Square helix versus zigzag chain of group 12 metal coordination polymers with 1,2-bis(diphenylphosphino)ethane (dppe)

Xiaoqing Liu; Yanyan Liu; Yongjing Hao; Xiao Juan Yang; Biao Wu

doi:10.1016/j.inoche.2010.01.024

Square helix versus zigzag chain of group 12 metal coordination polymers with 1,2-bis(diphenylphosphino)ethane (dppe)

Xiaoqing Liu, Yanyan Liu, Yongjing Hao, Xiao Juan Yang^*, Biao Wu

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

A novel 1D square-helical coordination polymer [ZnI₂(μ₂-dppe)]_n (1) was synthesized by the reaction of ZnI₂ with 1,2-bis(diphenylphosphino)ethane (dppe), while zigzag chains [MX₂(μ₂-dppe)]_n were obtained by using smaller anions (Cl^- and Br^-) and larger metal ions (Cd²⁺ and Hg²⁺).

Original language	English
Pages (from-to)	511-513
Number of pages	3
Journal	Inorganic Chemistry Communications
Volume	13
Issue number	4
DOIs	https://doi.org/10.1016/j.inoche.2010.01.024
Publication status	Published - Apr 2010
Externally published	Yes

Keywords

1,2-Bis(diphenylphosphino)ethane
Coordination polymers
Group 12 metals
Helix

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10.1016/j.inoche.2010.01.024

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Liu, X., Liu, Y., Hao, Y., Yang, X. J., & Wu, B. (2010). Square helix versus zigzag chain of group 12 metal coordination polymers with 1,2-bis(diphenylphosphino)ethane (dppe). Inorganic Chemistry Communications, 13(4), 511-513. https://doi.org/10.1016/j.inoche.2010.01.024

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title = "Square helix versus zigzag chain of group 12 metal coordination polymers with 1,2-bis(diphenylphosphino)ethane (dppe)",

abstract = "A novel 1D square-helical coordination polymer [ZnI2(μ2-dppe)]n (1) was synthesized by the reaction of ZnI2 with 1,2-bis(diphenylphosphino)ethane (dppe), while zigzag chains [MX2(μ2-dppe)]n were obtained by using smaller anions (Cl- and Br-) and larger metal ions (Cd2+ and Hg2+).",

keywords = "1,2-Bis(diphenylphosphino)ethane, Coordination polymers, Group 12 metals, Helix",

author = "Xiaoqing Liu and Yanyan Liu and Yongjing Hao and Yang, {Xiao Juan} and Biao Wu",

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T1 - Square helix versus zigzag chain of group 12 metal coordination polymers with 1,2-bis(diphenylphosphino)ethane (dppe)

AU - Liu, Xiaoqing

AU - Liu, Yanyan

AU - Hao, Yongjing

AU - Yang, Xiao Juan

AU - Wu, Biao

PY - 2010/4

Y1 - 2010/4

N2 - A novel 1D square-helical coordination polymer [ZnI2(μ2-dppe)]n (1) was synthesized by the reaction of ZnI2 with 1,2-bis(diphenylphosphino)ethane (dppe), while zigzag chains [MX2(μ2-dppe)]n were obtained by using smaller anions (Cl- and Br-) and larger metal ions (Cd2+ and Hg2+).

AB - A novel 1D square-helical coordination polymer [ZnI2(μ2-dppe)]n (1) was synthesized by the reaction of ZnI2 with 1,2-bis(diphenylphosphino)ethane (dppe), while zigzag chains [MX2(μ2-dppe)]n were obtained by using smaller anions (Cl- and Br-) and larger metal ions (Cd2+ and Hg2+).

KW - 1,2-Bis(diphenylphosphino)ethane

KW - Coordination polymers

KW - Group 12 metals

KW - Helix

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U2 - 10.1016/j.inoche.2010.01.024

DO - 10.1016/j.inoche.2010.01.024

M3 - Article

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SN - 1387-7003

VL - 13

SP - 511

EP - 513

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 4

ER -

Square helix versus zigzag chain of group 12 metal coordination polymers with 1,2-bis(diphenylphosphino)ethane (dppe)

Abstract

Keywords

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