Synthesis and structure of KBGe2O6: The first chiral zeotype borogermanate with 7-ring channels

Zhi En Lin; Jie Zhang; Guo Yu Yang

doi:10.1021/ic020511h

Synthesis and structure of KBGe₂O₆: The first chiral zeotype borogermanate with 7-ring channels

Zhi En Lin, Jie Zhang, Guo Yu Yang^*

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

82 Citations (Scopus)

Abstract

Among the known zeolite topologies, odd rings are rare with the exception of 5-ring. We report here the hydrothermal synthesis and structural characterization of a novel compound, KBGe₂O₆, the first germanate-based zeotype material with 7-ring channels. It crystallized in the orthorhombic system, space group P2₁2₁2₁ (No. 19), a = 4.8037(3) Å, b = 10.2063(7) Å, c = 10.7402(10) Å, V = 526.57(5) Å³, Z = 3. The framework topology of this compound is previous unknown with the vertex symbol 4·6·4·6· 6·7₂(vertex1), 4·6·4·6·6·7₂(vertex2), and 6·6·6·6·6₂· 7₂(vertex3). It is worth noting that the structure of the compound is chiral containing helices condensed from GeO₄ tetrahedra, which arrange around 2₁ screw axes. Furthermore, the K⁺ ions within the channels are mobile and can be partially ion-exchanged with Na⁺ at room temperature.

Original language	English
Pages (from-to)	1797-1799
Number of pages	3
Journal	Inorganic Chemistry
Volume	42
Issue number	6
DOIs	https://doi.org/10.1021/ic020511h
Publication status	Published - 24 Mar 2003
Externally published	Yes

Access to Document

10.1021/ic020511h

Cite this

@article{d7e18d1961da42ddbcb6b79144e6df00,

title = "Synthesis and structure of KBGe2O6: The first chiral zeotype borogermanate with 7-ring channels",

abstract = "Among the known zeolite topologies, odd rings are rare with the exception of 5-ring. We report here the hydrothermal synthesis and structural characterization of a novel compound, KBGe2O6, the first germanate-based zeotype material with 7-ring channels. It crystallized in the orthorhombic system, space group P212121 (No. 19), a = 4.8037(3) {\AA}, b = 10.2063(7) {\AA}, c = 10.7402(10) {\AA}, V = 526.57(5) {\AA}3, Z = 3. The framework topology of this compound is previous unknown with the vertex symbol 4·6·4·6· 6·72(vertex1), 4·6·4·6·6·72(vertex2), and 6·6·6·6·62· 72(vertex3). It is worth noting that the structure of the compound is chiral containing helices condensed from GeO4 tetrahedra, which arrange around 21 screw axes. Furthermore, the K+ ions within the channels are mobile and can be partially ion-exchanged with Na+ at room temperature.",

author = "Lin, {Zhi En} and Jie Zhang and Yang, {Guo Yu}",

year = "2003",

month = mar,

day = "24",

doi = "10.1021/ic020511h",

language = "English",

volume = "42",

pages = "1797--1799",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "6",

}

TY - JOUR

T1 - Synthesis and structure of KBGe2O6

T2 - The first chiral zeotype borogermanate with 7-ring channels

AU - Lin, Zhi En

AU - Zhang, Jie

AU - Yang, Guo Yu

PY - 2003/3/24

Y1 - 2003/3/24

N2 - Among the known zeolite topologies, odd rings are rare with the exception of 5-ring. We report here the hydrothermal synthesis and structural characterization of a novel compound, KBGe2O6, the first germanate-based zeotype material with 7-ring channels. It crystallized in the orthorhombic system, space group P212121 (No. 19), a = 4.8037(3) Å, b = 10.2063(7) Å, c = 10.7402(10) Å, V = 526.57(5) Å3, Z = 3. The framework topology of this compound is previous unknown with the vertex symbol 4·6·4·6· 6·72(vertex1), 4·6·4·6·6·72(vertex2), and 6·6·6·6·62· 72(vertex3). It is worth noting that the structure of the compound is chiral containing helices condensed from GeO4 tetrahedra, which arrange around 21 screw axes. Furthermore, the K+ ions within the channels are mobile and can be partially ion-exchanged with Na+ at room temperature.

AB - Among the known zeolite topologies, odd rings are rare with the exception of 5-ring. We report here the hydrothermal synthesis and structural characterization of a novel compound, KBGe2O6, the first germanate-based zeotype material with 7-ring channels. It crystallized in the orthorhombic system, space group P212121 (No. 19), a = 4.8037(3) Å, b = 10.2063(7) Å, c = 10.7402(10) Å, V = 526.57(5) Å3, Z = 3. The framework topology of this compound is previous unknown with the vertex symbol 4·6·4·6· 6·72(vertex1), 4·6·4·6·6·72(vertex2), and 6·6·6·6·62· 72(vertex3). It is worth noting that the structure of the compound is chiral containing helices condensed from GeO4 tetrahedra, which arrange around 21 screw axes. Furthermore, the K+ ions within the channels are mobile and can be partially ion-exchanged with Na+ at room temperature.

UR - http://www.scopus.com/inward/record.url?scp=0037464312&partnerID=8YFLogxK

U2 - 10.1021/ic020511h

DO - 10.1021/ic020511h

M3 - Article

AN - SCOPUS:0037464312

SN - 0020-1669

VL - 42

SP - 1797

EP - 1799

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 6

ER -

Synthesis and structure of KBGe₂O₆: The first chiral zeotype borogermanate with 7-ring channels

Abstract

Access to Document

Other files and links

Fingerprint

Cite this