Preparation of High-Energy ECPs by Retaining the Coordination Ability of Carbohydrazide Groups

Ting Wei Wang; Chao Zhang; Zu Jia Lu; Zhi Ming Xie; Bao Long Kuang; Zhen Xin Yi; Yan Li; Jian Guo Zhang

doi:10.1021/acs.langmuir.3c01193

Preparation of High-Energy ECPs by Retaining the Coordination Ability of Carbohydrazide Groups

Ting Wei Wang, Chao Zhang, Zu Jia Lu, Zhi Ming Xie, Bao Long Kuang, Zhen Xin Yi, Yan Li, Jian Guo Zhang^*

^*Corresponding author for this work

School of Mechatronical Engineering

Research output: Contribution to journal › Article › peer-review

Abstract

In order to preserve the coordinating ability of the hydrazide group, we used retrosynthetic analysis to design and synthesize ligand furan-2,5-dicarbohydrazide and its complex [Cu(FDCA)(H₂O)ClO₄]_n(ClO₄)_n·nH₂O (ECPs-1·H₂O). The structure of the product was confirmed by single-crystal X-ray diffraction, infrared spectroscopy, and elemental analysis. The solvent-free target material ECPs-1 exhibited good thermal stability, sensitivity to mechanical stimuli, and excellent explosive properties. Furthermore, it had good potential for laser ignition and comparable detonation power to LA. The simple preparation method and inexpensive starting materials enriched the research on primary explosives.

Original language	English
Pages (from-to)	9239-9245
Number of pages	7
Journal	Langmuir
Volume	39
Issue number	26
DOIs	https://doi.org/10.1021/acs.langmuir.3c01193
Publication status	Published - 4 Jul 2023

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Wang, T. W., Zhang, C., Lu, Z. J., Xie, Z. M., Kuang, B. L., Yi, Z. X., Li, Y., & Zhang, J. G. (2023). Preparation of High-Energy ECPs by Retaining the Coordination Ability of Carbohydrazide Groups. Langmuir, 39(26), 9239-9245. https://doi.org/10.1021/acs.langmuir.3c01193

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title = "Preparation of High-Energy ECPs by Retaining the Coordination Ability of Carbohydrazide Groups",

abstract = "In order to preserve the coordinating ability of the hydrazide group, we used retrosynthetic analysis to design and synthesize ligand furan-2,5-dicarbohydrazide and its complex [Cu(FDCA)(H2O)ClO4]n(ClO4)n·nH2O (ECPs-1·H2O). The structure of the product was confirmed by single-crystal X-ray diffraction, infrared spectroscopy, and elemental analysis. The solvent-free target material ECPs-1 exhibited good thermal stability, sensitivity to mechanical stimuli, and excellent explosive properties. Furthermore, it had good potential for laser ignition and comparable detonation power to LA. The simple preparation method and inexpensive starting materials enriched the research on primary explosives.",

author = "Wang, {Ting Wei} and Chao Zhang and Lu, {Zu Jia} and Xie, {Zhi Ming} and Kuang, {Bao Long} and Yi, {Zhen Xin} and Yan Li and Zhang, {Jian Guo}",

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doi = "10.1021/acs.langmuir.3c01193",

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T1 - Preparation of High-Energy ECPs by Retaining the Coordination Ability of Carbohydrazide Groups

AU - Wang, Ting Wei

AU - Zhang, Chao

AU - Lu, Zu Jia

AU - Xie, Zhi Ming

AU - Kuang, Bao Long

AU - Yi, Zhen Xin

AU - Li, Yan

AU - Zhang, Jian Guo

PY - 2023/7/4

Y1 - 2023/7/4

N2 - In order to preserve the coordinating ability of the hydrazide group, we used retrosynthetic analysis to design and synthesize ligand furan-2,5-dicarbohydrazide and its complex [Cu(FDCA)(H2O)ClO4]n(ClO4)n·nH2O (ECPs-1·H2O). The structure of the product was confirmed by single-crystal X-ray diffraction, infrared spectroscopy, and elemental analysis. The solvent-free target material ECPs-1 exhibited good thermal stability, sensitivity to mechanical stimuli, and excellent explosive properties. Furthermore, it had good potential for laser ignition and comparable detonation power to LA. The simple preparation method and inexpensive starting materials enriched the research on primary explosives.

AB - In order to preserve the coordinating ability of the hydrazide group, we used retrosynthetic analysis to design and synthesize ligand furan-2,5-dicarbohydrazide and its complex [Cu(FDCA)(H2O)ClO4]n(ClO4)n·nH2O (ECPs-1·H2O). The structure of the product was confirmed by single-crystal X-ray diffraction, infrared spectroscopy, and elemental analysis. The solvent-free target material ECPs-1 exhibited good thermal stability, sensitivity to mechanical stimuli, and excellent explosive properties. Furthermore, it had good potential for laser ignition and comparable detonation power to LA. The simple preparation method and inexpensive starting materials enriched the research on primary explosives.

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JO - Langmuir

JF - Langmuir

IS - 26

ER -

Preparation of High-Energy ECPs by Retaining the Coordination Ability of Carbohydrazide Groups

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