveling the chemical and structural evolution of novel Li-rich layered/rocksalt intergrown cathode for Li-ion batteries', Chinese Chemical Letters, vol. 35, no. 12, 109536. https://doi.org/10.1016/j.cclet.2024.109536
Unraveling the chemical and structural evolution of novel Li-rich layered/rocksalt intergrown cathode for Li-ion batteries. / Li, Yongjian; Zhu, Xinyu; Wei, Chenxi et al.
In:
Chinese Chemical Letters, Vol. 35, No. 12, 109536, 12.2024.
Research output: Contribution to journal › Article › peer-review
TY - JOUR
T1 - Unraveling the chemical and structural evolution of novel Li-rich layered/rocksalt intergrown cathode for Li-ion batteries
AU - Li, Yongjian
AU - Zhu, Xinyu
AU - Wei, Chenxi
AU - Fang, Youyou
AU - Wang, Xinyu
AU - Zhai, Yizhi
AU - Kang, Wenlong
AU - Chen, Lai
AU - Cao, Duanyun
AU - Wang, Meng
AU - Lu, Yun
AU - Huang, Qing
AU - Su, Yuefeng
AU - Yuan, Hong
AU - Li, Ning
AU - Wu, Feng
N1 - Publisher Copyright:
© 2024
PY - 2024/12
Y1 - 2024/12
N2 - The prototype material, Li1.23Ru0.41Ni0.36O2, is proposed to gain the deep and comprehensive understanding of chemical and structural changes of the novel layered/rocksalt intergrown cathodes. Synchrotron-based X-ray absorption spectra and resonant inelastic X-ray scattering reveal that both cationic and anionic redox evolves in the charge compensation process of the intergrown material, while synchrotron-based extended X-ray fine structure spectra and in situ X-ray diffraction measurements demonstrates that the intergrown material undergoes minimal local- and long-range structural variations at deep de/lithiation. This work highlights the great potential of the intergrown structure to inspire the design of advanced cathode materials for lithium-ion batteries.
AB - The prototype material, Li1.23Ru0.41Ni0.36O2, is proposed to gain the deep and comprehensive understanding of chemical and structural changes of the novel layered/rocksalt intergrown cathodes. Synchrotron-based X-ray absorption spectra and resonant inelastic X-ray scattering reveal that both cationic and anionic redox evolves in the charge compensation process of the intergrown material, while synchrotron-based extended X-ray fine structure spectra and in situ X-ray diffraction measurements demonstrates that the intergrown material undergoes minimal local- and long-range structural variations at deep de/lithiation. This work highlights the great potential of the intergrown structure to inspire the design of advanced cathode materials for lithium-ion batteries.
KW - Cathode materials
KW - Cationic-anionic redox
KW - Intergrown structure
KW - Low strain
KW - Synchrotron characterizations
UR - http://www.scopus.com/inward/record.url?scp=85203388118&partnerID=8YFLogxK
U2 - 10.1016/j.cclet.2024.109536
DO - 10.1016/j.cclet.2024.109536
M3 - Article
AN - SCOPUS:85203388118
SN - 1001-8417
VL - 35
JO - Chinese Chemical Letters
JF - Chinese Chemical Letters
IS - 12
M1 - 109536
ER -
Li Y, Zhu X, Wei C, Fang Y, Wang X, Zhai Y et al. Unraveling the chemical and structural evolution of novel Li-rich layered/rocksalt intergrown cathode for Li-ion batteries. Chinese Chemical Letters. 2024 Dec;35(12):109536. doi: 10.1016/j.cclet.2024.109536
