Phosphine-catalyzed rauhut-currier domino reaction: A facile strategy for the construction of highly functionalized cyclopentene

Chongchong Hu; Zhishuai Geng; Jianze Ma; You Huang; Ruyu Chen

doi:10.1002/asia.201200308

Phosphine-catalyzed rauhut-currier domino reaction: A facile strategy for the construction of highly functionalized cyclopentene

Chongchong Hu, Zhishuai Geng, Jianze Ma, You Huang^*, Ruyu Chen

^*Corresponding author for this work

Nankai University

Research output: Contribution to journal › Article › peer-review

34 Citations (Scopus)

Abstract

New strategy: A novel phosphine-catalyzed domino reaction of activated conjugated dienes and electron-deficient olefins was developed. In this reaction, intermolecular Rauhut-Currier reaction was successfully incorporated in a domino process, and a variety of highly functionalized cyclopentenes were obtained in good yields and diastereoselectivities. Two new C-C bonds were formed together with a quaternary carbon center.

Original language	English
Pages (from-to)	2032-2035
Number of pages	4
Journal	Chemistry - An Asian Journal
Volume	7
Issue number	9
DOIs	https://doi.org/10.1002/asia.201200308
Publication status	Published - Sept 2012
Externally published	Yes

Keywords

conjugated dienes
cycloaddition
domino reactions
phosphanes

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10.1002/asia.201200308

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abstract = "New strategy: A novel phosphine-catalyzed domino reaction of activated conjugated dienes and electron-deficient olefins was developed. In this reaction, intermolecular Rauhut-Currier reaction was successfully incorporated in a domino process, and a variety of highly functionalized cyclopentenes were obtained in good yields and diastereoselectivities. Two new C-C bonds were formed together with a quaternary carbon center.",

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AU - Huang, You

AU - Chen, Ruyu

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AB - New strategy: A novel phosphine-catalyzed domino reaction of activated conjugated dienes and electron-deficient olefins was developed. In this reaction, intermolecular Rauhut-Currier reaction was successfully incorporated in a domino process, and a variety of highly functionalized cyclopentenes were obtained in good yields and diastereoselectivities. Two new C-C bonds were formed together with a quaternary carbon center.

KW - conjugated dienes

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KW - phosphanes

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Phosphine-catalyzed rauhut-currier domino reaction: A facile strategy for the construction of highly functionalized cyclopentene

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Keywords

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