Synthesis, structures, luminescence/magnetic properties of complexes of the M/1-hydroxybenzotriazole, M = cobalt, nickel, silver, zinc and copper

Zhong Qiang Zhang; Ru Dan Huang; Lan Jun Dong; Yan Qing Xu; Li Qiong Yu; Zhi Wei Jiao; Chang Wen Hu

doi:10.1016/j.ica.2009.01.044

Synthesis, structures, luminescence/magnetic properties of complexes of the M/1-hydroxybenzotriazole, M = cobalt, nickel, silver, zinc and copper

Zhong Qiang Zhang, Ru Dan Huang^*, Lan Jun Dong, Yan Qing Xu, Li Qiong Yu, Zhi Wei Jiao, Chang Wen Hu

^*此作品的通讯作者

化学与化工学院

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16 引用（Scopus）

摘要

Five novel complexes, Co(OBt)₂ · 7H₂O (1) (OBt = 1-hydroxybenzotriazole ion), Ni₃(OBt)₆ · 6H₂O (2), [Ag(OBt)(HOBt)]_n (3), [Zn(OBt)₂]_n (4) and [Cu₂(OBt)₄ · 3H₂O]_n (5) were synthesized by hydrothermal method and characterized by elemental analysis, IR spectroscopy, TGA, XRPD, and single-crystal X-ray diffraction. The results from single-crystal X-ray diffraction indicate that 1-5 are zero-dimensional (0D), zero-dimensional, one-dimensional (1D), and three-dimensional (3D) frameworks, respectively. In particular, 3 is twin crystal; 4 possesses of double-stranded chains; 5 crystallizes in orthorhombic space group P2₁2₁2₁ with a helical chain in its structure. The luminescence properties and the magnetic properties of the five complexes were investigated.

源语言	英语
页（从-至）	3056-3064
页数	9
期刊	Inorganica Chimica Acta
卷	362
期	9
DOI	https://doi.org/10.1016/j.ica.2009.01.044
出版状态	已出版 - 1 7月 2009

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@article{2358c10d04b04fe3b04e1cfb3b1738b5,

title = "Synthesis, structures, luminescence/magnetic properties of complexes of the M/1-hydroxybenzotriazole, M = cobalt, nickel, silver, zinc and copper",

abstract = "Five novel complexes, Co(OBt)2 · 7H2O (1) (OBt = 1-hydroxybenzotriazole ion), Ni3(OBt)6 · 6H2O (2), [Ag(OBt)(HOBt)]n (3), [Zn(OBt)2]n (4) and [Cu2(OBt)4 · 3H2O]n (5) were synthesized by hydrothermal method and characterized by elemental analysis, IR spectroscopy, TGA, XRPD, and single-crystal X-ray diffraction. The results from single-crystal X-ray diffraction indicate that 1-5 are zero-dimensional (0D), zero-dimensional, one-dimensional (1D), and three-dimensional (3D) frameworks, respectively. In particular, 3 is twin crystal; 4 possesses of double-stranded chains; 5 crystallizes in orthorhombic space group P212121 with a helical chain in its structure. The luminescence properties and the magnetic properties of the five complexes were investigated.",

keywords = "Chemical synthesis, Crystal structure, Fluorescence, Magnetic properties, N,O ligand",

author = "Zhang, {Zhong Qiang} and Huang, {Ru Dan} and Dong, {Lan Jun} and Xu, {Yan Qing} and Yu, {Li Qiong} and Jiao, {Zhi Wei} and Hu, {Chang Wen}",

year = "2009",

month = jul,

day = "1",

doi = "10.1016/j.ica.2009.01.044",

language = "English",

volume = "362",

pages = "3056--3064",

journal = "Inorganica Chimica Acta",

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TY - JOUR

T1 - Synthesis, structures, luminescence/magnetic properties of complexes of the M/1-hydroxybenzotriazole, M = cobalt, nickel, silver, zinc and copper

AU - Zhang, Zhong Qiang

AU - Huang, Ru Dan

AU - Dong, Lan Jun

AU - Xu, Yan Qing

AU - Yu, Li Qiong

AU - Jiao, Zhi Wei

AU - Hu, Chang Wen

PY - 2009/7/1

Y1 - 2009/7/1

N2 - Five novel complexes, Co(OBt)2 · 7H2O (1) (OBt = 1-hydroxybenzotriazole ion), Ni3(OBt)6 · 6H2O (2), [Ag(OBt)(HOBt)]n (3), [Zn(OBt)2]n (4) and [Cu2(OBt)4 · 3H2O]n (5) were synthesized by hydrothermal method and characterized by elemental analysis, IR spectroscopy, TGA, XRPD, and single-crystal X-ray diffraction. The results from single-crystal X-ray diffraction indicate that 1-5 are zero-dimensional (0D), zero-dimensional, one-dimensional (1D), and three-dimensional (3D) frameworks, respectively. In particular, 3 is twin crystal; 4 possesses of double-stranded chains; 5 crystallizes in orthorhombic space group P212121 with a helical chain in its structure. The luminescence properties and the magnetic properties of the five complexes were investigated.

AB - Five novel complexes, Co(OBt)2 · 7H2O (1) (OBt = 1-hydroxybenzotriazole ion), Ni3(OBt)6 · 6H2O (2), [Ag(OBt)(HOBt)]n (3), [Zn(OBt)2]n (4) and [Cu2(OBt)4 · 3H2O]n (5) were synthesized by hydrothermal method and characterized by elemental analysis, IR spectroscopy, TGA, XRPD, and single-crystal X-ray diffraction. The results from single-crystal X-ray diffraction indicate that 1-5 are zero-dimensional (0D), zero-dimensional, one-dimensional (1D), and three-dimensional (3D) frameworks, respectively. In particular, 3 is twin crystal; 4 possesses of double-stranded chains; 5 crystallizes in orthorhombic space group P212121 with a helical chain in its structure. The luminescence properties and the magnetic properties of the five complexes were investigated.

KW - Chemical synthesis

KW - Crystal structure

KW - Fluorescence

KW - Magnetic properties

KW - N,O ligand

UR - http://www.scopus.com/inward/record.url?scp=67349106673&partnerID=8YFLogxK

U2 - 10.1016/j.ica.2009.01.044

DO - 10.1016/j.ica.2009.01.044

M3 - Article

AN - SCOPUS:67349106673

SN - 0020-1693

VL - 362

SP - 3056

EP - 3064

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 9

ER -

Synthesis, structures, luminescence/magnetic properties of complexes of the M/1-hydroxybenzotriazole, M = cobalt, nickel, silver, zinc and copper

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