Synthesis, structural investigation and properties of a novel energetic coordination polymer [Pb(tza)2]n

Zhimin Li; Guotao Zhang; Tonglai Zhang; Jianguo Zhang; Li Yang; Zunning Zhou; Shuyuan Qi; Kaibei Yu; Fengqi Zhao; Jianhua Yi; Siyu Xu; Hongxu Gao

Synthesis, structural investigation and properties of a novel energetic coordination polymer [Pb(tza)₂]_n

Zhimin Li, Guotao Zhang, Tonglai Zhang^*, Jianguo Zhang, Li Yang, Zunning Zhou, Shuyuan Qi, Kaibei Yu, Fengqi Zhao, Jianhua Yi, Siyu Xu, Hongxu Gao

^*Corresponding author for this work

School of Mechatronical Engineering

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

A novel energetic coordination polymer [Pb (tza)₂]_n was synthesized by the reaction of PbCO₃ and tetrazole-1-acetic acid in water solution, and characterized by elemental analysis and Fourier transform infrared (FT-IR) spectra. The crystal structure was investigated by using single-crystal X-ray diffraction, and it belongs to monoclinic system with space group C2/c, a=1.5370 (5) nm, b=1.0373 (3) nm, c=0.8261 (3) nm, β=119.415 (4)°, V=1.1473 (7) nm³, ρ=2.671 g/cm³, Z=2. The thermal decomposition process of [Pb (tza)₂]_n and non-isothermal kinetics analysis were investigated by using DSC and TG-DTG methods, also its sensitivities were tested according to the specifications. The study results verify that [Pb (tza)₂]_n presents good properties for potential application as an energetic material.

Original language	English
Pages (from-to)	1253-1258
Number of pages	6
Journal	Acta Chimica Sinica
Volume	69
Issue number	10
Publication status	Published - 28 May 2011

Keywords

Crystal structure
Energetic coordination polymer
Tetrazole-1-acetic acid
Thermal property

Cite this

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title = "Synthesis, structural investigation and properties of a novel energetic coordination polymer [Pb(tza)2]n",

abstract = "A novel energetic coordination polymer [Pb (tza)2]n was synthesized by the reaction of PbCO3 and tetrazole-1-acetic acid in water solution, and characterized by elemental analysis and Fourier transform infrared (FT-IR) spectra. The crystal structure was investigated by using single-crystal X-ray diffraction, and it belongs to monoclinic system with space group C2/c, a=1.5370 (5) nm, b=1.0373 (3) nm, c=0.8261 (3) nm, β=119.415 (4)°, V=1.1473 (7) nm3, ρ=2.671 g/cm3, Z=2. The thermal decomposition process of [Pb (tza)2]n and non-isothermal kinetics analysis were investigated by using DSC and TG-DTG methods, also its sensitivities were tested according to the specifications. The study results verify that [Pb (tza)2]n presents good properties for potential application as an energetic material.",

keywords = "Crystal structure, Energetic coordination polymer, Tetrazole-1-acetic acid, Thermal property",

author = "Zhimin Li and Guotao Zhang and Tonglai Zhang and Jianguo Zhang and Li Yang and Zunning Zhou and Shuyuan Qi and Kaibei Yu and Fengqi Zhao and Jianhua Yi and Siyu Xu and Hongxu Gao",

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language = "English",

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T1 - Synthesis, structural investigation and properties of a novel energetic coordination polymer [Pb(tza)2]n

AU - Li, Zhimin

AU - Zhang, Guotao

AU - Zhang, Tonglai

AU - Zhang, Jianguo

AU - Yang, Li

AU - Zhou, Zunning

AU - Qi, Shuyuan

AU - Yu, Kaibei

AU - Zhao, Fengqi

AU - Yi, Jianhua

AU - Xu, Siyu

AU - Gao, Hongxu

PY - 2011/5/28

Y1 - 2011/5/28

N2 - A novel energetic coordination polymer [Pb (tza)2]n was synthesized by the reaction of PbCO3 and tetrazole-1-acetic acid in water solution, and characterized by elemental analysis and Fourier transform infrared (FT-IR) spectra. The crystal structure was investigated by using single-crystal X-ray diffraction, and it belongs to monoclinic system with space group C2/c, a=1.5370 (5) nm, b=1.0373 (3) nm, c=0.8261 (3) nm, β=119.415 (4)°, V=1.1473 (7) nm3, ρ=2.671 g/cm3, Z=2. The thermal decomposition process of [Pb (tza)2]n and non-isothermal kinetics analysis were investigated by using DSC and TG-DTG methods, also its sensitivities were tested according to the specifications. The study results verify that [Pb (tza)2]n presents good properties for potential application as an energetic material.

AB - A novel energetic coordination polymer [Pb (tza)2]n was synthesized by the reaction of PbCO3 and tetrazole-1-acetic acid in water solution, and characterized by elemental analysis and Fourier transform infrared (FT-IR) spectra. The crystal structure was investigated by using single-crystal X-ray diffraction, and it belongs to monoclinic system with space group C2/c, a=1.5370 (5) nm, b=1.0373 (3) nm, c=0.8261 (3) nm, β=119.415 (4)°, V=1.1473 (7) nm3, ρ=2.671 g/cm3, Z=2. The thermal decomposition process of [Pb (tza)2]n and non-isothermal kinetics analysis were investigated by using DSC and TG-DTG methods, also its sensitivities were tested according to the specifications. The study results verify that [Pb (tza)2]n presents good properties for potential application as an energetic material.

KW - Crystal structure

KW - Energetic coordination polymer

KW - Tetrazole-1-acetic acid

KW - Thermal property

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M3 - Article

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SN - 0567-7351

VL - 69

SP - 1253

EP - 1258

JO - Acta Chimica Sinica

JF - Acta Chimica Sinica

IS - 10

ER -

Synthesis, structural investigation and properties of a novel energetic coordination polymer [Pb(tza)₂]_n

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Keywords

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