Structural diversity and luminescent properties of europium(III) complexes with acrylic acid ligands

Jun Yan; Yongmiao Guo; Hui Li; Xiaoping Sun; Zhen Wang

doi:10.1016/j.molstruc.2008.03.050

Structural diversity and luminescent properties of europium(III) complexes with acrylic acid ligands

Jun Yan, Yongmiao Guo, Hui Li^*, Xiaoping Sun, Zhen Wang

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

Three Europium complexes: [Eu(L¹)₃(H₂O)₂]₂ (L¹ = (E)-3-(2- hydroxyl-phenyl)-acrylic acid) (1), [[Eu(L²)₃(H₂O)]·H₂O (L² = (E)-3-(3-hydroxyl-phenyl)-acrylic acid) (2), and [[Eu(L³)₃(H₂O)₂] (L³ = (E)-3-(4-hydroxyl-phenyl)-acrylic acid) (3) were synthesized and structurally analyzed by IR, elemental analysis, and the single-crystal X-ray diffraction method. Complex 1 adopts a dinuclear structure, while complexes 2 and 3 are a one-dimensional coordination polymer. The complex 2 possesses a helical H-bonding between the adjacent two chains with homochirality in crystalline solid state. All the complexes form a 3D supramolecular framework by O-H^···O hydrogen bonding and π-π interaction in the crystal lattices. The solid photoluminescence of the three complexes has also been investigated at room temperature.

Original language	English
Pages (from-to)	298-304
Number of pages	7
Journal	Journal of Molecular Structure
Volume	891
Issue number	1-3
DOIs	https://doi.org/10.1016/j.molstruc.2008.03.050
Publication status	Published - 26 Nov 2008

Keywords

Acrylic acid
Europium complex
Hydrogen bond
Supramolecular architecture

Access to Document

10.1016/j.molstruc.2008.03.050

Cite this

@article{1e7854a1e1ff4ad8a1bc718b9d4f3f03,

title = "Structural diversity and luminescent properties of europium(III) complexes with acrylic acid ligands",

abstract = "Three Europium complexes: [Eu(L1)3(H2O)2]2 (L1 = (E)-3-(2- hydroxyl-phenyl)-acrylic acid) (1), [[Eu(L2)3(H2O)]·H2O (L2 = (E)-3-(3-hydroxyl-phenyl)-acrylic acid) (2), and [[Eu(L3)3(H2O)2] (L3 = (E)-3-(4-hydroxyl-phenyl)-acrylic acid) (3) were synthesized and structurally analyzed by IR, elemental analysis, and the single-crystal X-ray diffraction method. Complex 1 adopts a dinuclear structure, while complexes 2 and 3 are a one-dimensional coordination polymer. The complex 2 possesses a helical H-bonding between the adjacent two chains with homochirality in crystalline solid state. All the complexes form a 3D supramolecular framework by O-H···O hydrogen bonding and π-π interaction in the crystal lattices. The solid photoluminescence of the three complexes has also been investigated at room temperature.",

keywords = "Acrylic acid, Europium complex, Hydrogen bond, Supramolecular architecture",

author = "Jun Yan and Yongmiao Guo and Hui Li and Xiaoping Sun and Zhen Wang",

year = "2008",

month = nov,

day = "26",

doi = "10.1016/j.molstruc.2008.03.050",

language = "English",

volume = "891",

pages = "298--304",

journal = "Journal of Molecular Structure",

issn = "0022-2860",

publisher = "Elsevier B.V.",

number = "1-3",

}

TY - JOUR

T1 - Structural diversity and luminescent properties of europium(III) complexes with acrylic acid ligands

AU - Yan, Jun

AU - Guo, Yongmiao

AU - Li, Hui

AU - Sun, Xiaoping

AU - Wang, Zhen

PY - 2008/11/26

Y1 - 2008/11/26

N2 - Three Europium complexes: [Eu(L1)3(H2O)2]2 (L1 = (E)-3-(2- hydroxyl-phenyl)-acrylic acid) (1), [[Eu(L2)3(H2O)]·H2O (L2 = (E)-3-(3-hydroxyl-phenyl)-acrylic acid) (2), and [[Eu(L3)3(H2O)2] (L3 = (E)-3-(4-hydroxyl-phenyl)-acrylic acid) (3) were synthesized and structurally analyzed by IR, elemental analysis, and the single-crystal X-ray diffraction method. Complex 1 adopts a dinuclear structure, while complexes 2 and 3 are a one-dimensional coordination polymer. The complex 2 possesses a helical H-bonding between the adjacent two chains with homochirality in crystalline solid state. All the complexes form a 3D supramolecular framework by O-H···O hydrogen bonding and π-π interaction in the crystal lattices. The solid photoluminescence of the three complexes has also been investigated at room temperature.

AB - Three Europium complexes: [Eu(L1)3(H2O)2]2 (L1 = (E)-3-(2- hydroxyl-phenyl)-acrylic acid) (1), [[Eu(L2)3(H2O)]·H2O (L2 = (E)-3-(3-hydroxyl-phenyl)-acrylic acid) (2), and [[Eu(L3)3(H2O)2] (L3 = (E)-3-(4-hydroxyl-phenyl)-acrylic acid) (3) were synthesized and structurally analyzed by IR, elemental analysis, and the single-crystal X-ray diffraction method. Complex 1 adopts a dinuclear structure, while complexes 2 and 3 are a one-dimensional coordination polymer. The complex 2 possesses a helical H-bonding between the adjacent two chains with homochirality in crystalline solid state. All the complexes form a 3D supramolecular framework by O-H···O hydrogen bonding and π-π interaction in the crystal lattices. The solid photoluminescence of the three complexes has also been investigated at room temperature.

KW - Acrylic acid

KW - Europium complex

KW - Hydrogen bond

KW - Supramolecular architecture

UR - http://www.scopus.com/inward/record.url?scp=55249100035&partnerID=8YFLogxK

U2 - 10.1016/j.molstruc.2008.03.050

DO - 10.1016/j.molstruc.2008.03.050

M3 - Article

AN - SCOPUS:55249100035

SN - 0022-2860

VL - 891

SP - 298

EP - 304

JO - Journal of Molecular Structure

JF - Journal of Molecular Structure

IS - 1-3

ER -

Structural diversity and luminescent properties of europium(III) complexes with acrylic acid ligands

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this