Purity analysis method of 5,5'-bistetrazole-1,1'-dyhydroxy dihydrate

Shu Ling Xiong; Shu Sen Chen; Li Jie Li; Shao Hua Jin; Qing Hai Shu; Zong Rui Tong; Jing Lin Li

doi:10.11943/j.issn.1006-9941.2016.02.017

Purity analysis method of 5,5'-bistetrazole-1,1'-dyhydroxy dihydrate

Shu Ling Xiong, Shu Sen Chen, Li Jie Li^*, Shao Hua Jin, Qing Hai Shu, Zong Rui Tong, Jing Lin Li

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

Analysis conditions of 5,5'-bistetrazole-1,1'-dyhydroxy dehydrate (BTO) by high performance liquid chromatography (HPLC) were determined as follows: UV detection wavelength 213 nm, reversed phase column (SinoChrom ODS-BP, 4.6 mm×200 mm, 5 μm), binary mobile phase acetonitrile and water (volume ratio of 30/70) with flow rate of 1.0 mL·min^-1 at column temperature of 25℃. External standard method was used to analyze BTO standard solution. Results show that there is a good linearity between peak height(h) and concentration(c) from 0.12 mg·mL^-1 to 0.60 mg·mL^-1. The linear equation is h=573.78c-1.18 with linear correlation coefficient of 0.9998. The relative standard deviation is 0.48%-1.00% and the average recovery is 98.10%-100.64%, indicating that the method is accurate and sensitive and can be applied in the determination of BTO purity.

Original language	English
Pages (from-to)	209-212
Number of pages	4
Journal	Hanneng Cailiao/Chinese Journal of Energetic Materials
Volume	24
Issue number	2
DOIs	https://doi.org/10.11943/j.issn.1006-9941.2016.02.017
Publication status	Published - 25 Feb 2016

Keywords

5,5'-bistetrazole-1,1'-dyhydroxy dehydrate (BTO)
External standard method
High performance liquid chromatography (HPLC)
Purity analysis

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10.11943/j.issn.1006-9941.2016.02.017

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title = "Purity analysis method of 5,5'-bistetrazole-1,1'-dyhydroxy dihydrate",

abstract = "Analysis conditions of 5,5'-bistetrazole-1,1'-dyhydroxy dehydrate (BTO) by high performance liquid chromatography (HPLC) were determined as follows: UV detection wavelength 213 nm, reversed phase column (SinoChrom ODS-BP, 4.6 mm×200 mm, 5 μm), binary mobile phase acetonitrile and water (volume ratio of 30/70) with flow rate of 1.0 mL·min-1 at column temperature of 25℃. External standard method was used to analyze BTO standard solution. Results show that there is a good linearity between peak height(h) and concentration(c) from 0.12 mg·mL-1 to 0.60 mg·mL-1. The linear equation is h=573.78c-1.18 with linear correlation coefficient of 0.9998. The relative standard deviation is 0.48%-1.00% and the average recovery is 98.10%-100.64%, indicating that the method is accurate and sensitive and can be applied in the determination of BTO purity.",

keywords = "5,5'-bistetrazole-1,1'-dyhydroxy dehydrate (BTO), External standard method, High performance liquid chromatography (HPLC), Purity analysis",

author = "Xiong, {Shu Ling} and Chen, {Shu Sen} and Li, {Li Jie} and Jin, {Shao Hua} and Shu, {Qing Hai} and Tong, {Zong Rui} and Li, {Jing Lin}",

year = "2016",

month = feb,

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doi = "10.11943/j.issn.1006-9941.2016.02.017",

language = "English",

volume = "24",

pages = "209--212",

journal = "Hanneng Cailiao/Chinese Journal of Energetic Materials",

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T1 - Purity analysis method of 5,5'-bistetrazole-1,1'-dyhydroxy dihydrate

AU - Xiong, Shu Ling

AU - Chen, Shu Sen

AU - Li, Li Jie

AU - Jin, Shao Hua

AU - Shu, Qing Hai

AU - Tong, Zong Rui

AU - Li, Jing Lin

PY - 2016/2/25

Y1 - 2016/2/25

N2 - Analysis conditions of 5,5'-bistetrazole-1,1'-dyhydroxy dehydrate (BTO) by high performance liquid chromatography (HPLC) were determined as follows: UV detection wavelength 213 nm, reversed phase column (SinoChrom ODS-BP, 4.6 mm×200 mm, 5 μm), binary mobile phase acetonitrile and water (volume ratio of 30/70) with flow rate of 1.0 mL·min-1 at column temperature of 25℃. External standard method was used to analyze BTO standard solution. Results show that there is a good linearity between peak height(h) and concentration(c) from 0.12 mg·mL-1 to 0.60 mg·mL-1. The linear equation is h=573.78c-1.18 with linear correlation coefficient of 0.9998. The relative standard deviation is 0.48%-1.00% and the average recovery is 98.10%-100.64%, indicating that the method is accurate and sensitive and can be applied in the determination of BTO purity.

AB - Analysis conditions of 5,5'-bistetrazole-1,1'-dyhydroxy dehydrate (BTO) by high performance liquid chromatography (HPLC) were determined as follows: UV detection wavelength 213 nm, reversed phase column (SinoChrom ODS-BP, 4.6 mm×200 mm, 5 μm), binary mobile phase acetonitrile and water (volume ratio of 30/70) with flow rate of 1.0 mL·min-1 at column temperature of 25℃. External standard method was used to analyze BTO standard solution. Results show that there is a good linearity between peak height(h) and concentration(c) from 0.12 mg·mL-1 to 0.60 mg·mL-1. The linear equation is h=573.78c-1.18 with linear correlation coefficient of 0.9998. The relative standard deviation is 0.48%-1.00% and the average recovery is 98.10%-100.64%, indicating that the method is accurate and sensitive and can be applied in the determination of BTO purity.

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KW - External standard method

KW - High performance liquid chromatography (HPLC)

KW - Purity analysis

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Purity analysis method of 5,5'-bistetrazole-1,1'-dyhydroxy dihydrate

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