Synthesis and characterization of a novel organic-inorganic hybrid compound [Ni(DMF)6]3 [PMo12O40]2

Yun Gong; Chang Wen Hu; Hui Li; Yang Guang Li; Yong Hui Wang

Synthesis and characterization of a novel organic-inorganic hybrid compound [Ni(DMF)₆]₃ [PMo₁₂O₄₀]₂

Yun Gong^*, Chang Wen Hu, Hui Li, Yang Guang Li, Yong Hui Wang

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

Abstract

The title compound [Ni(DMF)₆]₃ [PMo₁₂O₄₀]₂(DMF=N, N'-dimethyllformamide) was synthesized and structurally characterized by elemental analysis, IR, UV and single crystal X-ray diffraction. It crystallized in the trigonal system, space group R-3, a=1.5917(2) nm, b=1.5917(2) nm, c=3.2269(7) nm, α=90.00°, β=90.00°, γ=120.00°, V=7.080(2) nm³, Z=3 and R₁=0.0837. It consists of two Keggin polyoxometalates [PMo₁₂O₄₀]^3- linked together with three [Ni(DMF)₆]²⁺ cations through hydrogen bonding interaction.

Original language	English
Pages (from-to)	348-351
Number of pages	4
Journal	Journal of Beijing Institute of Technology (English Edition)
Volume	15
Issue number	3
Publication status	Published - Sept 2006

Keywords

Crystal structure
Keggin
Nickel
Polyoxometalates
Synthesis

Cite this

@article{6710268526394516950df30f23fa1c05,

title = "Synthesis and characterization of a novel organic-inorganic hybrid compound [Ni(DMF)6]3 [PMo12O40]2",

abstract = "The title compound [Ni(DMF)6]3 [PMo12O40]2(DMF=N, N'-dimethyllformamide) was synthesized and structurally characterized by elemental analysis, IR, UV and single crystal X-ray diffraction. It crystallized in the trigonal system, space group R-3, a=1.5917(2) nm, b=1.5917(2) nm, c=3.2269(7) nm, α=90.00°, β=90.00°, γ=120.00°, V=7.080(2) nm3, Z=3 and R1=0.0837. It consists of two Keggin polyoxometalates [PMo12O40]3- linked together with three [Ni(DMF)6]2+ cations through hydrogen bonding interaction.",

keywords = "Crystal structure, Keggin, Nickel, Polyoxometalates, Synthesis",

author = "Yun Gong and Hu, {Chang Wen} and Hui Li and Li, {Yang Guang} and Wang, {Yong Hui}",

year = "2006",

month = sep,

language = "English",

volume = "15",

pages = "348--351",

journal = "Journal of Beijing Institute of Technology (English Edition)",

issn = "1004-0579",

publisher = "Beijing Institute of Technology",

number = "3",

}

TY - JOUR

T1 - Synthesis and characterization of a novel organic-inorganic hybrid compound [Ni(DMF)6]3 [PMo12O40]2

AU - Gong, Yun

AU - Hu, Chang Wen

AU - Li, Hui

AU - Li, Yang Guang

AU - Wang, Yong Hui

PY - 2006/9

Y1 - 2006/9

N2 - The title compound [Ni(DMF)6]3 [PMo12O40]2(DMF=N, N'-dimethyllformamide) was synthesized and structurally characterized by elemental analysis, IR, UV and single crystal X-ray diffraction. It crystallized in the trigonal system, space group R-3, a=1.5917(2) nm, b=1.5917(2) nm, c=3.2269(7) nm, α=90.00°, β=90.00°, γ=120.00°, V=7.080(2) nm3, Z=3 and R1=0.0837. It consists of two Keggin polyoxometalates [PMo12O40]3- linked together with three [Ni(DMF)6]2+ cations through hydrogen bonding interaction.

AB - The title compound [Ni(DMF)6]3 [PMo12O40]2(DMF=N, N'-dimethyllformamide) was synthesized and structurally characterized by elemental analysis, IR, UV and single crystal X-ray diffraction. It crystallized in the trigonal system, space group R-3, a=1.5917(2) nm, b=1.5917(2) nm, c=3.2269(7) nm, α=90.00°, β=90.00°, γ=120.00°, V=7.080(2) nm3, Z=3 and R1=0.0837. It consists of two Keggin polyoxometalates [PMo12O40]3- linked together with three [Ni(DMF)6]2+ cations through hydrogen bonding interaction.

KW - Crystal structure

KW - Keggin

KW - Nickel

KW - Polyoxometalates

KW - Synthesis

UR - http://www.scopus.com/inward/record.url?scp=33751563543&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:33751563543

SN - 1004-0579

VL - 15

SP - 348

EP - 351

JO - Journal of Beijing Institute of Technology (English Edition)

JF - Journal of Beijing Institute of Technology (English Edition)

IS - 3

ER -

Synthesis and characterization of a novel organic-inorganic hybrid compound [Ni(DMF)₆]₃ [PMo₁₂O₄₀]₂

Abstract

Keywords

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