Specific heat capacity of sodium salts of 2, 4, 6-trinitro-l, 3, 5-trihydroxybenzene

Ling Hui Li; Tong Lai Zhang; Jian Guo Zhang; Cui Na Sun

Specific heat capacity of sodium salts of 2, 4, 6-trinitro-l, 3, 5-trihydroxybenzene

Ling Hui Li^*, Tong Lai Zhang, Jian Guo Zhang, Cui Na Sun

^*Corresponding author for this work

School of Mechatronical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

The continuous specific heat capacities at constant pressure (C_p) of 2,4,6-trinitro-1,3,5-trihydroxybenzene (TNPG), mono-substituted sodium (Na₁TNPG), di-substituted (Na₂TNPG) and tri-substituted (Na₃TNPG) trinitrophloro-glucinate were measured by differential scanning calorimeter (DSC) method. The change of enthalpy and entropy were calculated at an interval of 5°C in the range from 50°C to 100°C. The temperature dependence of C_p were determined from the experimental values as C_p (J· g^-1·°C^-1) = a + bT + cT² + dT³ with the exception d = 0 for the substituted sodium salts of TNPG. The deviation analysis indicates that DSC method is effective and can be used to measure the specific heat capacity of other energetic materials. The correlation coefficients that are close to 1 show that the C_p values of these compounds are well-regulated.

Original language	English
Pages (from-to)	228-230
Number of pages	3
Journal	Hanneng Cailiao/Chinese Journal of Energetic Materials
Volume	15
Issue number	3
Publication status	Published - Jun 2007

Keywords

2, 4, 6-trinitro-1, 3, 5-trihydroxybenzene (TNPG)
Analytical chemistry
Differential scanning calorimeter (DSC)
Sodium salt
Specific heat capacity

Cite this

@article{e38d3effa39b48e7baf1897718420758,

title = "Specific heat capacity of sodium salts of 2, 4, 6-trinitro-l, 3, 5-trihydroxybenzene",

abstract = "The continuous specific heat capacities at constant pressure (Cp) of 2,4,6-trinitro-1,3,5-trihydroxybenzene (TNPG), mono-substituted sodium (Na1TNPG), di-substituted (Na2TNPG) and tri-substituted (Na3TNPG) trinitrophloro-glucinate were measured by differential scanning calorimeter (DSC) method. The change of enthalpy and entropy were calculated at an interval of 5°C in the range from 50°C to 100°C. The temperature dependence of Cp were determined from the experimental values as Cp (J· g-1·°C-1) = a + bT + cT2 + dT3 with the exception d = 0 for the substituted sodium salts of TNPG. The deviation analysis indicates that DSC method is effective and can be used to measure the specific heat capacity of other energetic materials. The correlation coefficients that are close to 1 show that the Cp values of these compounds are well-regulated.",

keywords = "2, 4, 6-trinitro-1, 3, 5-trihydroxybenzene (TNPG), Analytical chemistry, Differential scanning calorimeter (DSC), Sodium salt, Specific heat capacity",

author = "Li, {Ling Hui} and Zhang, {Tong Lai} and Zhang, {Jian Guo} and Sun, {Cui Na}",

year = "2007",

month = jun,

language = "English",

volume = "15",

pages = "228--230",

journal = "Hanneng Cailiao/Chinese Journal of Energetic Materials",

issn = "1006-9941",

publisher = "Institute of Chemical Materials, China Academy of Engineering Physics",

number = "3",

}

TY - JOUR

T1 - Specific heat capacity of sodium salts of 2, 4, 6-trinitro-l, 3, 5-trihydroxybenzene

AU - Li, Ling Hui

AU - Zhang, Tong Lai

AU - Zhang, Jian Guo

AU - Sun, Cui Na

PY - 2007/6

Y1 - 2007/6

N2 - The continuous specific heat capacities at constant pressure (Cp) of 2,4,6-trinitro-1,3,5-trihydroxybenzene (TNPG), mono-substituted sodium (Na1TNPG), di-substituted (Na2TNPG) and tri-substituted (Na3TNPG) trinitrophloro-glucinate were measured by differential scanning calorimeter (DSC) method. The change of enthalpy and entropy were calculated at an interval of 5°C in the range from 50°C to 100°C. The temperature dependence of Cp were determined from the experimental values as Cp (J· g-1·°C-1) = a + bT + cT2 + dT3 with the exception d = 0 for the substituted sodium salts of TNPG. The deviation analysis indicates that DSC method is effective and can be used to measure the specific heat capacity of other energetic materials. The correlation coefficients that are close to 1 show that the Cp values of these compounds are well-regulated.

AB - The continuous specific heat capacities at constant pressure (Cp) of 2,4,6-trinitro-1,3,5-trihydroxybenzene (TNPG), mono-substituted sodium (Na1TNPG), di-substituted (Na2TNPG) and tri-substituted (Na3TNPG) trinitrophloro-glucinate were measured by differential scanning calorimeter (DSC) method. The change of enthalpy and entropy were calculated at an interval of 5°C in the range from 50°C to 100°C. The temperature dependence of Cp were determined from the experimental values as Cp (J· g-1·°C-1) = a + bT + cT2 + dT3 with the exception d = 0 for the substituted sodium salts of TNPG. The deviation analysis indicates that DSC method is effective and can be used to measure the specific heat capacity of other energetic materials. The correlation coefficients that are close to 1 show that the Cp values of these compounds are well-regulated.

KW - 2, 4, 6-trinitro-1, 3, 5-trihydroxybenzene (TNPG)

KW - Analytical chemistry

KW - Differential scanning calorimeter (DSC)

KW - Sodium salt

KW - Specific heat capacity

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M3 - Article

AN - SCOPUS:34447633905

SN - 1006-9941

VL - 15

SP - 228

EP - 230

JO - Hanneng Cailiao/Chinese Journal of Energetic Materials

JF - Hanneng Cailiao/Chinese Journal of Energetic Materials

IS - 3

ER -

Specific heat capacity of sodium salts of 2, 4, 6-trinitro-l, 3, 5-trihydroxybenzene

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Keywords

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