Synthesis, characterization and thermal stability of the aluminum boroxine-linked compound with N-aryl substituted β-Diketiminato Ligand

Peng Fei Hao; Zhi Yang; Xiao Li Ma; Jia Rong Li

doi:10.3969/j.issn.1001-4861.2013.00.296

Synthesis, characterization and thermal stability of the aluminum boroxine-linked compound with N-aryl substituted β-Diketiminato Ligand

Peng Fei Hao, Zhi Yang^*, Xiao Li Ma, Jia Rong Li

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

The reaction of LA1H₂ (L=(Z)-4-[(2,6-diisopropylphenyl)amino]pent-3-en-2-ylidene-2,6-diisopropylaniline) with 2-trifluoromethylphenylboronic acid resulted in the boroxine-linked organic aluminum compound LAI [OB(2-CF₃C₆H₄)]₂ (μ-O). Compound is an unique example of a spiro-centered aluminum atom, showing the inorganic A1O₃B₂ ring fused to the organic C₃N₂ part. Compound was characterized by ¹H NMR, IR, elemental analysis, and single crystal X-ray structural analysis. Furthermore, compound was studied by TG analysis.

Original language	English
Pages (from-to)	1909-1913
Number of pages	5
Journal	Chinese Journal of Inorganic Chemistry
Volume	29
Issue number	9
DOIs	https://doi.org/10.3969/j.issn.1001-4861.2013.00.296
Publication status	Published - Sept 2013

Keywords

3-diketiminato ligand
Aluminum boroxine
Six-membered ring
Thermal stability

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10.3969/j.issn.1001-4861.2013.00.296

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title = "Synthesis, characterization and thermal stability of the aluminum boroxine-linked compound with N-aryl substituted β-Diketiminato Ligand",

abstract = "The reaction of LA1H2 (L=(Z)-4-[(2,6-diisopropylphenyl)amino]pent-3-en-2-ylidene-2,6-diisopropylaniline) with 2-trifluoromethylphenylboronic acid resulted in the boroxine-linked organic aluminum compound LAI [OB(2-CF3C6H4)]2 (μ-O). Compound is an unique example of a spiro-centered aluminum atom, showing the inorganic A1O3B2 ring fused to the organic C3N2 part. Compound was characterized by 1H NMR, IR, elemental analysis, and single crystal X-ray structural analysis. Furthermore, compound was studied by TG analysis.",

keywords = "3-diketiminato ligand, Aluminum boroxine, Six-membered ring, Thermal stability",

author = "Hao, {Peng Fei} and Zhi Yang and Ma, {Xiao Li} and Li, {Jia Rong}",

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doi = "10.3969/j.issn.1001-4861.2013.00.296",

language = "English",

volume = "29",

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journal = "Chinese Journal of Inorganic Chemistry",

issn = "1001-4861",

publisher = "Chinese Chemical Society",

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TY - JOUR

T1 - Synthesis, characterization and thermal stability of the aluminum boroxine-linked compound with N-aryl substituted β-Diketiminato Ligand

AU - Hao, Peng Fei

AU - Yang, Zhi

AU - Ma, Xiao Li

AU - Li, Jia Rong

PY - 2013/9

Y1 - 2013/9

N2 - The reaction of LA1H2 (L=(Z)-4-[(2,6-diisopropylphenyl)amino]pent-3-en-2-ylidene-2,6-diisopropylaniline) with 2-trifluoromethylphenylboronic acid resulted in the boroxine-linked organic aluminum compound LAI [OB(2-CF3C6H4)]2 (μ-O). Compound is an unique example of a spiro-centered aluminum atom, showing the inorganic A1O3B2 ring fused to the organic C3N2 part. Compound was characterized by 1H NMR, IR, elemental analysis, and single crystal X-ray structural analysis. Furthermore, compound was studied by TG analysis.

AB - The reaction of LA1H2 (L=(Z)-4-[(2,6-diisopropylphenyl)amino]pent-3-en-2-ylidene-2,6-diisopropylaniline) with 2-trifluoromethylphenylboronic acid resulted in the boroxine-linked organic aluminum compound LAI [OB(2-CF3C6H4)]2 (μ-O). Compound is an unique example of a spiro-centered aluminum atom, showing the inorganic A1O3B2 ring fused to the organic C3N2 part. Compound was characterized by 1H NMR, IR, elemental analysis, and single crystal X-ray structural analysis. Furthermore, compound was studied by TG analysis.

KW - 3-diketiminato ligand

KW - Aluminum boroxine

KW - Six-membered ring

KW - Thermal stability

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U2 - 10.3969/j.issn.1001-4861.2013.00.296

DO - 10.3969/j.issn.1001-4861.2013.00.296

M3 - Article

AN - SCOPUS:84907976307

SN - 1001-4861

VL - 29

SP - 1909

EP - 1913

JO - Chinese Journal of Inorganic Chemistry

JF - Chinese Journal of Inorganic Chemistry

IS - 9

ER -

Synthesis, characterization and thermal stability of the aluminum boroxine-linked compound with N-aryl substituted β-Diketiminato Ligand

Abstract

Keywords

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