Phosphine-catalyzed rauhut-currier domino reaction: A facile strategy for the construction of highly functionalized cyclopentene

Chongchong Hu; Zhishuai Geng; Jianze Ma; You Huang; Ruyu Chen

doi:10.1002/asia.201200308

Phosphine-catalyzed rauhut-currier domino reaction: A facile strategy for the construction of highly functionalized cyclopentene

Chongchong Hu, Zhishuai Geng, Jianze Ma, You Huang^*, Ruyu Chen

^*此作品的通讯作者

Nankai University

科研成果: 期刊稿件 › 文章 › 同行评审

34 引用（Scopus）

摘要

New strategy: A novel phosphine-catalyzed domino reaction of activated conjugated dienes and electron-deficient olefins was developed. In this reaction, intermolecular Rauhut-Currier reaction was successfully incorporated in a domino process, and a variety of highly functionalized cyclopentenes were obtained in good yields and diastereoselectivities. Two new C-C bonds were formed together with a quaternary carbon center.

源语言	英语
页（从-至）	2032-2035
页数	4
期刊	Chemistry - An Asian Journal
卷	7
期	9
DOI	https://doi.org/10.1002/asia.201200308
出版状态	已出版 - 9月 2012
已对外发布	是

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abstract = "New strategy: A novel phosphine-catalyzed domino reaction of activated conjugated dienes and electron-deficient olefins was developed. In this reaction, intermolecular Rauhut-Currier reaction was successfully incorporated in a domino process, and a variety of highly functionalized cyclopentenes were obtained in good yields and diastereoselectivities. Two new C-C bonds were formed together with a quaternary carbon center.",

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author = "Chongchong Hu and Zhishuai Geng and Jianze Ma and You Huang and Ruyu Chen",

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AU - Geng, Zhishuai

AU - Ma, Jianze

AU - Huang, You

AU - Chen, Ruyu

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N2 - New strategy: A novel phosphine-catalyzed domino reaction of activated conjugated dienes and electron-deficient olefins was developed. In this reaction, intermolecular Rauhut-Currier reaction was successfully incorporated in a domino process, and a variety of highly functionalized cyclopentenes were obtained in good yields and diastereoselectivities. Two new C-C bonds were formed together with a quaternary carbon center.

AB - New strategy: A novel phosphine-catalyzed domino reaction of activated conjugated dienes and electron-deficient olefins was developed. In this reaction, intermolecular Rauhut-Currier reaction was successfully incorporated in a domino process, and a variety of highly functionalized cyclopentenes were obtained in good yields and diastereoselectivities. Two new C-C bonds were formed together with a quaternary carbon center.

KW - conjugated dienes

KW - cycloaddition

KW - domino reactions

KW - phosphanes

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Phosphine-catalyzed rauhut-currier domino reaction: A facile strategy for the construction of highly functionalized cyclopentene

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