The synthesis, structure and characterization of V2O6 · H3NCH2CH2NH3

Jia Ning Xu; Guo Yu Yang; De Jun Wang; Wen Ying Ma; Hao Ran Sun; Ji Qing Xu; Xiao Ying Huang

The synthesis, structure and characterization of V₂O₆ · H₃NCH₂CH₂NH₃

Jia Ning Xu, Guo Yu Yang, De Jun Wang, Wen Ying Ma, Hao Ran Sun, Ji Qing Xu, Xiao Ying Huang

Research output: Contribution to journal › Article › peer-review

Abstract

A metavanadate in coffee colour, V₂O₆ · H₃NCH₂CH₂NH₃, was synthesized by hydrothermal method and its crystal structure was determined by single crystal X-ray diffraction. Crystal data: monoclinic, space group P2₁/c, a = 0.552 9(2) nm, b=1.290 0(7) nm, c=0. 568 3(2) nm, β=97. 57(3)°, V=0.401 8(3) nm³, F(000)=260, D_c=2.15 g · cm^-3, Z=2, R=0.041, R_w= 0.052. The structure is based on VO₄ tetrahedra sharing two vertex to form a single type of chain running along the c axis. The hydrogen bond (O⋯ H - N) between (VO₃^-)_∞ chains and H₃NCH₂CH₂NH₃²⁺ was formed. IR spectrum confirmed that the ethylenediamine is protonated. The analysis of DRS and SPS are given.

Original language	English
Pages (from-to)	x5-1021
Journal	Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities
Volume	17
Issue number	7
Publication status	Published - 1996
Externally published	Yes

Keywords

Metavanadate
Structure
VO tetrahedra

Cite this

Xu, J. N., Yang, G. Y., Wang, D. J., Ma, W. Y., Sun, H. R., Xu, J. Q., & Huang, X. Y. (1996). The synthesis, structure and characterization of V₂O₆ · H₃NCH₂CH₂NH₃. Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities, 17(7), x5-1021.

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title = "The synthesis, structure and characterization of V2O6 · H3NCH2CH2NH3",

abstract = "A metavanadate in coffee colour, V2O6 · H3NCH2CH2NH3, was synthesized by hydrothermal method and its crystal structure was determined by single crystal X-ray diffraction. Crystal data: monoclinic, space group P21/c, a = 0.552 9(2) nm, b=1.290 0(7) nm, c=0. 568 3(2) nm, β=97. 57(3)°, V=0.401 8(3) nm3, F(000)=260, Dc=2.15 g · cm-3, Z=2, R=0.041, Rw= 0.052. The structure is based on VO4 tetrahedra sharing two vertex to form a single type of chain running along the c axis. The hydrogen bond (O⋯ H - N) between (VO3-)∞ chains and H3NCH2CH2NH32+ was formed. IR spectrum confirmed that the ethylenediamine is protonated. The analysis of DRS and SPS are given.",

keywords = "Metavanadate, Structure, VO tetrahedra",

author = "Xu, {Jia Ning} and Yang, {Guo Yu} and Wang, {De Jun} and Ma, {Wen Ying} and Sun, {Hao Ran} and Xu, {Ji Qing} and Huang, {Xiao Ying}",

year = "1996",

language = "English",

volume = "17",

pages = "x5--1021",

journal = "Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities",

issn = "0251-0790",

publisher = "Higher Education Press Limited Company",

number = "7",

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TY - JOUR

T1 - The synthesis, structure and characterization of V2O6 · H3NCH2CH2NH3

AU - Xu, Jia Ning

AU - Yang, Guo Yu

AU - Wang, De Jun

AU - Ma, Wen Ying

AU - Sun, Hao Ran

AU - Xu, Ji Qing

AU - Huang, Xiao Ying

PY - 1996

Y1 - 1996

N2 - A metavanadate in coffee colour, V2O6 · H3NCH2CH2NH3, was synthesized by hydrothermal method and its crystal structure was determined by single crystal X-ray diffraction. Crystal data: monoclinic, space group P21/c, a = 0.552 9(2) nm, b=1.290 0(7) nm, c=0. 568 3(2) nm, β=97. 57(3)°, V=0.401 8(3) nm3, F(000)=260, Dc=2.15 g · cm-3, Z=2, R=0.041, Rw= 0.052. The structure is based on VO4 tetrahedra sharing two vertex to form a single type of chain running along the c axis. The hydrogen bond (O⋯ H - N) between (VO3-)∞ chains and H3NCH2CH2NH32+ was formed. IR spectrum confirmed that the ethylenediamine is protonated. The analysis of DRS and SPS are given.

AB - A metavanadate in coffee colour, V2O6 · H3NCH2CH2NH3, was synthesized by hydrothermal method and its crystal structure was determined by single crystal X-ray diffraction. Crystal data: monoclinic, space group P21/c, a = 0.552 9(2) nm, b=1.290 0(7) nm, c=0. 568 3(2) nm, β=97. 57(3)°, V=0.401 8(3) nm3, F(000)=260, Dc=2.15 g · cm-3, Z=2, R=0.041, Rw= 0.052. The structure is based on VO4 tetrahedra sharing two vertex to form a single type of chain running along the c axis. The hydrogen bond (O⋯ H - N) between (VO3-)∞ chains and H3NCH2CH2NH32+ was formed. IR spectrum confirmed that the ethylenediamine is protonated. The analysis of DRS and SPS are given.

KW - Metavanadate

KW - Structure

KW - VO tetrahedra

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M3 - Article

AN - SCOPUS:2842584624

SN - 0251-0790

VL - 17

SP - x5-1021

JO - Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities

JF - Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities

IS - 7

ER -

The synthesis, structure and characterization of V₂O₆ · H₃NCH₂CH₂NH₃

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