Synthesis and characterization of a new double-cubane Mo-Fe-S cluster compound, [NEt4]3[Mo2Fe6S 8(μ-OMe)3(SPh)3Cl3]

Ji Qing Xu; Xun Gao Zhang; Hui Cai; Ning Hai Hu; Hang Ping Wei; Guo Yu Yang; Tie Gang Wang

doi:10.1039/CC9960000757

Synthesis and characterization of a new double-cubane Mo-Fe-S cluster compound, [NEt₄]₃[Mo₂Fe₆S ₈(μ-OMe)₃(SPh)₃Cl₃]

Ji Qing Xu^*, Xun Gao Zhang, Hui Cai, Ning Hai Hu, Hang Ping Wei, Guo Yu Yang, Tie Gang Wang

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

The new double-cubane cluster compound [NEt₄]₃[Mo₂Fe₆S ₈(μ-OMe)₃(SPh)₃Cl₃] is synthesized from (NH₄)₂MoS₄, FeCl₃, Fe powder, S powder, NaSPh and NEt₄Br in MeOH-DMF, its crystal structure is determined by X-ray crystallography, and results of XPS indicate a valence state of +4 for Mo.

Original language	English
Pages (from-to)	757-758
Number of pages	2
Journal	Chemical Communications
Issue number	6
DOIs	https://doi.org/10.1039/CC9960000757
Publication status	Published - 1996
Externally published	Yes

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Xu, J. Q., Zhang, X. G., Cai, H., Hu, N. H., Wei, H. P., Yang, G. Y., & Wang, T. G. (1996). Synthesis and characterization of a new double-cubane Mo-Fe-S cluster compound, [NEt₄]₃[Mo₂Fe₆S ₈(μ-OMe)₃(SPh)₃Cl₃]. Chemical Communications, (6), 757-758. https://doi.org/10.1039/CC9960000757

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title = "Synthesis and characterization of a new double-cubane Mo-Fe-S cluster compound, [NEt4]3[Mo2Fe6S 8(μ-OMe)3(SPh)3Cl3]",

abstract = "The new double-cubane cluster compound [NEt4]3[Mo2Fe6S 8(μ-OMe)3(SPh)3Cl3] is synthesized from (NH4)2MoS4, FeCl3, Fe powder, S powder, NaSPh and NEt4Br in MeOH-DMF, its crystal structure is determined by X-ray crystallography, and results of XPS indicate a valence state of +4 for Mo.",

author = "Xu, {Ji Qing} and Zhang, {Xun Gao} and Hui Cai and Hu, {Ning Hai} and Wei, {Hang Ping} and Yang, {Guo Yu} and Wang, {Tie Gang}",

year = "1996",

doi = "10.1039/CC9960000757",

language = "English",

pages = "757--758",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "6",

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T1 - Synthesis and characterization of a new double-cubane Mo-Fe-S cluster compound, [NEt4]3[Mo2Fe6S 8(μ-OMe)3(SPh)3Cl3]

AU - Xu, Ji Qing

AU - Zhang, Xun Gao

AU - Cai, Hui

AU - Hu, Ning Hai

AU - Wei, Hang Ping

AU - Yang, Guo Yu

AU - Wang, Tie Gang

PY - 1996

Y1 - 1996

N2 - The new double-cubane cluster compound [NEt4]3[Mo2Fe6S 8(μ-OMe)3(SPh)3Cl3] is synthesized from (NH4)2MoS4, FeCl3, Fe powder, S powder, NaSPh and NEt4Br in MeOH-DMF, its crystal structure is determined by X-ray crystallography, and results of XPS indicate a valence state of +4 for Mo.

AB - The new double-cubane cluster compound [NEt4]3[Mo2Fe6S 8(μ-OMe)3(SPh)3Cl3] is synthesized from (NH4)2MoS4, FeCl3, Fe powder, S powder, NaSPh and NEt4Br in MeOH-DMF, its crystal structure is determined by X-ray crystallography, and results of XPS indicate a valence state of +4 for Mo.

UR - http://www.scopus.com/inward/record.url?scp=0041091212&partnerID=8YFLogxK

U2 - 10.1039/CC9960000757

DO - 10.1039/CC9960000757

M3 - Article

AN - SCOPUS:0041091212

SN - 1359-7345

SP - 757

EP - 758

JO - Chemical Communications

JF - Chemical Communications

IS - 6

ER -

Synthesis and characterization of a new double-cubane Mo-Fe-S cluster compound, [NEt₄]₃[Mo₂Fe₆S ₈(μ-OMe)₃(SPh)₃Cl₃]

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