Synthesis of [Pb(H2O)6][ATZ]·H2O and its impact on potassium nitrate decomposition temperature

Zhiyue Han; Li Gong; Zhiming Du; Wenchao Tong; Qi Jiang; Yu Wen

doi:10.1007/s10973-019-08864-8

Synthesis of [Pb(H₂O)₆][ATZ]·H₂O and its impact on potassium nitrate decomposition temperature

Zhiyue Han^*, Li Gong, Zhiming Du, Wenchao Tong, Qi Jiang, Yu Wen

^*Corresponding author for this work

School of Mechatronical Engineering

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

In this study, catalyst formation [Pb(H₂O)₆][ATZ]·H₂O (ATZ = azo tetrazolium anion) was successfully synthesized originally; meanwhile, the single-crystal structure of the compound was cultivated and analyzed by diffraction single-crystal method. The influence of the compound in which [Pb(H₂O)₆][ATZ]·H₂O was used as combustion catalyst on the decomposition temperature of potassium nitrate was studied by TG–DSC. The result proved that [Pb(H₂O)₆][ATZ]·H₂O can effectively reduce the decomposition temperature. In other words, [Pb(H₂O)₆][ATZ]·H₂O can reduce the decomposition temperature of potassium nitrate, so the addition of [Pb(H₂O)₆][ATZ]·H₂O can make potassium nitrate better to be used in the fields of initiating explosive device and fire engineering.

Original language	English
Pages (from-to)	373-379
Number of pages	7
Journal	Journal of Thermal Analysis and Calorimetry
Volume	140
Issue number	1
DOIs	https://doi.org/10.1007/s10973-019-08864-8
Publication status	Published - 1 Apr 2020

Keywords

Decomposition temperature
Potassium nitrate
Single-crystal lattice
[Pb(HO)][ATZ]·HO

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10.1007/s10973-019-08864-8

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title = "Synthesis of [Pb(H2O)6][ATZ]·H2O and its impact on potassium nitrate decomposition temperature",

abstract = "In this study, catalyst formation [Pb(H2O)6][ATZ]·H2O (ATZ = azo tetrazolium anion) was successfully synthesized originally; meanwhile, the single-crystal structure of the compound was cultivated and analyzed by diffraction single-crystal method. The influence of the compound in which [Pb(H2O)6][ATZ]·H2O was used as combustion catalyst on the decomposition temperature of potassium nitrate was studied by TG–DSC. The result proved that [Pb(H2O)6][ATZ]·H2O can effectively reduce the decomposition temperature. In other words, [Pb(H2O)6][ATZ]·H2O can reduce the decomposition temperature of potassium nitrate, so the addition of [Pb(H2O)6][ATZ]·H2O can make potassium nitrate better to be used in the fields of initiating explosive device and fire engineering.",

keywords = "Decomposition temperature, Potassium nitrate, Single-crystal lattice, [Pb(HO)][ATZ]·HO",

author = "Zhiyue Han and Li Gong and Zhiming Du and Wenchao Tong and Qi Jiang and Yu Wen",

note = "Publisher Copyright: {\textcopyright} 2019, Akad{\'e}miai Kiad{\'o}, Budapest, Hungary.",

year = "2020",

month = apr,

day = "1",

doi = "10.1007/s10973-019-08864-8",

language = "English",

volume = "140",

pages = "373--379",

journal = "Journal of Thermal Analysis and Calorimetry",

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T1 - Synthesis of [Pb(H2O)6][ATZ]·H2O and its impact on potassium nitrate decomposition temperature

AU - Han, Zhiyue

AU - Gong, Li

AU - Du, Zhiming

AU - Tong, Wenchao

AU - Jiang, Qi

AU - Wen, Yu

PY - 2020/4/1

Y1 - 2020/4/1

N2 - In this study, catalyst formation [Pb(H2O)6][ATZ]·H2O (ATZ = azo tetrazolium anion) was successfully synthesized originally; meanwhile, the single-crystal structure of the compound was cultivated and analyzed by diffraction single-crystal method. The influence of the compound in which [Pb(H2O)6][ATZ]·H2O was used as combustion catalyst on the decomposition temperature of potassium nitrate was studied by TG–DSC. The result proved that [Pb(H2O)6][ATZ]·H2O can effectively reduce the decomposition temperature. In other words, [Pb(H2O)6][ATZ]·H2O can reduce the decomposition temperature of potassium nitrate, so the addition of [Pb(H2O)6][ATZ]·H2O can make potassium nitrate better to be used in the fields of initiating explosive device and fire engineering.

AB - In this study, catalyst formation [Pb(H2O)6][ATZ]·H2O (ATZ = azo tetrazolium anion) was successfully synthesized originally; meanwhile, the single-crystal structure of the compound was cultivated and analyzed by diffraction single-crystal method. The influence of the compound in which [Pb(H2O)6][ATZ]·H2O was used as combustion catalyst on the decomposition temperature of potassium nitrate was studied by TG–DSC. The result proved that [Pb(H2O)6][ATZ]·H2O can effectively reduce the decomposition temperature. In other words, [Pb(H2O)6][ATZ]·H2O can reduce the decomposition temperature of potassium nitrate, so the addition of [Pb(H2O)6][ATZ]·H2O can make potassium nitrate better to be used in the fields of initiating explosive device and fire engineering.

KW - Decomposition temperature

KW - Potassium nitrate

KW - Single-crystal lattice

KW - [Pb(HO)][ATZ]·HO

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U2 - 10.1007/s10973-019-08864-8

DO - 10.1007/s10973-019-08864-8

M3 - Article

AN - SCOPUS:85082300396

SN - 1388-6150

VL - 140

SP - 373

EP - 379

JO - Journal of Thermal Analysis and Calorimetry

JF - Journal of Thermal Analysis and Calorimetry

IS - 1

ER -

Synthesis of [Pb(H₂O)₆][ATZ]·H₂O and its impact on potassium nitrate decomposition temperature

Abstract

Keywords

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