[Pb(en)0.5][B5O8(OH)]: A New Bilayered Organic–Inorganic Hybrid Lead Borate Built by B5O8(OH) Cluster Units

Lan Ma; Huan He; Bai Feng Yang; Qiang Zhang; Guo Yu Yang

doi:10.1007/s10876-015-0840-7

[Pb(en)_0.5][B₅O₈(OH)]: A New Bilayered Organic–Inorganic Hybrid Lead Borate Built by B₅O₈(OH) Cluster Units

Lan Ma, Huan He, Bai Feng Yang, Qiang Zhang^*, Guo Yu Yang

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

A new layered organic–inorganic hybrid lead borate [Pb(en)_0.5][B₅O₈(OH)] (1, en = ethylenediamine), has been hydro(solvo)thermally synthesized and characterized by single-crystal X-ray diffraction, powder X-ray diffraction, FT-IR spectroscopy and thermogravimetric analysis, respectively. Compound 1 crystallizes in triclinic system space group P-1 (No. 2), a = 6.6537(6) Å, b = 6.7157(6) Å, c = 10.6911(9) Å, α = 99.015(7)°, β = 93.657(7)°, γ = 118.915(9)°, V = 407.59(6) Å³, Z = 2. The structure consists of two infinite borate layers constructed from [B₅O₈(OH)]²⁻ cluster building units, then two such layers are further connected by the linear [Pb₂(en)]⁴⁺ complex linkers to form the novel bilayer structure.

Original language	English
Pages (from-to)	1495-1502
Number of pages	8
Journal	Journal of Cluster Science
Volume	26
Issue number	5
DOIs	https://doi.org/10.1007/s10876-015-0840-7
Publication status	Published - 24 Sept 2015

Keywords

Crystal structure
Hydrothermal synthesis
Lead
Lead borate
Oxo boron cluster

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10.1007/s10876-015-0840-7

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Ma, L., He, H., Yang, B. F., Zhang, Q., & Yang, G. Y. (2015). [Pb(en)_0.5][B₅O₈(OH)]: A New Bilayered Organic–Inorganic Hybrid Lead Borate Built by B₅O₈(OH) Cluster Units. Journal of Cluster Science, 26(5), 1495-1502. https://doi.org/10.1007/s10876-015-0840-7

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title = "[Pb(en)0.5][B5O8(OH)]: A New Bilayered Organic–Inorganic Hybrid Lead Borate Built by B5O8(OH) Cluster Units",

abstract = "A new layered organic–inorganic hybrid lead borate [Pb(en)0.5][B5O8(OH)] (1, en = ethylenediamine), has been hydro(solvo)thermally synthesized and characterized by single-crystal X-ray diffraction, powder X-ray diffraction, FT-IR spectroscopy and thermogravimetric analysis, respectively. Compound 1 crystallizes in triclinic system space group P-1 (No. 2), a = 6.6537(6) {\AA}, b = 6.7157(6) {\AA}, c = 10.6911(9) {\AA}, α = 99.015(7)°, β = 93.657(7)°, γ = 118.915(9)°, V = 407.59(6) {\AA}3, Z = 2. The structure consists of two infinite borate layers constructed from [B5O8(OH)]2− cluster building units, then two such layers are further connected by the linear [Pb2(en)]4+ complex linkers to form the novel bilayer structure.",

keywords = "Crystal structure, Hydrothermal synthesis, Lead, Lead borate, Oxo boron cluster",

author = "Lan Ma and Huan He and Yang, {Bai Feng} and Qiang Zhang and Yang, {Guo Yu}",

note = "Publisher Copyright: {\textcopyright} 2015, Springer Science+Business Media New York.",

year = "2015",

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doi = "10.1007/s10876-015-0840-7",

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AU - Ma, Lan

AU - He, Huan

AU - Yang, Bai Feng

AU - Zhang, Qiang

AU - Yang, Guo Yu

PY - 2015/9/24

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N2 - A new layered organic–inorganic hybrid lead borate [Pb(en)0.5][B5O8(OH)] (1, en = ethylenediamine), has been hydro(solvo)thermally synthesized and characterized by single-crystal X-ray diffraction, powder X-ray diffraction, FT-IR spectroscopy and thermogravimetric analysis, respectively. Compound 1 crystallizes in triclinic system space group P-1 (No. 2), a = 6.6537(6) Å, b = 6.7157(6) Å, c = 10.6911(9) Å, α = 99.015(7)°, β = 93.657(7)°, γ = 118.915(9)°, V = 407.59(6) Å3, Z = 2. The structure consists of two infinite borate layers constructed from [B5O8(OH)]2− cluster building units, then two such layers are further connected by the linear [Pb2(en)]4+ complex linkers to form the novel bilayer structure.

AB - A new layered organic–inorganic hybrid lead borate [Pb(en)0.5][B5O8(OH)] (1, en = ethylenediamine), has been hydro(solvo)thermally synthesized and characterized by single-crystal X-ray diffraction, powder X-ray diffraction, FT-IR spectroscopy and thermogravimetric analysis, respectively. Compound 1 crystallizes in triclinic system space group P-1 (No. 2), a = 6.6537(6) Å, b = 6.7157(6) Å, c = 10.6911(9) Å, α = 99.015(7)°, β = 93.657(7)°, γ = 118.915(9)°, V = 407.59(6) Å3, Z = 2. The structure consists of two infinite borate layers constructed from [B5O8(OH)]2− cluster building units, then two such layers are further connected by the linear [Pb2(en)]4+ complex linkers to form the novel bilayer structure.

KW - Crystal structure

KW - Hydrothermal synthesis

KW - Lead

KW - Lead borate

KW - Oxo boron cluster

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[Pb(en)_0.5][B₅O₈(OH)]: A New Bilayered Organic–Inorganic Hybrid Lead Borate Built by B₅O₈(OH) Cluster Units

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