Synthesis and characterization of heterobimetallic aluminum-germanium(IV) disulfides

Zhi Yang; Xiaoli Ma; Zhensheng Zhang; Herbert W. Roesky; Jörg Magull; Arne Ringe

doi:10.1002/zaac.200800030

Synthesis and characterization of heterobimetallic aluminum-germanium(IV) disulfides

Zhi Yang^*, Xiaoli Ma, Zhensheng Zhang, Herbert W. Roesky, Jörg Magull, Arne Ringe

^*Corresponding author for this work

University of Göttingen

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

Three heterobimetallic aluminum-germanium(IV) disulfides are synthesized. The reaction of {LAl[(SLi)₂(THF)₂]}₂ (1) (L = HC(CMeNAr)₂, Ar = 2,6-iPr₂C₆H₃) with Ph₂GeCl₂, Me₂GeCl₂, and GeCl ₄, respectively, in THF afforded LAl(μ-S)₂GePh ₂ (2), LAl(μ-S)₂GeMe₂ (3) and LAl(μ-S)₂Ge(μ-S)₂AlL (4) in good yields. Compounds 2, 3 and 4 were investigated by elemental analysis, NMR, EI-MS and 3 was also characterized by single crystal X-ray structural analysis.

Original language	English
Pages (from-to)	2740-2742
Number of pages	3
Journal	Zeitschrift fur Anorganische und Allgemeine Chemie
Volume	634
Issue number	15
DOIs	https://doi.org/10.1002/zaac.200800030
Publication status	Published - Dec 2008
Externally published	Yes

Keywords

Aluminum
Disulfides
Germanium
Heterobimetallic compounds

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10.1002/zaac.200800030

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title = "Synthesis and characterization of heterobimetallic aluminum-germanium(IV) disulfides",

abstract = "Three heterobimetallic aluminum-germanium(IV) disulfides are synthesized. The reaction of {LAl[(SLi)2(THF)2]}2 (1) (L = HC(CMeNAr)2, Ar = 2,6-iPr2C6H3) with Ph2GeCl2, Me2GeCl2, and GeCl 4, respectively, in THF afforded LAl(μ-S)2GePh 2 (2), LAl(μ-S)2GeMe2 (3) and LAl(μ-S)2Ge(μ-S)2AlL (4) in good yields. Compounds 2, 3 and 4 were investigated by elemental analysis, NMR, EI-MS and 3 was also characterized by single crystal X-ray structural analysis.",

keywords = "Aluminum, Disulfides, Germanium, Heterobimetallic compounds",

author = "Zhi Yang and Xiaoli Ma and Zhensheng Zhang and Roesky, {Herbert W.} and J{\"o}rg Magull and Arne Ringe",

year = "2008",

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doi = "10.1002/zaac.200800030",

language = "English",

volume = "634",

pages = "2740--2742",

journal = "Zeitschrift fur Anorganische und Allgemeine Chemie",

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TY - JOUR

T1 - Synthesis and characterization of heterobimetallic aluminum-germanium(IV) disulfides

AU - Yang, Zhi

AU - Ma, Xiaoli

AU - Zhang, Zhensheng

AU - Roesky, Herbert W.

AU - Magull, Jörg

AU - Ringe, Arne

PY - 2008/12

Y1 - 2008/12

N2 - Three heterobimetallic aluminum-germanium(IV) disulfides are synthesized. The reaction of {LAl[(SLi)2(THF)2]}2 (1) (L = HC(CMeNAr)2, Ar = 2,6-iPr2C6H3) with Ph2GeCl2, Me2GeCl2, and GeCl 4, respectively, in THF afforded LAl(μ-S)2GePh 2 (2), LAl(μ-S)2GeMe2 (3) and LAl(μ-S)2Ge(μ-S)2AlL (4) in good yields. Compounds 2, 3 and 4 were investigated by elemental analysis, NMR, EI-MS and 3 was also characterized by single crystal X-ray structural analysis.

AB - Three heterobimetallic aluminum-germanium(IV) disulfides are synthesized. The reaction of {LAl[(SLi)2(THF)2]}2 (1) (L = HC(CMeNAr)2, Ar = 2,6-iPr2C6H3) with Ph2GeCl2, Me2GeCl2, and GeCl 4, respectively, in THF afforded LAl(μ-S)2GePh 2 (2), LAl(μ-S)2GeMe2 (3) and LAl(μ-S)2Ge(μ-S)2AlL (4) in good yields. Compounds 2, 3 and 4 were investigated by elemental analysis, NMR, EI-MS and 3 was also characterized by single crystal X-ray structural analysis.

KW - Aluminum

KW - Disulfides

KW - Germanium

KW - Heterobimetallic compounds

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U2 - 10.1002/zaac.200800030

DO - 10.1002/zaac.200800030

M3 - Article

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VL - 634

SP - 2740

EP - 2742

JO - Zeitschrift fur Anorganische und Allgemeine Chemie

JF - Zeitschrift fur Anorganische und Allgemeine Chemie

IS - 15

ER -

Synthesis and characterization of heterobimetallic aluminum-germanium(IV) disulfides

Abstract

Keywords

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