Synthesis of dihydroxylammonium 5, 5'-Bistetrazole -1, 1'-diolate

Xiao Jun Wang; Qiang Su; Xiao Peng Zhang; Jun Feng Wang; Chun Yuan Zhang; Xia Wang; Fen Qin Shang; Shao Hua Jin

doi:10.11943/j.issn.1006-9941.2015.05.004

Synthesis of dihydroxylammonium 5, 5'-Bistetrazole -1, 1'-diolate

Xiao Jun Wang^*, Qiang Su, Xiao Peng Zhang, Jun Feng Wang, Chun Yuan Zhang, Xia Wang, Fen Qin Shang, Shao Hua Jin

^*Corresponding author for this work

School of Material Science and Engineering

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

The dihydroxylammonium 5, 5'-bistetrazole -1, 1'-diolate(TKX-50) was synthesized using solution glyoxal (40% w/w in H₂O) and hydroxylammonium as starting materials by substitution, chloration, nitrine reaction, ring formation reaction, and salt formation reaction. Its structure was characterized by elemental analysis and NMR, and its impact sensitivity and friction sensitivity were studied. The effects of reaction temperature, holding time and holding temperature on yield of 5, 5'-bistetrazole -1, 1'-diolate (BTO), and the effect of concentration of hydroxylamine on yield of TKX-50 were discussed. Results show that the impact sensitivity H₅₀ for TKX-50 is 41 cm, and its friction sensitivity is 0%.The optimal reaction condition are as following: reaction temperature 0-5℃, holding time 12 h, holding temperature 20-25℃, when the concentration of hydroxylamine is 50%(w/w in H₂O).

Original language	English
Pages (from-to)	424-427
Number of pages	4
Journal	Hanneng Cailiao/Chinese Journal of Energetic Materials
Volume	23
Issue number	5
DOIs	https://doi.org/10.11943/j.issn.1006-9941.2015.05.004
Publication status	Published - 25 May 2015

Keywords

Dihydroxylammonium 5, 5'-bistetrazole -1, 1'-diolate(TKX-50)
Energetic materials
Sensitivity
Synthesis

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10.11943/j.issn.1006-9941.2015.05.004

Cite this

Wang, X. J., Su, Q., Zhang, X. P., Wang, J. F., Zhang, C. Y., Wang, X., Shang, F. Q., & Jin, S. H. (2015). Synthesis of dihydroxylammonium 5, 5'-Bistetrazole -1, 1'-diolate. Hanneng Cailiao/Chinese Journal of Energetic Materials, 23(5), 424-427. https://doi.org/10.11943/j.issn.1006-9941.2015.05.004

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title = "Synthesis of dihydroxylammonium 5, 5'-Bistetrazole -1, 1'-diolate",

abstract = "The dihydroxylammonium 5, 5'-bistetrazole -1, 1'-diolate(TKX-50) was synthesized using solution glyoxal (40% w/w in H2O) and hydroxylammonium as starting materials by substitution, chloration, nitrine reaction, ring formation reaction, and salt formation reaction. Its structure was characterized by elemental analysis and NMR, and its impact sensitivity and friction sensitivity were studied. The effects of reaction temperature, holding time and holding temperature on yield of 5, 5'-bistetrazole -1, 1'-diolate (BTO), and the effect of concentration of hydroxylamine on yield of TKX-50 were discussed. Results show that the impact sensitivity H50 for TKX-50 is 41 cm, and its friction sensitivity is 0%.The optimal reaction condition are as following: reaction temperature 0-5℃, holding time 12 h, holding temperature 20-25℃, when the concentration of hydroxylamine is 50%(w/w in H2O).",

keywords = "Dihydroxylammonium 5, 5'-bistetrazole -1, 1'-diolate(TKX-50), Energetic materials, Sensitivity, Synthesis",

author = "Wang, {Xiao Jun} and Qiang Su and Zhang, {Xiao Peng} and Wang, {Jun Feng} and Zhang, {Chun Yuan} and Xia Wang and Shang, {Fen Qin} and Jin, {Shao Hua}",

year = "2015",

month = may,

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doi = "10.11943/j.issn.1006-9941.2015.05.004",

language = "English",

volume = "23",

pages = "424--427",

journal = "Hanneng Cailiao/Chinese Journal of Energetic Materials",

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T1 - Synthesis of dihydroxylammonium 5, 5'-Bistetrazole -1, 1'-diolate

AU - Wang, Xiao Jun

AU - Su, Qiang

AU - Zhang, Xiao Peng

AU - Wang, Jun Feng

AU - Zhang, Chun Yuan

AU - Wang, Xia

AU - Shang, Fen Qin

AU - Jin, Shao Hua

PY - 2015/5/25

Y1 - 2015/5/25

N2 - The dihydroxylammonium 5, 5'-bistetrazole -1, 1'-diolate(TKX-50) was synthesized using solution glyoxal (40% w/w in H2O) and hydroxylammonium as starting materials by substitution, chloration, nitrine reaction, ring formation reaction, and salt formation reaction. Its structure was characterized by elemental analysis and NMR, and its impact sensitivity and friction sensitivity were studied. The effects of reaction temperature, holding time and holding temperature on yield of 5, 5'-bistetrazole -1, 1'-diolate (BTO), and the effect of concentration of hydroxylamine on yield of TKX-50 were discussed. Results show that the impact sensitivity H50 for TKX-50 is 41 cm, and its friction sensitivity is 0%.The optimal reaction condition are as following: reaction temperature 0-5℃, holding time 12 h, holding temperature 20-25℃, when the concentration of hydroxylamine is 50%(w/w in H2O).

AB - The dihydroxylammonium 5, 5'-bistetrazole -1, 1'-diolate(TKX-50) was synthesized using solution glyoxal (40% w/w in H2O) and hydroxylammonium as starting materials by substitution, chloration, nitrine reaction, ring formation reaction, and salt formation reaction. Its structure was characterized by elemental analysis and NMR, and its impact sensitivity and friction sensitivity were studied. The effects of reaction temperature, holding time and holding temperature on yield of 5, 5'-bistetrazole -1, 1'-diolate (BTO), and the effect of concentration of hydroxylamine on yield of TKX-50 were discussed. Results show that the impact sensitivity H50 for TKX-50 is 41 cm, and its friction sensitivity is 0%.The optimal reaction condition are as following: reaction temperature 0-5℃, holding time 12 h, holding temperature 20-25℃, when the concentration of hydroxylamine is 50%(w/w in H2O).

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KW - Sensitivity

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JF - Hanneng Cailiao/Chinese Journal of Energetic Materials

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Synthesis of dihydroxylammonium 5, 5'-Bistetrazole -1, 1'-diolate

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