The primary decomposition product of TKX-50 under adiabatic condition and its thermal decomposition

Junfeng Wang; Shusen Chen; Shaohua Jin; Rui Shi; Zhenfei Yu; Qiang Su; Xiao Ma; Chunyuan Zhang; Qinghai Shu

doi:10.1007/s10973-018-7820-8

The primary decomposition product of TKX-50 under adiabatic condition and its thermal decomposition

Junfeng Wang, Shusen Chen, Shaohua Jin, Rui Shi, Zhenfei Yu, Qiang Su, Xiao Ma, Chunyuan Zhang, Qinghai Shu^*

^*Corresponding author for this work

School of Material Science and Engineering

Research output: Contribution to journal › Article › peer-review

26 Citations (Scopus)

Abstract

The primary decomposition product (TKX-50-M) of dihydroxylammonium 5,5′-bistetrazole-1,1′-diolate (TKX-50) was obtained under adiabatic condition by using accelerating rate calorimeter (ARC). Meanwhile, diammonium 5,5′-bistetrazole-1,1′-diolate (ABTOX) was confirmed as the main component of TKX-50-M. Specific heat capacity of TKX-50-M and ABTOX was studied from 0 to 45 °C. In addition, the thermal decomposition of TKX-50-M and ABTOX was studied under adiabatic condition. The experiment results revealed that TKX-50-M were more thermal sensitive than ABTOX. Furthermore, ABTOX exhibited much violent than that of TKX-50-M during decomposition.

Original language	English
Pages (from-to)	2049-2055
Number of pages	7
Journal	Journal of Thermal Analysis and Calorimetry
Volume	134
Issue number	3
DOIs	https://doi.org/10.1007/s10973-018-7820-8
Publication status	Published - 1 Dec 2018

Keywords

Accelerating rate calorimeter (ARC)
Diammonium 5,5′-bistetrazole-1,1′-diolate (ABTOX)
Dihydroxylammonium 5,5′-bistetrazole-1,1′-diolate (TKX-50)
Thermal decomposition

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10.1007/s10973-018-7820-8

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title = "The primary decomposition product of TKX-50 under adiabatic condition and its thermal decomposition",

abstract = "The primary decomposition product (TKX-50-M) of dihydroxylammonium 5,5′-bistetrazole-1,1′-diolate (TKX-50) was obtained under adiabatic condition by using accelerating rate calorimeter (ARC). Meanwhile, diammonium 5,5′-bistetrazole-1,1′-diolate (ABTOX) was confirmed as the main component of TKX-50-M. Specific heat capacity of TKX-50-M and ABTOX was studied from 0 to 45 °C. In addition, the thermal decomposition of TKX-50-M and ABTOX was studied under adiabatic condition. The experiment results revealed that TKX-50-M were more thermal sensitive than ABTOX. Furthermore, ABTOX exhibited much violent than that of TKX-50-M during decomposition.",

keywords = "Accelerating rate calorimeter (ARC), Diammonium 5,5′-bistetrazole-1,1′-diolate (ABTOX), Dihydroxylammonium 5,5′-bistetrazole-1,1′-diolate (TKX-50), Thermal decomposition",

author = "Junfeng Wang and Shusen Chen and Shaohua Jin and Rui Shi and Zhenfei Yu and Qiang Su and Xiao Ma and Chunyuan Zhang and Qinghai Shu",

note = "Publisher Copyright: {\textcopyright} 2018, Akad{\'e}miai Kiad{\'o}, Budapest, Hungary.",

year = "2018",

month = dec,

day = "1",

doi = "10.1007/s10973-018-7820-8",

language = "English",

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journal = "Journal of Thermal Analysis and Calorimetry",

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TY - JOUR

T1 - The primary decomposition product of TKX-50 under adiabatic condition and its thermal decomposition

AU - Wang, Junfeng

AU - Chen, Shusen

AU - Jin, Shaohua

AU - Shi, Rui

AU - Yu, Zhenfei

AU - Su, Qiang

AU - Ma, Xiao

AU - Zhang, Chunyuan

AU - Shu, Qinghai

PY - 2018/12/1

Y1 - 2018/12/1

N2 - The primary decomposition product (TKX-50-M) of dihydroxylammonium 5,5′-bistetrazole-1,1′-diolate (TKX-50) was obtained under adiabatic condition by using accelerating rate calorimeter (ARC). Meanwhile, diammonium 5,5′-bistetrazole-1,1′-diolate (ABTOX) was confirmed as the main component of TKX-50-M. Specific heat capacity of TKX-50-M and ABTOX was studied from 0 to 45 °C. In addition, the thermal decomposition of TKX-50-M and ABTOX was studied under adiabatic condition. The experiment results revealed that TKX-50-M were more thermal sensitive than ABTOX. Furthermore, ABTOX exhibited much violent than that of TKX-50-M during decomposition.

AB - The primary decomposition product (TKX-50-M) of dihydroxylammonium 5,5′-bistetrazole-1,1′-diolate (TKX-50) was obtained under adiabatic condition by using accelerating rate calorimeter (ARC). Meanwhile, diammonium 5,5′-bistetrazole-1,1′-diolate (ABTOX) was confirmed as the main component of TKX-50-M. Specific heat capacity of TKX-50-M and ABTOX was studied from 0 to 45 °C. In addition, the thermal decomposition of TKX-50-M and ABTOX was studied under adiabatic condition. The experiment results revealed that TKX-50-M were more thermal sensitive than ABTOX. Furthermore, ABTOX exhibited much violent than that of TKX-50-M during decomposition.

KW - Accelerating rate calorimeter (ARC)

KW - Diammonium 5,5′-bistetrazole-1,1′-diolate (ABTOX)

KW - Dihydroxylammonium 5,5′-bistetrazole-1,1′-diolate (TKX-50)

KW - Thermal decomposition

UR - http://www.scopus.com/inward/record.url?scp=85055705573&partnerID=8YFLogxK

U2 - 10.1007/s10973-018-7820-8

DO - 10.1007/s10973-018-7820-8

M3 - Article

AN - SCOPUS:85055705573

SN - 1388-6150

VL - 134

SP - 2049

EP - 2055

JO - Journal of Thermal Analysis and Calorimetry

JF - Journal of Thermal Analysis and Calorimetry

IS - 3

ER -

The primary decomposition product of TKX-50 under adiabatic condition and its thermal decomposition

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Keywords

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