Synthesis of porous nitrogen-doped graphene decorated by γ-Fe2O3 nanorings for enhancing microwave absorbing performance

Shanshan Wang, Qingze Jiao, Quan Shi, Huanhuan Zhu, Tongying Feng, Qinliang Lu, Caihong Feng, Hansheng Li, Daxin Shi, Yun Zhao*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

39 Citations (Scopus)

Abstract

Excellent wave absorbers are key materials for reducing electromagnetic radiation pollution. In this work, novel γ-Fe2O3 nanoring/porous nitrogen-doped graphene (γ-Fe2O3 NR/PNG) composites with varying mass ratios were successfully synthesized as lightweight absorbers using a two-step solvothermal method in combination with a partial reduction process. The diameter of the uniform γ-Fe2O3 NRs is approximately 150 nm with a shell thickness of approximately 50 nm. The uniform γ-Fe2O3 NRs are dispersed onto PNG sheets. Compared with pure γ-Fe2O3 NRs and PNG, all γ-Fe2O3 NR/PNG composites exhibit better microwave absorbing performance, among which a γ-Fe2O3 NR/PNG composite with a 4:1 mass ratio of γ-Fe2O3 NR:PNG shows the best absorption over a broad bandwidth for its special nanoring and porous structure and excellent impedance matching. The minimum reflection loss (RLmin) reaches −40.18 dB at 7.80 GHz with a thickness of 2.5 mm; the absorption bandwidth (RL < −10 dB) is 3.41 GHz. Moreover, the composite also reveals a good absorption for microwaves in the low frequency range. At 3.38 GHz, RLmin reaches −32.69 dB with a thickness of 5.5 mm. This work provides guidance for designing absorbers that are lightweight, wideband with strong absorption.

Original languageEnglish
Pages (from-to)1002-1010
Number of pages9
JournalCeramics International
Volume46
Issue number1
DOIs
Publication statusPublished - Jan 2020

Keywords

  • Microwave absorbing performance
  • Nanoring
  • Nitrogen-doped graphene
  • Porous composite
  • γ-FeO

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