Synthesis and characterization of gallium(III) and germanium(II) chlorides bearing the C6F5-substituted β-diketiminate HC[(CMe)(NC6F5)]2 ligand

Zhi Yang; Xiaoli Ma; Herbert W. Roesky; Ying Yang; Hongping Zhu; Jörg Magull; Arne Ringe

doi:10.1002/zaac.200800087

Synthesis and characterization of gallium(III) and germanium(II) chlorides bearing the C₆F₅-substituted β-diketiminate HC[(CMe)(NC₆F₅)]₂ ligand

Zhi Yang, Xiaoli Ma, Herbert W. Roesky, Ying Yang, Hongping Zhu, Jörg Magull, Arne Ringe

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

The germanium(II) and gallium(III) organochlorides containing the C ₆F₅-substituted β-diketiminate ligand LGeCl (2) and LGaCl₂ (3) (L = HC[(CMe)(NC₆F₅)]₂) were synthesized. Salt elimination reactions of the C₆F ₅-substituted β-diketiminato lithium salt with the corresponding germanium(II) and gallium(III) chlorides led to the organochlorides respectively. Compounds 2 and 3 were characterized by spectroscopic and elemental analyses, and 2 was further investigated by single crystal X-ray structural analysis.

Original language	English
Pages (from-to)	1490-1492
Number of pages	3
Journal	Zeitschrift fur Anorganische und Allgemeine Chemie
Volume	634
Issue number	9
DOIs	https://doi.org/10.1002/zaac.200800087
Publication status	Published - Aug 2008
Externally published	Yes

Keywords

CF-substituted
Gallium
Germanium
β-Diketiminate ligand

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10.1002/zaac.200800087

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title = "Synthesis and characterization of gallium(III) and germanium(II) chlorides bearing the C6F5-substituted β-diketiminate HC[(CMe)(NC6F5)]2 ligand",

abstract = "The germanium(II) and gallium(III) organochlorides containing the C 6F5-substituted β-diketiminate ligand LGeCl (2) and LGaCl2 (3) (L = HC[(CMe)(NC6F5)]2) were synthesized. Salt elimination reactions of the C6F 5-substituted β-diketiminato lithium salt with the corresponding germanium(II) and gallium(III) chlorides led to the organochlorides respectively. Compounds 2 and 3 were characterized by spectroscopic and elemental analyses, and 2 was further investigated by single crystal X-ray structural analysis.",

keywords = "CF-substituted, Gallium, Germanium, β-Diketiminate ligand",

author = "Zhi Yang and Xiaoli Ma and Roesky, {Herbert W.} and Ying Yang and Hongping Zhu and J{\"o}rg Magull and Arne Ringe",

year = "2008",

month = aug,

doi = "10.1002/zaac.200800087",

language = "English",

volume = "634",

pages = "1490--1492",

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TY - JOUR

T1 - Synthesis and characterization of gallium(III) and germanium(II) chlorides bearing the C6F5-substituted β-diketiminate HC[(CMe)(NC6F5)]2 ligand

AU - Yang, Zhi

AU - Ma, Xiaoli

AU - Roesky, Herbert W.

AU - Yang, Ying

AU - Zhu, Hongping

AU - Magull, Jörg

AU - Ringe, Arne

PY - 2008/8

Y1 - 2008/8

N2 - The germanium(II) and gallium(III) organochlorides containing the C 6F5-substituted β-diketiminate ligand LGeCl (2) and LGaCl2 (3) (L = HC[(CMe)(NC6F5)]2) were synthesized. Salt elimination reactions of the C6F 5-substituted β-diketiminato lithium salt with the corresponding germanium(II) and gallium(III) chlorides led to the organochlorides respectively. Compounds 2 and 3 were characterized by spectroscopic and elemental analyses, and 2 was further investigated by single crystal X-ray structural analysis.

AB - The germanium(II) and gallium(III) organochlorides containing the C 6F5-substituted β-diketiminate ligand LGeCl (2) and LGaCl2 (3) (L = HC[(CMe)(NC6F5)]2) were synthesized. Salt elimination reactions of the C6F 5-substituted β-diketiminato lithium salt with the corresponding germanium(II) and gallium(III) chlorides led to the organochlorides respectively. Compounds 2 and 3 were characterized by spectroscopic and elemental analyses, and 2 was further investigated by single crystal X-ray structural analysis.

KW - CF-substituted

KW - Gallium

KW - Germanium

KW - β-Diketiminate ligand

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DO - 10.1002/zaac.200800087

M3 - Article

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VL - 634

SP - 1490

EP - 1492

JO - Zeitschrift fur Anorganische und Allgemeine Chemie

JF - Zeitschrift fur Anorganische und Allgemeine Chemie

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Synthesis and characterization of gallium(III) and germanium(II) chlorides bearing the C₆F₅-substituted β-diketiminate HC[(CMe)(NC₆F₅)]₂ ligand

Abstract

Keywords

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