Synthesis of transparent nanocomposite monoliths for gamma scintillation

Chao Liu, Tibor J. Hajagos, David Kishpaugh, Yunxia Jin, Wei Hu, Qi Chen, Qibing Pei

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

1 Citation (Scopus)

Abstract

During the past decade, inorganic nanoparticles/polymer nanocomposites have been intensively studied to provide a low cost, high performance alternative for gamma scintillation. However, the aggregation of nanoparticles often occurs even at low nanoparticle concentrations and thus deteriorates the transparency and performance of these nanocomposite scintillators. Here we report an efficient fabrication protocol of transparent nanocomposite monoliths based on surface modified hafnium oxide nanoparticles. Using hafnium oxide nanoparticles with surface-grafted methacrylate groups, highly transparent bulk-size nanocomposite monoliths (2 mm thick, transmittance at 550 nm >75%) are fabricated with nanoparticle loadings up to 40 wt% (net hafnium wt% up to 28.5%). These nanocomposite monoliths of 1 cm diameter and 2 mm thickness are capable of producing a full energy photopeak for 662 keV gamma rays, with the best deconvoluted photopeak energy resolution reaching 8%.

Original languageEnglish
Title of host publicationHard X-Ray, Gamma-Ray, and Neutron Detector Physics XVII
EditorsMichael Fiederle, Arnold Burger, Larry Franks, Ralph B. James
PublisherSPIE
ISBN (Electronic)9781628417593
DOIs
Publication statusPublished - 2015
Externally publishedYes
EventHard X-Ray, Gamma-Ray, and Neutron Detector Physics XVII - San Diego, United States
Duration: 10 Aug 201512 Aug 2015

Publication series

NameProceedings of SPIE - The International Society for Optical Engineering
Volume9593
ISSN (Print)0277-786X
ISSN (Electronic)1996-756X

Conference

ConferenceHard X-Ray, Gamma-Ray, and Neutron Detector Physics XVII
Country/TerritoryUnited States
CitySan Diego
Period10/08/1512/08/15

Keywords

  • Gamma scintillator
  • Nanocomposites
  • Oxide nanoparticles
  • Surface modifications

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