Synthesis and characterization of Ga2(phen)(HPO4 )3: A new 2D hybrid gallium phosphate with neutral framework

Zhi En Lin; Jie Zhang; Shou Tian Zheng; Guo Yu Yang

doi:10.1016/j.micromeso.2004.04.016

Synthesis and characterization of Ga₂(phen)(HPO₄ )₃: A new 2D hybrid gallium phosphate with neutral framework

Zhi En Lin, Jie Zhang, Shou Tian Zheng, Guo Yu Yang^*

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

A new layered inorganic-organic hybrid gallium phosphate, Ga₂ (phen)(HPO₄)₃ (phen=1,10-phenanthroline), has been hydrothermally synthesized and characterized by single crystal X-ray diffraction, FTIR, elemental analysis, ICP, power X-ray diffraction and thermogravimetric analysis. This compound crystallizes in the triclinic system, space group P-1 (No. 2), a=7.7730(6) Å, b=11.7968(10) Å, c=12.1458(9) Å, α=114.089(2)°, β=102.310(2) °, γ=102.905(2)°, V=931.28(13) Å³, Z=2. The structure is built from strictly alternating GaO₄N₂ octahedra, GaO₄ tetrahedra and HPO₄ tetrahedra through their vertices, forming a neutral layered architecture grafted with phen ligands. The adjacent sheets are stacked in an AAAA sequence along [0 0 1] direction and held together by strong π-π interactions.

Original language	English
Pages (from-to)	43-47
Number of pages	5
Journal	Microporous and Mesoporous Materials
Volume	72
Issue number	1-3
DOIs	https://doi.org/10.1016/j.micromeso.2004.04.016
Publication status	Published - 8 Jul 2004
Externally published	Yes

Keywords

Crystal structure
Gallium phosphate
Hybrid solid
Hydrothermal synthesis
Layer

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10.1016/j.micromeso.2004.04.016

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title = "Synthesis and characterization of Ga2(phen)(HPO4 )3: A new 2D hybrid gallium phosphate with neutral framework",

abstract = "A new layered inorganic-organic hybrid gallium phosphate, Ga2 (phen)(HPO4)3 (phen=1,10-phenanthroline), has been hydrothermally synthesized and characterized by single crystal X-ray diffraction, FTIR, elemental analysis, ICP, power X-ray diffraction and thermogravimetric analysis. This compound crystallizes in the triclinic system, space group P-1 (No. 2), a=7.7730(6) {\AA}, b=11.7968(10) {\AA}, c=12.1458(9) {\AA}, α=114.089(2)°, β=102.310(2) °, γ=102.905(2)°, V=931.28(13) {\AA}3, Z=2. The structure is built from strictly alternating GaO4N2 octahedra, GaO4 tetrahedra and HPO4 tetrahedra through their vertices, forming a neutral layered architecture grafted with phen ligands. The adjacent sheets are stacked in an AAAA sequence along [0 0 1] direction and held together by strong π-π interactions.",

keywords = "Crystal structure, Gallium phosphate, Hybrid solid, Hydrothermal synthesis, Layer",

author = "Lin, {Zhi En} and Jie Zhang and Zheng, {Shou Tian} and Yang, {Guo Yu}",

year = "2004",

month = jul,

day = "8",

doi = "10.1016/j.micromeso.2004.04.016",

language = "English",

volume = "72",

pages = "43--47",

journal = "Microporous and Mesoporous Materials",

issn = "1387-1811",

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number = "1-3",

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TY - JOUR

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T2 - A new 2D hybrid gallium phosphate with neutral framework

AU - Lin, Zhi En

AU - Zhang, Jie

AU - Zheng, Shou Tian

AU - Yang, Guo Yu

PY - 2004/7/8

Y1 - 2004/7/8

N2 - A new layered inorganic-organic hybrid gallium phosphate, Ga2 (phen)(HPO4)3 (phen=1,10-phenanthroline), has been hydrothermally synthesized and characterized by single crystal X-ray diffraction, FTIR, elemental analysis, ICP, power X-ray diffraction and thermogravimetric analysis. This compound crystallizes in the triclinic system, space group P-1 (No. 2), a=7.7730(6) Å, b=11.7968(10) Å, c=12.1458(9) Å, α=114.089(2)°, β=102.310(2) °, γ=102.905(2)°, V=931.28(13) Å3, Z=2. The structure is built from strictly alternating GaO4N2 octahedra, GaO4 tetrahedra and HPO4 tetrahedra through their vertices, forming a neutral layered architecture grafted with phen ligands. The adjacent sheets are stacked in an AAAA sequence along [0 0 1] direction and held together by strong π-π interactions.

AB - A new layered inorganic-organic hybrid gallium phosphate, Ga2 (phen)(HPO4)3 (phen=1,10-phenanthroline), has been hydrothermally synthesized and characterized by single crystal X-ray diffraction, FTIR, elemental analysis, ICP, power X-ray diffraction and thermogravimetric analysis. This compound crystallizes in the triclinic system, space group P-1 (No. 2), a=7.7730(6) Å, b=11.7968(10) Å, c=12.1458(9) Å, α=114.089(2)°, β=102.310(2) °, γ=102.905(2)°, V=931.28(13) Å3, Z=2. The structure is built from strictly alternating GaO4N2 octahedra, GaO4 tetrahedra and HPO4 tetrahedra through their vertices, forming a neutral layered architecture grafted with phen ligands. The adjacent sheets are stacked in an AAAA sequence along [0 0 1] direction and held together by strong π-π interactions.

KW - Crystal structure

KW - Gallium phosphate

KW - Hybrid solid

KW - Hydrothermal synthesis

KW - Layer

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SN - 1387-1811

VL - 72

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EP - 47

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JF - Microporous and Mesoporous Materials

IS - 1-3

ER -

Synthesis and characterization of Ga₂(phen)(HPO₄ )₃: A new 2D hybrid gallium phosphate with neutral framework

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Keywords

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