Synthesis, structures, luminescence/magnetic properties of complexes of the M/1-hydroxybenzotriazole, M = cobalt, nickel, silver, zinc and copper

Zhong Qiang Zhang, Ru Dan Huang*, Lan Jun Dong, Yan Qing Xu, Li Qiong Yu, Zhi Wei Jiao, Chang Wen Hu

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

16 Citations (Scopus)

Abstract

Five novel complexes, Co(OBt)2 · 7H2O (1) (OBt = 1-hydroxybenzotriazole ion), Ni3(OBt)6 · 6H2O (2), [Ag(OBt)(HOBt)]n (3), [Zn(OBt)2]n (4) and [Cu2(OBt)4 · 3H2O]n (5) were synthesized by hydrothermal method and characterized by elemental analysis, IR spectroscopy, TGA, XRPD, and single-crystal X-ray diffraction. The results from single-crystal X-ray diffraction indicate that 1-5 are zero-dimensional (0D), zero-dimensional, one-dimensional (1D), and three-dimensional (3D) frameworks, respectively. In particular, 3 is twin crystal; 4 possesses of double-stranded chains; 5 crystallizes in orthorhombic space group P212121 with a helical chain in its structure. The luminescence properties and the magnetic properties of the five complexes were investigated.

Original languageEnglish
Pages (from-to)3056-3064
Number of pages9
JournalInorganica Chimica Acta
Volume362
Issue number9
DOIs
Publication statusPublished - 1 Jul 2009

Keywords

  • Chemical synthesis
  • Crystal structure
  • Fluorescence
  • Magnetic properties
  • N,O ligand

Fingerprint

Dive into the research topics of 'Synthesis, structures, luminescence/magnetic properties of complexes of the M/1-hydroxybenzotriazole, M = cobalt, nickel, silver, zinc and copper'. Together they form a unique fingerprint.

Cite this

Zhang, Z. Q., Huang, R. D., Dong, L. J., Xu, Y. Q., Yu, L. Q., Jiao, Z. W., & Hu, C. W. (2009). Synthesis, structures, luminescence/magnetic properties of complexes of the M/1-hydroxybenzotriazole, M = cobalt, nickel, silver, zinc and copper. Inorganica Chimica Acta, 362(9), 3056-3064. https://doi.org/10.1016/j.ica.2009.01.044