Synthesis of 1H-polychlorofluorocycloolefins

Gang Yang; Chengping Zhang; Hui e. Yang; Hengdao Quan

doi:10.1016/j.jfluchem.2018.10.005

Synthesis of 1H-polychlorofluorocycloolefins

Gang Yang, Chengping Zhang, Hui e. Yang, Hengdao Quan^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

The synthesis of 1H-polychlorofluorocycloolefin by the hydrodehalogenation of perchlorofluorocycloolefin containing –CCl=CCl– or –CCl=CF– group in dimethylformaide (DMF) or dimethylacetamide (DMAC) over Zn was investigated. It was found that the hydrodehalogenation of perchlorofluorocycloolefin occurred only on the C (sp²) position but not on C (sp³) position. In addition, the mechanisms of the hydrodehalogenation of perchlorofluorocycloolefin were proposed.

Original language	English
Pages (from-to)	96-101
Number of pages	6
Journal	Journal of Fluorine Chemistry
Volume	216
DOIs	https://doi.org/10.1016/j.jfluchem.2018.10.005
Publication status	Published - Dec 2018
Externally published	Yes

Keywords

1H-perchlorofluorocycloolefins
Cl-H exchange
DMAC
DMF
Hydrodehalogenation

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10.1016/j.jfluchem.2018.10.005

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@article{48e1e53005354633b52ef603e65ac8ab,

title = "Synthesis of 1H-polychlorofluorocycloolefins",

abstract = "The synthesis of 1H-polychlorofluorocycloolefin by the hydrodehalogenation of perchlorofluorocycloolefin containing –CCl=CCl– or –CCl=CF– group in dimethylformaide (DMF) or dimethylacetamide (DMAC) over Zn was investigated. It was found that the hydrodehalogenation of perchlorofluorocycloolefin occurred only on the C (sp2) position but not on C (sp3) position. In addition, the mechanisms of the hydrodehalogenation of perchlorofluorocycloolefin were proposed.",

keywords = "1H-perchlorofluorocycloolefins, Cl-H exchange, DMAC, DMF, Hydrodehalogenation",

author = "Gang Yang and Chengping Zhang and Yang, {Hui e.} and Hengdao Quan",

note = "Publisher Copyright: {\textcopyright} 2018 Elsevier B.V.",

year = "2018",

month = dec,

doi = "10.1016/j.jfluchem.2018.10.005",

language = "English",

volume = "216",

pages = "96--101",

journal = "Journal of Fluorine Chemistry",

issn = "0022-1139",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Synthesis of 1H-polychlorofluorocycloolefins

AU - Yang, Gang

AU - Zhang, Chengping

AU - Yang, Hui e.

AU - Quan, Hengdao

PY - 2018/12

Y1 - 2018/12

N2 - The synthesis of 1H-polychlorofluorocycloolefin by the hydrodehalogenation of perchlorofluorocycloolefin containing –CCl=CCl– or –CCl=CF– group in dimethylformaide (DMF) or dimethylacetamide (DMAC) over Zn was investigated. It was found that the hydrodehalogenation of perchlorofluorocycloolefin occurred only on the C (sp2) position but not on C (sp3) position. In addition, the mechanisms of the hydrodehalogenation of perchlorofluorocycloolefin were proposed.

AB - The synthesis of 1H-polychlorofluorocycloolefin by the hydrodehalogenation of perchlorofluorocycloolefin containing –CCl=CCl– or –CCl=CF– group in dimethylformaide (DMF) or dimethylacetamide (DMAC) over Zn was investigated. It was found that the hydrodehalogenation of perchlorofluorocycloolefin occurred only on the C (sp2) position but not on C (sp3) position. In addition, the mechanisms of the hydrodehalogenation of perchlorofluorocycloolefin were proposed.

KW - 1H-perchlorofluorocycloolefins

KW - Cl-H exchange

KW - DMAC

KW - DMF

KW - Hydrodehalogenation

UR - http://www.scopus.com/inward/record.url?scp=85055505309&partnerID=8YFLogxK

U2 - 10.1016/j.jfluchem.2018.10.005

DO - 10.1016/j.jfluchem.2018.10.005

M3 - Article

AN - SCOPUS:85055505309

SN - 0022-1139

VL - 216

SP - 96

EP - 101

JO - Journal of Fluorine Chemistry

JF - Journal of Fluorine Chemistry

ER -

Synthesis of 1H-polychlorofluorocycloolefins

Abstract

Keywords

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