Study on the hydrolysis of TADFIW under alkaline condition by online infrared

Sui Zhou Sun*, Shao Hua Jin, Li Jie Li, Shu Sen Chen, Tian Yu Wei, Zhi Hua Li

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

1 Citation (Scopus)

Abstract

The hydrolysis of TADFIW under alkaline condition was studied using the online infrared. The results show that the hydrolysis of the two formamides on the TADFIW's six-member ring can be easily carried out at room temperature. But the two acetamides of the TADFIW on the five-member ring almost have no reaction, even if the temperature rised to 60 °C and reaction time extended to three hours. Under the condition, through the hydrolysis of TADFIW, TAIW can be obtained, and further hydrolysis reaction can not take place, if only the reaction condition be changed.

Original languageEnglish
Pages (from-to)20-23
Number of pages4
JournalHuozhayao Xuebao/Chinese Journal of Explosives and Propellants
Volume32
Issue number6
Publication statusPublished - 2009

Keywords

  • Alkaline hydrolysis
  • Online infrared
  • Organic chemistry
  • TADFIW
  • TAIW

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