Phosphate-induced fluorescence of a tetraphenylethene-substituted tripodal tris(urea) receptor

Jie Zhao; Dong Yang; Yanxia Zhao; Liping Cao; Zhibin Zhang; Xiao Juan Yang; Biao Wu

doi:10.1039/c6dt00672h

Phosphate-induced fluorescence of a tetraphenylethene-substituted tripodal tris(urea) receptor

Jie Zhao, Dong Yang, Yanxia Zhao, Liping Cao, Zhibin Zhang, Xiao Juan Yang^*, Biao Wu

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

A tetraphenylethene (TPE)-decorated tripodal tris(urea) ligand L was synthesized, which shows large emission enhancement when binding to an orthophosphate anion (PO₄^3-), but exhibits only weak or no fluorescence with other anions. The anion-binding and fluorescence properties were studied by X-ray crystal structure, NMR and fluorescence spectroscopy, and by DFT computations and the results demonstrate that the different fluorescence performance may be determined by the anion-binding modes (i.e., full- or half-encapsulation).

Original language	English
Pages (from-to)	7360-7365
Number of pages	6
Journal	Dalton Transactions
Volume	45
Issue number	17
DOIs	https://doi.org/10.1039/c6dt00672h
Publication status	Published - 7 May 2016
Externally published	Yes

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title = "Phosphate-induced fluorescence of a tetraphenylethene-substituted tripodal tris(urea) receptor",

abstract = "A tetraphenylethene (TPE)-decorated tripodal tris(urea) ligand L was synthesized, which shows large emission enhancement when binding to an orthophosphate anion (PO43-), but exhibits only weak or no fluorescence with other anions. The anion-binding and fluorescence properties were studied by X-ray crystal structure, NMR and fluorescence spectroscopy, and by DFT computations and the results demonstrate that the different fluorescence performance may be determined by the anion-binding modes (i.e., full- or half-encapsulation).",

author = "Jie Zhao and Dong Yang and Yanxia Zhao and Liping Cao and Zhibin Zhang and Yang, {Xiao Juan} and Biao Wu",

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T1 - Phosphate-induced fluorescence of a tetraphenylethene-substituted tripodal tris(urea) receptor

AU - Zhao, Jie

AU - Yang, Dong

AU - Zhao, Yanxia

AU - Cao, Liping

AU - Zhang, Zhibin

AU - Yang, Xiao Juan

AU - Wu, Biao

PY - 2016/5/7

Y1 - 2016/5/7

N2 - A tetraphenylethene (TPE)-decorated tripodal tris(urea) ligand L was synthesized, which shows large emission enhancement when binding to an orthophosphate anion (PO43-), but exhibits only weak or no fluorescence with other anions. The anion-binding and fluorescence properties were studied by X-ray crystal structure, NMR and fluorescence spectroscopy, and by DFT computations and the results demonstrate that the different fluorescence performance may be determined by the anion-binding modes (i.e., full- or half-encapsulation).

AB - A tetraphenylethene (TPE)-decorated tripodal tris(urea) ligand L was synthesized, which shows large emission enhancement when binding to an orthophosphate anion (PO43-), but exhibits only weak or no fluorescence with other anions. The anion-binding and fluorescence properties were studied by X-ray crystal structure, NMR and fluorescence spectroscopy, and by DFT computations and the results demonstrate that the different fluorescence performance may be determined by the anion-binding modes (i.e., full- or half-encapsulation).

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U2 - 10.1039/c6dt00672h

DO - 10.1039/c6dt00672h

M3 - Article

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VL - 45

SP - 7360

EP - 7365

JO - Dalton Transactions

JF - Dalton Transactions

IS - 17

ER -

Phosphate-induced fluorescence of a tetraphenylethene-substituted tripodal tris(urea) receptor

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