Synthesis and characterization of a new layered lead borate

Guo Ming Wang; Yan Qiong Sun; Guo Yu Yang

doi:10.1016/j.jssc.2005.10.034

Synthesis and characterization of a new layered lead borate

Guo Ming Wang, Yan Qiong Sun, Guo Yu Yang^*

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

25 Citations (Scopus)

Abstract

A new lead borate, Pb[B₈O₁₁(OH)₄], has been hydrothermally synthesized and structurally characterized by single crystal X-ray diffraction, FTIR, powder X-ray diffraction and thermogravimetric analysis. The compound crystallizes in the monoclinic system, space group P2₁/n (No. 14), a=7.9081(2)Å, b=14.0248(3)Å, c=9.9910(3)Å, β=90.327(2)°, V=1108.08(5)Å3, and Z=4. The structure consists of layers of 9-membered borate rings enclosing Pb ²⁺ cations. Adjacent borate layers are interconnected via ionic Pb-O bonds and hydrogen bonding to form a 3D supramolecular network.

Original language	English
Pages (from-to)	398-403
Number of pages	6
Journal	Journal of Solid State Chemistry
Volume	179
Issue number	2
DOIs	https://doi.org/10.1016/j.jssc.2005.10.034
Publication status	Published - Feb 2006
Externally published	Yes

Keywords

Borates
Crystal structure
Hydrothermal synthesis
Lead borate

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10.1016/j.jssc.2005.10.034

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title = "Synthesis and characterization of a new layered lead borate",

abstract = "A new lead borate, Pb[B8O11(OH)4], has been hydrothermally synthesized and structurally characterized by single crystal X-ray diffraction, FTIR, powder X-ray diffraction and thermogravimetric analysis. The compound crystallizes in the monoclinic system, space group P21/n (No. 14), a=7.9081(2){\AA}, b=14.0248(3){\AA}, c=9.9910(3){\AA}, β=90.327(2)°, V=1108.08(5){\AA}3, and Z=4. The structure consists of layers of 9-membered borate rings enclosing Pb 2+ cations. Adjacent borate layers are interconnected via ionic Pb-O bonds and hydrogen bonding to form a 3D supramolecular network.",

keywords = "Borates, Crystal structure, Hydrothermal synthesis, Lead borate",

author = "Wang, {Guo Ming} and Sun, {Yan Qiong} and Yang, {Guo Yu}",

year = "2006",

month = feb,

doi = "10.1016/j.jssc.2005.10.034",

language = "English",

volume = "179",

pages = "398--403",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

publisher = "Academic Press Inc.",

number = "2",

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TY - JOUR

T1 - Synthesis and characterization of a new layered lead borate

AU - Wang, Guo Ming

AU - Sun, Yan Qiong

AU - Yang, Guo Yu

PY - 2006/2

Y1 - 2006/2

N2 - A new lead borate, Pb[B8O11(OH)4], has been hydrothermally synthesized and structurally characterized by single crystal X-ray diffraction, FTIR, powder X-ray diffraction and thermogravimetric analysis. The compound crystallizes in the monoclinic system, space group P21/n (No. 14), a=7.9081(2)Å, b=14.0248(3)Å, c=9.9910(3)Å, β=90.327(2)°, V=1108.08(5)Å3, and Z=4. The structure consists of layers of 9-membered borate rings enclosing Pb 2+ cations. Adjacent borate layers are interconnected via ionic Pb-O bonds and hydrogen bonding to form a 3D supramolecular network.

AB - A new lead borate, Pb[B8O11(OH)4], has been hydrothermally synthesized and structurally characterized by single crystal X-ray diffraction, FTIR, powder X-ray diffraction and thermogravimetric analysis. The compound crystallizes in the monoclinic system, space group P21/n (No. 14), a=7.9081(2)Å, b=14.0248(3)Å, c=9.9910(3)Å, β=90.327(2)°, V=1108.08(5)Å3, and Z=4. The structure consists of layers of 9-membered borate rings enclosing Pb 2+ cations. Adjacent borate layers are interconnected via ionic Pb-O bonds and hydrogen bonding to form a 3D supramolecular network.

KW - Borates

KW - Crystal structure

KW - Hydrothermal synthesis

KW - Lead borate

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U2 - 10.1016/j.jssc.2005.10.034

DO - 10.1016/j.jssc.2005.10.034

M3 - Article

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SN - 0022-4596

VL - 179

SP - 398

EP - 403

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

IS - 2

ER -

Synthesis and characterization of a new layered lead borate

Abstract

Keywords

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