TY - JOUR
T1 - Preparation of multi-functional type coordination compounds
T2 - spanning the quantitative restriction of oxidizing groups
AU - Wang, Tingwei
AU - Lu, Zujia
AU - Yi, Zhenxin
AU - Kuang, Baolong
AU - Bu, Shu
AU - Xie, Zhiming
AU - Zhang, Chao
AU - Li, Yan
AU - Wang, Kun
AU - Zhang, Jian Guo
N1 - Publisher Copyright:
© 2023 The Royal Society of Chemistry.
PY - 2023/1/31
Y1 - 2023/1/31
N2 - Based on the ideas of coordination and design chemistry, we propose a new strategy to break through the limitation of the number of oxidizing acid radicals in energetic coordination compounds by preparing multi-functional type energetic coordination compounds. Therefore, we creatively designed and prepared the ligand 5-amino-1-methyl-pyrazole-4-carbohydrazide (AMPZCA) and complex Cu(HAMPZCA)2(ClO4)4·2H2O (ECCs-1). As expected, the structure of ECCs-1 was a double-type ionic-salt coordination compound, which was proved by IR, EA, and single-crystal XRD. Because of the special structural combination, ECCs-1 has more ClO4−, higher OB value, and excellent detonation performance (D = 7700 m s−1, P = 27.9 GPa). In addition, ECCs-1 exhibits acceptable mechanical sensitivity due to the introduction of methyl groups in the ligand (IS = 10 J, FS = 40 N). Laser initiation and detonation initiation tests show that ECCs-1 has the potential to play a dual role as both primary and secondary explosives.
AB - Based on the ideas of coordination and design chemistry, we propose a new strategy to break through the limitation of the number of oxidizing acid radicals in energetic coordination compounds by preparing multi-functional type energetic coordination compounds. Therefore, we creatively designed and prepared the ligand 5-amino-1-methyl-pyrazole-4-carbohydrazide (AMPZCA) and complex Cu(HAMPZCA)2(ClO4)4·2H2O (ECCs-1). As expected, the structure of ECCs-1 was a double-type ionic-salt coordination compound, which was proved by IR, EA, and single-crystal XRD. Because of the special structural combination, ECCs-1 has more ClO4−, higher OB value, and excellent detonation performance (D = 7700 m s−1, P = 27.9 GPa). In addition, ECCs-1 exhibits acceptable mechanical sensitivity due to the introduction of methyl groups in the ligand (IS = 10 J, FS = 40 N). Laser initiation and detonation initiation tests show that ECCs-1 has the potential to play a dual role as both primary and secondary explosives.
UR - http://www.scopus.com/inward/record.url?scp=85148663865&partnerID=8YFLogxK
U2 - 10.1039/d2qi02679a
DO - 10.1039/d2qi02679a
M3 - Article
AN - SCOPUS:85148663865
SN - 2052-1545
VL - 10
SP - 1475
EP - 1484
JO - Inorganic Chemistry Frontiers
JF - Inorganic Chemistry Frontiers
IS - 5
ER -