The new dual anion solvent-free nickel complex based on the pyridine-4-carbohydrazide ligand

Bao Long Kuang; Bin Shan Zhao; Zu Jia Lu; Ting Wei Wang; Zhi Ming Xie; Mou Sun; Qi Yao Yu; Jian Guo Zhang

doi:10.1039/d4nj02087a

The new dual anion solvent-free nickel complex based on the pyridine-4-carbohydrazide ligand

Bao Long Kuang, Bin Shan Zhao, Zu Jia Lu, Ting Wei Wang, Zhi Ming Xie, Mou Sun, Qi Yao Yu^*, Jian Guo Zhang^*

^*Corresponding author for this work

School of Mechatronical Engineering

Research output: Contribution to journal › Article › peer-review

Abstract

Based on the ideas of coordination and design chemistry, we propose a new strategy to balance the energy and sensitivity conflict by synthesizing dual anion structures in the realm of energetic complex compounds. Therefore, a novel solvent-free complex, [Ni(4-PDCA)₂(NO₃)₂](ClO₄)₂ (ECCs-1), which has a six-coordinated octahedral structure and contains dual anions, was synthesized. The structure was identified by IR, EA and single-crystal XRD. To the best of our knowledge, it is the first reported dual anion structure that exhibits excellent insensitivity with acceptable thermal stability and detonation performance.

Original language	English
Pages (from-to)	12873-12876
Number of pages	4
Journal	New Journal of Chemistry
Volume	48
Issue number	29
DOIs	https://doi.org/10.1039/d4nj02087a
Publication status	Published - 24 Jun 2024

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title = "The new dual anion solvent-free nickel complex based on the pyridine-4-carbohydrazide ligand",

abstract = "Based on the ideas of coordination and design chemistry, we propose a new strategy to balance the energy and sensitivity conflict by synthesizing dual anion structures in the realm of energetic complex compounds. Therefore, a novel solvent-free complex, [Ni(4-PDCA)2(NO3)2](ClO4)2 (ECCs-1), which has a six-coordinated octahedral structure and contains dual anions, was synthesized. The structure was identified by IR, EA and single-crystal XRD. To the best of our knowledge, it is the first reported dual anion structure that exhibits excellent insensitivity with acceptable thermal stability and detonation performance.",

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T1 - The new dual anion solvent-free nickel complex based on the pyridine-4-carbohydrazide ligand

AU - Kuang, Bao Long

AU - Zhao, Bin Shan

AU - Lu, Zu Jia

AU - Wang, Ting Wei

AU - Xie, Zhi Ming

AU - Sun, Mou

AU - Yu, Qi Yao

AU - Zhang, Jian Guo

PY - 2024/6/24

Y1 - 2024/6/24

N2 - Based on the ideas of coordination and design chemistry, we propose a new strategy to balance the energy and sensitivity conflict by synthesizing dual anion structures in the realm of energetic complex compounds. Therefore, a novel solvent-free complex, [Ni(4-PDCA)2(NO3)2](ClO4)2 (ECCs-1), which has a six-coordinated octahedral structure and contains dual anions, was synthesized. The structure was identified by IR, EA and single-crystal XRD. To the best of our knowledge, it is the first reported dual anion structure that exhibits excellent insensitivity with acceptable thermal stability and detonation performance.

AB - Based on the ideas of coordination and design chemistry, we propose a new strategy to balance the energy and sensitivity conflict by synthesizing dual anion structures in the realm of energetic complex compounds. Therefore, a novel solvent-free complex, [Ni(4-PDCA)2(NO3)2](ClO4)2 (ECCs-1), which has a six-coordinated octahedral structure and contains dual anions, was synthesized. The structure was identified by IR, EA and single-crystal XRD. To the best of our knowledge, it is the first reported dual anion structure that exhibits excellent insensitivity with acceptable thermal stability and detonation performance.

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DO - 10.1039/d4nj02087a

M3 - Article

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SN - 1144-0546

VL - 48

SP - 12873

EP - 12876

JO - New Journal of Chemistry

JF - New Journal of Chemistry

IS - 29

ER -

The new dual anion solvent-free nickel complex based on the pyridine-4-carbohydrazide ligand

Abstract

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