Studies on Preparation, Crystal Structure and Application of [Mn(CHZ)3](ClO4)2

Jian Guo Zhang; Tong Lai Zhang; Zhao Rong Wei; Kai Bei Yu

Studies on Preparation, Crystal Structure and Application of [Mn(CHZ)₃](ClO₄)₂

Jian Guo Zhang^*, Tong Lai Zhang, Zhao Rong Wei, Kai Bei Yu

^*Corresponding author for this work

School of Mechatronical Engineering

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

The title compound was prepared by mixing the aqueous solution of carbohydrazide and manganese perchlorate. It was characterized by X-ray diffraction. The crystal of the title compound, [Mn(CHZ)₃](ClO₄)₂, belongs to space group P2₁/n with the crystal parameters a=1. 019 7(2) nm, b= 0. 859 3(1) nm, c=2. 141 2(3) nm, β=100. 86(1)°; V=1. 842 6(5) nm3, Z=4. The results show that all carbohydrazides are coordinated as bidentate by the oxygen atom of the carbonyl group and one nitrogen atom of the end group, forming a distorted octahedron. The explosive properties of the title complex were tested, the application in the engineering detonator was investigated.

Original language	English
Pages (from-to)	897
Number of pages	1
Journal	Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities
Volume	22
Issue number	6
Publication status	Published - Jun 2001

Keywords

Carbohydrazide
Crystal structure
Explosive properties
Manganese perchlorate
Preparation

Cite this

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title = "Studies on Preparation, Crystal Structure and Application of [Mn(CHZ)3](ClO4)2",

abstract = "The title compound was prepared by mixing the aqueous solution of carbohydrazide and manganese perchlorate. It was characterized by X-ray diffraction. The crystal of the title compound, [Mn(CHZ)3](ClO4)2, belongs to space group P21/n with the crystal parameters a=1. 019 7(2) nm, b= 0. 859 3(1) nm, c=2. 141 2(3) nm, β=100. 86(1)°; V=1. 842 6(5) nm3, Z=4. The results show that all carbohydrazides are coordinated as bidentate by the oxygen atom of the carbonyl group and one nitrogen atom of the end group, forming a distorted octahedron. The explosive properties of the title complex were tested, the application in the engineering detonator was investigated.",

keywords = "Carbohydrazide, Crystal structure, Explosive properties, Manganese perchlorate, Preparation",

author = "Zhang, {Jian Guo} and Zhang, {Tong Lai} and Wei, {Zhao Rong} and Yu, {Kai Bei}",

year = "2001",

month = jun,

language = "English",

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journal = "Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities",

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TY - JOUR

T1 - Studies on Preparation, Crystal Structure and Application of [Mn(CHZ)3](ClO4)2

AU - Zhang, Jian Guo

AU - Zhang, Tong Lai

AU - Wei, Zhao Rong

AU - Yu, Kai Bei

PY - 2001/6

Y1 - 2001/6

N2 - The title compound was prepared by mixing the aqueous solution of carbohydrazide and manganese perchlorate. It was characterized by X-ray diffraction. The crystal of the title compound, [Mn(CHZ)3](ClO4)2, belongs to space group P21/n with the crystal parameters a=1. 019 7(2) nm, b= 0. 859 3(1) nm, c=2. 141 2(3) nm, β=100. 86(1)°; V=1. 842 6(5) nm3, Z=4. The results show that all carbohydrazides are coordinated as bidentate by the oxygen atom of the carbonyl group and one nitrogen atom of the end group, forming a distorted octahedron. The explosive properties of the title complex were tested, the application in the engineering detonator was investigated.

AB - The title compound was prepared by mixing the aqueous solution of carbohydrazide and manganese perchlorate. It was characterized by X-ray diffraction. The crystal of the title compound, [Mn(CHZ)3](ClO4)2, belongs to space group P21/n with the crystal parameters a=1. 019 7(2) nm, b= 0. 859 3(1) nm, c=2. 141 2(3) nm, β=100. 86(1)°; V=1. 842 6(5) nm3, Z=4. The results show that all carbohydrazides are coordinated as bidentate by the oxygen atom of the carbonyl group and one nitrogen atom of the end group, forming a distorted octahedron. The explosive properties of the title complex were tested, the application in the engineering detonator was investigated.

KW - Carbohydrazide

KW - Crystal structure

KW - Explosive properties

KW - Manganese perchlorate

KW - Preparation

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M3 - Article

AN - SCOPUS:0345858092

SN - 0251-0790

VL - 22

SP - 897

JO - Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities

JF - Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities

IS - 6

ER -

Studies on Preparation, Crystal Structure and Application of [Mn(CHZ)₃](ClO₄)₂

Abstract

Keywords

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