Abstract
The title compound [Ni(DMF)6]3 [PMo12O40]2(DMF=N, N'-dimethyllformamide) was synthesized and structurally characterized by elemental analysis, IR, UV and single crystal X-ray diffraction. It crystallized in the trigonal system, space group R-3, a=1.5917(2) nm, b=1.5917(2) nm, c=3.2269(7) nm, α=90.00°, β=90.00°, γ=120.00°, V=7.080(2) nm3, Z=3 and R1=0.0837. It consists of two Keggin polyoxometalates [PMo12O40]3- linked together with three [Ni(DMF)6]2+ cations through hydrogen bonding interaction.
Original language | English |
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Pages (from-to) | 348-351 |
Number of pages | 4 |
Journal | Journal of Beijing Institute of Technology (English Edition) |
Volume | 15 |
Issue number | 3 |
Publication status | Published - Sept 2006 |
Keywords
- Crystal structure
- Keggin
- Nickel
- Polyoxometalates
- Synthesis
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Gong, Y., Hu, C. W., Li, H., Li, Y. G., & Wang, Y. H. (2006). Synthesis and characterization of a novel organic-inorganic hybrid compound [Ni(DMF)6]3 [PMo12O40]2. Journal of Beijing Institute of Technology (English Edition), 15(3), 348-351.