Synthesis and characterization of aluminum-containing tin(IV) heterobimetallic sulfides

Zhi Yang; Xiaoli Ma; Vojtech Jancik; Zhensheng Zhang; Herbert W. Roesky; Jörg Magull; Mathias Noltemeyer; Hans Georg Schmidt; Raymundo Cea-Olivares; Rubén A. Toscano

doi:10.1021/ic052139m

Synthesis and characterization of aluminum-containing tin(IV) heterobimetallic sulfides

Zhi Yang, Xiaoli Ma, Vojtech Jancik, Zhensheng Zhang, Herbert W. Roesky^*, Jörg Magull, Mathias Noltemeyer, Hans Georg Schmidt, Raymundo Cea-Olivares, Rubén A. Toscano

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

Three novel aluminum-containing tin(IV) heterobimetallic sulfides are reported. The reaction of [LAl(SLi)₂(THF)₂]₂ (1) [L = HC(CMeNAr)₂, Ar = 2,6-iPr₂C₆H ₃] with Ph₂SnCl₂, Me₂SnCl ₂, and SnCl₄ in THF respectively afforded LAl(μ-S) ₂SnPh₂ (2), LAl(μ-S)₂SnMe₂ (3), and LAl(μ-S)₂Sn(μ-S)₂AIL (4) in moderate yields. Compounds 2, 3, and 4 were characterized by elemental analysis, NMR, electron-impact mass spectrometry, and single-crystal X-ray structural analysis.

Original language	English
Pages (from-to)	3312-3315
Number of pages	4
Journal	Inorganic Chemistry
Volume	45
Issue number	8
DOIs	https://doi.org/10.1021/ic052139m
Publication status	Published - 17 Apr 2006
Externally published	Yes

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@article{d043da7659a441b8b001375aec8359fc,

title = "Synthesis and characterization of aluminum-containing tin(IV) heterobimetallic sulfides",

abstract = "Three novel aluminum-containing tin(IV) heterobimetallic sulfides are reported. The reaction of [LAl(SLi)2(THF)2]2 (1) [L = HC(CMeNAr)2, Ar = 2,6-iPr2C6H 3] with Ph2SnCl2, Me2SnCl 2, and SnCl4 in THF respectively afforded LAl(μ-S) 2SnPh2 (2), LAl(μ-S)2SnMe2 (3), and LAl(μ-S)2Sn(μ-S)2AIL (4) in moderate yields. Compounds 2, 3, and 4 were characterized by elemental analysis, NMR, electron-impact mass spectrometry, and single-crystal X-ray structural analysis.",

author = "Zhi Yang and Xiaoli Ma and Vojtech Jancik and Zhensheng Zhang and Roesky, {Herbert W.} and J{\"o}rg Magull and Mathias Noltemeyer and Schmidt, {Hans Georg} and Raymundo Cea-Olivares and Toscano, {Rub{\'e}n A.}",

year = "2006",

month = apr,

day = "17",

doi = "10.1021/ic052139m",

language = "English",

volume = "45",

pages = "3312--3315",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

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TY - JOUR

T1 - Synthesis and characterization of aluminum-containing tin(IV) heterobimetallic sulfides

AU - Yang, Zhi

AU - Ma, Xiaoli

AU - Jancik, Vojtech

AU - Zhang, Zhensheng

AU - Roesky, Herbert W.

AU - Magull, Jörg

AU - Noltemeyer, Mathias

AU - Schmidt, Hans Georg

AU - Cea-Olivares, Raymundo

AU - Toscano, Rubén A.

PY - 2006/4/17

Y1 - 2006/4/17

N2 - Three novel aluminum-containing tin(IV) heterobimetallic sulfides are reported. The reaction of [LAl(SLi)2(THF)2]2 (1) [L = HC(CMeNAr)2, Ar = 2,6-iPr2C6H 3] with Ph2SnCl2, Me2SnCl 2, and SnCl4 in THF respectively afforded LAl(μ-S) 2SnPh2 (2), LAl(μ-S)2SnMe2 (3), and LAl(μ-S)2Sn(μ-S)2AIL (4) in moderate yields. Compounds 2, 3, and 4 were characterized by elemental analysis, NMR, electron-impact mass spectrometry, and single-crystal X-ray structural analysis.

AB - Three novel aluminum-containing tin(IV) heterobimetallic sulfides are reported. The reaction of [LAl(SLi)2(THF)2]2 (1) [L = HC(CMeNAr)2, Ar = 2,6-iPr2C6H 3] with Ph2SnCl2, Me2SnCl 2, and SnCl4 in THF respectively afforded LAl(μ-S) 2SnPh2 (2), LAl(μ-S)2SnMe2 (3), and LAl(μ-S)2Sn(μ-S)2AIL (4) in moderate yields. Compounds 2, 3, and 4 were characterized by elemental analysis, NMR, electron-impact mass spectrometry, and single-crystal X-ray structural analysis.

UR - http://www.scopus.com/inward/record.url?scp=33646391527&partnerID=8YFLogxK

U2 - 10.1021/ic052139m

DO - 10.1021/ic052139m

M3 - Article

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SN - 0020-1669

VL - 45

SP - 3312

EP - 3315

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 8

ER -

Synthesis and characterization of aluminum-containing tin(IV) heterobimetallic sulfides

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