Zhang, D., Wu, Y. C., Yang, M., Liu, X., Coileáin, C., Xu, H., Abid, M., Abid, M., Wang, J. J., Shvets, I. V., Liu, H., Wang, Z., Yin, H., Liu, H., Chun, B. S., Zhang, X., & Wu, H. C. (2016). Probing thermal expansion coefficients of monolayers using surface enhanced Raman scattering. RSC Advances, 6(101), 99053-99059. https://doi.org/10.1039/c6ra20623a
Zhang, Duan ; Wu, Ye Cun ; Yang, Mei et al. / Probing thermal expansion coefficients of monolayers using surface enhanced Raman scattering. In: RSC Advances. 2016 ; Vol. 6, No. 101. pp. 99053-99059.
@article{72a05f2fce014d6780429b90479e628b,
title = "Probing thermal expansion coefficients of monolayers using surface enhanced Raman scattering",
abstract = "Monolayer transition metal dichalcogenides exhibit remarkable electronic and optical properties, making them candidates for application within flexible nano-optoelectronics, however direct experimental determination of their thermal expansion coefficients (TECs) is difficult. Here, we propose a non-destructive method to probe the TECs of monolayer materials using surface-enhanced Raman spectroscopy (SERS). A strongly coupled Ag nanoparticle over-layer is used to controllably introduce temperature dependent strain in monolayers. Changes in the first-order temperature coefficient of the Raman shift, produced by TEC mismatch, can be used to estimate relative expansion coefficient of the monolayer. As a demonstration, the linear TEC of monolayer WS2 is probed and is found to be 10.3 × 10-6 K-1, which would appear support theoretical predictions of a small TEC. This method opens a route to probe and control the TECs of monolayer materials.",
author = "Duan Zhang and Wu, {Ye Cun} and Mei Yang and Xiao Liu and Cormac Coile{\'a}in and Hongjun Xu and Mourad Abid and Mohamed Abid and Wang, {Jing Jing} and Shvets, {Igor V.} and Haonan Liu and Zhi Wang and Hongxing Yin and Huajun Liu and Chun, {Byong Sun} and Xiangdong Zhang and Wu, {Han Chun}",
note = "Publisher Copyright: {\textcopyright} 2016 The Royal Society of Chemistry.",
year = "2016",
doi = "10.1039/c6ra20623a",
language = "English",
volume = "6",
pages = "99053--99059",
journal = "RSC Advances",
issn = "2046-2069",
publisher = "Royal Society of Chemistry",
number = "101",
}
Zhang, D, Wu, YC, Yang, M, Liu, X, Coileáin, C, Xu, H, Abid, M, Abid, M, Wang, JJ, Shvets, IV, Liu, H, Wang, Z, Yin, H, Liu, H, Chun, BS, Zhang, X & Wu, HC 2016, 'Probing thermal expansion coefficients of monolayers using surface enhanced Raman scattering', RSC Advances, vol. 6, no. 101, pp. 99053-99059. https://doi.org/10.1039/c6ra20623a
Probing thermal expansion coefficients of monolayers using surface enhanced Raman scattering. / Zhang, Duan; Wu, Ye Cun; Yang, Mei et al.
In:
RSC Advances, Vol. 6, No. 101, 2016, p. 99053-99059.
Research output: Contribution to journal › Article › peer-review
TY - JOUR
T1 - Probing thermal expansion coefficients of monolayers using surface enhanced Raman scattering
AU - Zhang, Duan
AU - Wu, Ye Cun
AU - Yang, Mei
AU - Liu, Xiao
AU - Coileáin, Cormac
AU - Xu, Hongjun
AU - Abid, Mourad
AU - Abid, Mohamed
AU - Wang, Jing Jing
AU - Shvets, Igor V.
AU - Liu, Haonan
AU - Wang, Zhi
AU - Yin, Hongxing
AU - Liu, Huajun
AU - Chun, Byong Sun
AU - Zhang, Xiangdong
AU - Wu, Han Chun
N1 - Publisher Copyright:
© 2016 The Royal Society of Chemistry.
PY - 2016
Y1 - 2016
N2 - Monolayer transition metal dichalcogenides exhibit remarkable electronic and optical properties, making them candidates for application within flexible nano-optoelectronics, however direct experimental determination of their thermal expansion coefficients (TECs) is difficult. Here, we propose a non-destructive method to probe the TECs of monolayer materials using surface-enhanced Raman spectroscopy (SERS). A strongly coupled Ag nanoparticle over-layer is used to controllably introduce temperature dependent strain in monolayers. Changes in the first-order temperature coefficient of the Raman shift, produced by TEC mismatch, can be used to estimate relative expansion coefficient of the monolayer. As a demonstration, the linear TEC of monolayer WS2 is probed and is found to be 10.3 × 10-6 K-1, which would appear support theoretical predictions of a small TEC. This method opens a route to probe and control the TECs of monolayer materials.
AB - Monolayer transition metal dichalcogenides exhibit remarkable electronic and optical properties, making them candidates for application within flexible nano-optoelectronics, however direct experimental determination of their thermal expansion coefficients (TECs) is difficult. Here, we propose a non-destructive method to probe the TECs of monolayer materials using surface-enhanced Raman spectroscopy (SERS). A strongly coupled Ag nanoparticle over-layer is used to controllably introduce temperature dependent strain in monolayers. Changes in the first-order temperature coefficient of the Raman shift, produced by TEC mismatch, can be used to estimate relative expansion coefficient of the monolayer. As a demonstration, the linear TEC of monolayer WS2 is probed and is found to be 10.3 × 10-6 K-1, which would appear support theoretical predictions of a small TEC. This method opens a route to probe and control the TECs of monolayer materials.
UR - http://www.scopus.com/inward/record.url?scp=84992337682&partnerID=8YFLogxK
U2 - 10.1039/c6ra20623a
DO - 10.1039/c6ra20623a
M3 - Article
AN - SCOPUS:84992337682
SN - 2046-2069
VL - 6
SP - 99053
EP - 99059
JO - RSC Advances
JF - RSC Advances
IS - 101
ER -
Zhang D, Wu YC, Yang M, Liu X, Coileáin C, Xu H et al. Probing thermal expansion coefficients of monolayers using surface enhanced Raman scattering. RSC Advances. 2016;6(101):99053-99059. doi: 10.1039/c6ra20623a