Synthesis and structural characterization of [Co(Q)2(H2O)2] (Q = 8-hydroxyquinoline ion)

Chang Wen Hu; Chun Xiu Wang; Hui Li; Xue Li Niu; Wan Long Pan; Yun Gong

Synthesis and structural characterization of [Co(Q)₂(H₂O)₂] (Q = 8-hydroxyquinoline ion)

Chang Wen Hu^*, Chun Xiu Wang, Hui Li, Xue Li Niu, Wan Long Pan, Yun Gong

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

The single crystal of bi (8-hydroxyquinoline) bihydrated cobalt(II) complex, [Co(Q)₂(H₂O)₂] (Q = 8-hydroxyquinoline ion), has been synthesized by general method and structurally characterized by single crystal X-ray diffraction. Crystal data: C₁₈H₁₆CoN₂O₄, monoclinic, C2/c, a = 1.336 2(4) nm, b = 0.941 2(3) nm, c = 1.354 3(4) nm, β = 109.672(4)°, Z = 4. In the complex, Co(II) ion is six-coordinated, forming a distorted octahedron. H-bonding and π-π stacking interaction play a significant role to form and stabilize the three-dimensional structure.

Original language	English
Pages (from-to)	221-224
Number of pages	4
Journal	Journal of Beijing Institute of Technology (English Edition)
Volume	15
Issue number	2
Publication status	Published - Jun 2006

Keywords

8-hydroxyquinoline
Co(II) complex
Crystal structure
Hydrogen bonding
π-π stacking

Cite this

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title = "Synthesis and structural characterization of [Co(Q)2(H2O)2] (Q = 8-hydroxyquinoline ion)",

abstract = "The single crystal of bi (8-hydroxyquinoline) bihydrated cobalt(II) complex, [Co(Q)2(H2O)2] (Q = 8-hydroxyquinoline ion), has been synthesized by general method and structurally characterized by single crystal X-ray diffraction. Crystal data: C18H16CoN2O4, monoclinic, C2/c, a = 1.336 2(4) nm, b = 0.941 2(3) nm, c = 1.354 3(4) nm, β = 109.672(4)°, Z = 4. In the complex, Co(II) ion is six-coordinated, forming a distorted octahedron. H-bonding and π-π stacking interaction play a significant role to form and stabilize the three-dimensional structure.",

keywords = "8-hydroxyquinoline, Co(II) complex, Crystal structure, Hydrogen bonding, π-π stacking",

author = "Hu, {Chang Wen} and Wang, {Chun Xiu} and Hui Li and Niu, {Xue Li} and Pan, {Wan Long} and Yun Gong",

year = "2006",

month = jun,

language = "English",

volume = "15",

pages = "221--224",

journal = "Journal of Beijing Institute of Technology (English Edition)",

issn = "1004-0579",

publisher = "Beijing Institute of Technology",

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TY - JOUR

T1 - Synthesis and structural characterization of [Co(Q)2(H2O)2] (Q = 8-hydroxyquinoline ion)

AU - Hu, Chang Wen

AU - Wang, Chun Xiu

AU - Li, Hui

AU - Niu, Xue Li

AU - Pan, Wan Long

AU - Gong, Yun

PY - 2006/6

Y1 - 2006/6

N2 - The single crystal of bi (8-hydroxyquinoline) bihydrated cobalt(II) complex, [Co(Q)2(H2O)2] (Q = 8-hydroxyquinoline ion), has been synthesized by general method and structurally characterized by single crystal X-ray diffraction. Crystal data: C18H16CoN2O4, monoclinic, C2/c, a = 1.336 2(4) nm, b = 0.941 2(3) nm, c = 1.354 3(4) nm, β = 109.672(4)°, Z = 4. In the complex, Co(II) ion is six-coordinated, forming a distorted octahedron. H-bonding and π-π stacking interaction play a significant role to form and stabilize the three-dimensional structure.

AB - The single crystal of bi (8-hydroxyquinoline) bihydrated cobalt(II) complex, [Co(Q)2(H2O)2] (Q = 8-hydroxyquinoline ion), has been synthesized by general method and structurally characterized by single crystal X-ray diffraction. Crystal data: C18H16CoN2O4, monoclinic, C2/c, a = 1.336 2(4) nm, b = 0.941 2(3) nm, c = 1.354 3(4) nm, β = 109.672(4)°, Z = 4. In the complex, Co(II) ion is six-coordinated, forming a distorted octahedron. H-bonding and π-π stacking interaction play a significant role to form and stabilize the three-dimensional structure.

KW - 8-hydroxyquinoline

KW - Co(II) complex

KW - Crystal structure

KW - Hydrogen bonding

KW - π-π stacking

UR - http://www.scopus.com/inward/record.url?scp=33748454882&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:33748454882

SN - 1004-0579

VL - 15

SP - 221

EP - 224

JO - Journal of Beijing Institute of Technology (English Edition)

JF - Journal of Beijing Institute of Technology (English Edition)

IS - 2

ER -

Synthesis and structural characterization of [Co(Q)₂(H₂O)₂] (Q = 8-hydroxyquinoline ion)

Abstract

Keywords

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