Synthesis of 1H-polychlorofluorocycloolefins

Gang Yang; Chengping Zhang; Hui e. Yang; Hengdao Quan

doi:10.1016/j.jfluchem.2018.10.005

Synthesis of 1H-polychlorofluorocycloolefins

Gang Yang, Chengping Zhang, Hui e. Yang, Hengdao Quan^*

^*此作品的通讯作者

科研成果: 期刊稿件 › 文章 › 同行评审

5 引用（Scopus）

摘要

The synthesis of 1H-polychlorofluorocycloolefin by the hydrodehalogenation of perchlorofluorocycloolefin containing –CCl=CCl– or –CCl=CF– group in dimethylformaide (DMF) or dimethylacetamide (DMAC) over Zn was investigated. It was found that the hydrodehalogenation of perchlorofluorocycloolefin occurred only on the C (sp²) position but not on C (sp³) position. In addition, the mechanisms of the hydrodehalogenation of perchlorofluorocycloolefin were proposed.

源语言	英语
页（从-至）	96-101
页数	6
期刊	Journal of Fluorine Chemistry
卷	216
DOI	https://doi.org/10.1016/j.jfluchem.2018.10.005
出版状态	已出版 - 12月 2018
已对外发布	是

访问文件

10.1016/j.jfluchem.2018.10.005

其它文件与链接

链接到 Scopus 的出版物

引用此

@article{48e1e53005354633b52ef603e65ac8ab,

title = "Synthesis of 1H-polychlorofluorocycloolefins",

abstract = "The synthesis of 1H-polychlorofluorocycloolefin by the hydrodehalogenation of perchlorofluorocycloolefin containing –CCl=CCl– or –CCl=CF– group in dimethylformaide (DMF) or dimethylacetamide (DMAC) over Zn was investigated. It was found that the hydrodehalogenation of perchlorofluorocycloolefin occurred only on the C (sp2) position but not on C (sp3) position. In addition, the mechanisms of the hydrodehalogenation of perchlorofluorocycloolefin were proposed.",

keywords = "1H-perchlorofluorocycloolefins, Cl-H exchange, DMAC, DMF, Hydrodehalogenation",

author = "Gang Yang and Chengping Zhang and Yang, {Hui e.} and Hengdao Quan",

note = "Publisher Copyright: {\textcopyright} 2018 Elsevier B.V.",

year = "2018",

month = dec,

doi = "10.1016/j.jfluchem.2018.10.005",

language = "English",

volume = "216",

pages = "96--101",

journal = "Journal of Fluorine Chemistry",

issn = "0022-1139",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Synthesis of 1H-polychlorofluorocycloolefins

AU - Yang, Gang

AU - Zhang, Chengping

AU - Yang, Hui e.

AU - Quan, Hengdao

PY - 2018/12

Y1 - 2018/12

N2 - The synthesis of 1H-polychlorofluorocycloolefin by the hydrodehalogenation of perchlorofluorocycloolefin containing –CCl=CCl– or –CCl=CF– group in dimethylformaide (DMF) or dimethylacetamide (DMAC) over Zn was investigated. It was found that the hydrodehalogenation of perchlorofluorocycloolefin occurred only on the C (sp2) position but not on C (sp3) position. In addition, the mechanisms of the hydrodehalogenation of perchlorofluorocycloolefin were proposed.

AB - The synthesis of 1H-polychlorofluorocycloolefin by the hydrodehalogenation of perchlorofluorocycloolefin containing –CCl=CCl– or –CCl=CF– group in dimethylformaide (DMF) or dimethylacetamide (DMAC) over Zn was investigated. It was found that the hydrodehalogenation of perchlorofluorocycloolefin occurred only on the C (sp2) position but not on C (sp3) position. In addition, the mechanisms of the hydrodehalogenation of perchlorofluorocycloolefin were proposed.

KW - 1H-perchlorofluorocycloolefins

KW - Cl-H exchange

KW - DMAC

KW - DMF

KW - Hydrodehalogenation

UR - http://www.scopus.com/inward/record.url?scp=85055505309&partnerID=8YFLogxK

U2 - 10.1016/j.jfluchem.2018.10.005

DO - 10.1016/j.jfluchem.2018.10.005

M3 - Article

AN - SCOPUS:85055505309

SN - 0022-1139

VL - 216

SP - 96

EP - 101

JO - Journal of Fluorine Chemistry

JF - Journal of Fluorine Chemistry

ER -