Synthesis, crystal structure of 1-D double-helical chain manganese(II) coordination polymer constructed by 2,2′-bpy and flexible dicarboxylate ligand with strong fluorescent emission

Li Yang; Wei Yu; Tong Lai Zhang; Jian Guo Zhang; Shao Zong Wang; Rui Feng Wu

doi:10.1002/zaac.200700292

Synthesis, crystal structure of 1-D double-helical chain manganese(II) coordination polymer constructed by 2,2′-bpy and flexible dicarboxylate ligand with strong fluorescent emission

Li Yang^*, Wei Yu, Tong Lai Zhang, Jian Guo Zhang, Shao Zong Wang, Rui Feng Wu

^*Corresponding author for this work

School of Mechatronical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

A new coordination polymer [Mn₂(nbdoa)₂(2,2′- bpy)₂]_n was obtained by hydrothermal reaction, which was constructed by 2,2′-bpy and flexible ligand 2-nitro-benzene-1,4- di(oxyacetate). The crystal structure reveals that there exists 1-D double-helical chain, which is connected to 2-D network via π-π stacking interactions. The thermal analysis shows that the complex begins to decompose at 567 K. The luminescence property was investigated and the complex shows photoluminescence in the solid state at room temperature.

Original language	English
Pages (from-to)	2046-2048
Number of pages	3
Journal	Zeitschrift fur Anorganische und Allgemeine Chemie
Volume	633
Issue number	11-12
DOIs	https://doi.org/10.1002/zaac.200700292
Publication status	Published - 2007

Keywords

2-nitro-benzene-1,4-di(oxyacetate)
Coordination polymers
Fluorescent emission
Manganese

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10.1002/zaac.200700292

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Yang, L., Yu, W., Zhang, T. L., Zhang, J. G., Wang, S. Z., & Wu, R. F. (2007). Synthesis, crystal structure of 1-D double-helical chain manganese(II) coordination polymer constructed by 2,2′-bpy and flexible dicarboxylate ligand with strong fluorescent emission. Zeitschrift fur Anorganische und Allgemeine Chemie, 633(11-12), 2046-2048. https://doi.org/10.1002/zaac.200700292

@article{3676471de6cf4f53b24a6fd6bc4457bc,

title = "Synthesis, crystal structure of 1-D double-helical chain manganese(II) coordination polymer constructed by 2,2′-bpy and flexible dicarboxylate ligand with strong fluorescent emission",

abstract = "A new coordination polymer [Mn2(nbdoa)2(2,2′- bpy)2]n was obtained by hydrothermal reaction, which was constructed by 2,2′-bpy and flexible ligand 2-nitro-benzene-1,4- di(oxyacetate). The crystal structure reveals that there exists 1-D double-helical chain, which is connected to 2-D network via π-π stacking interactions. The thermal analysis shows that the complex begins to decompose at 567 K. The luminescence property was investigated and the complex shows photoluminescence in the solid state at room temperature.",

keywords = "2-nitro-benzene-1,4-di(oxyacetate), Coordination polymers, Fluorescent emission, Manganese",

author = "Li Yang and Wei Yu and Zhang, {Tong Lai} and Zhang, {Jian Guo} and Wang, {Shao Zong} and Wu, {Rui Feng}",

year = "2007",

doi = "10.1002/zaac.200700292",

language = "English",

volume = "633",

pages = "2046--2048",

journal = "Zeitschrift fur Anorganische und Allgemeine Chemie",

issn = "0044-2313",

publisher = "Wiley-VCH Verlag",

number = "11-12",

}

Yang, L, Yu, W, Zhang, TL, Zhang, JG, Wang, SZ & Wu, RF 2007, 'Synthesis, crystal structure of 1-D double-helical chain manganese(II) coordination polymer constructed by 2,2′-bpy and flexible dicarboxylate ligand with strong fluorescent emission', Zeitschrift fur Anorganische und Allgemeine Chemie, vol. 633, no. 11-12, pp. 2046-2048. https://doi.org/10.1002/zaac.200700292

Synthesis, crystal structure of 1-D double-helical chain manganese(II) coordination polymer constructed by 2,2′-bpy and flexible dicarboxylate ligand with strong fluorescent emission. / Yang, Li; Yu, Wei; Zhang, Tong Lai et al.
In: Zeitschrift fur Anorganische und Allgemeine Chemie, Vol. 633, No. 11-12, 2007, p. 2046-2048.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis, crystal structure of 1-D double-helical chain manganese(II) coordination polymer constructed by 2,2′-bpy and flexible dicarboxylate ligand with strong fluorescent emission

AU - Yang, Li

AU - Yu, Wei

AU - Zhang, Tong Lai

AU - Zhang, Jian Guo

AU - Wang, Shao Zong

AU - Wu, Rui Feng

PY - 2007

Y1 - 2007

N2 - A new coordination polymer [Mn2(nbdoa)2(2,2′- bpy)2]n was obtained by hydrothermal reaction, which was constructed by 2,2′-bpy and flexible ligand 2-nitro-benzene-1,4- di(oxyacetate). The crystal structure reveals that there exists 1-D double-helical chain, which is connected to 2-D network via π-π stacking interactions. The thermal analysis shows that the complex begins to decompose at 567 K. The luminescence property was investigated and the complex shows photoluminescence in the solid state at room temperature.

AB - A new coordination polymer [Mn2(nbdoa)2(2,2′- bpy)2]n was obtained by hydrothermal reaction, which was constructed by 2,2′-bpy and flexible ligand 2-nitro-benzene-1,4- di(oxyacetate). The crystal structure reveals that there exists 1-D double-helical chain, which is connected to 2-D network via π-π stacking interactions. The thermal analysis shows that the complex begins to decompose at 567 K. The luminescence property was investigated and the complex shows photoluminescence in the solid state at room temperature.

KW - 2-nitro-benzene-1,4-di(oxyacetate)

KW - Coordination polymers

KW - Fluorescent emission

KW - Manganese

UR - http://www.scopus.com/inward/record.url?scp=34548744093&partnerID=8YFLogxK

U2 - 10.1002/zaac.200700292

DO - 10.1002/zaac.200700292

M3 - Article

AN - SCOPUS:34548744093

SN - 0044-2313

VL - 633

SP - 2046

EP - 2048

JO - Zeitschrift fur Anorganische und Allgemeine Chemie

JF - Zeitschrift fur Anorganische und Allgemeine Chemie

IS - 11-12

ER -

Synthesis, crystal structure of 1-D double-helical chain manganese(II) coordination polymer constructed by 2,2′-bpy and flexible dicarboxylate ligand with strong fluorescent emission

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