Abstract
Allylamine compounds are one of the important compounds in organic synthetic chemistry and pharmaceutical chemistry, the synthetic methods of which are concerned. Using aroyloxycarbamates as start material, which was prepared in situ by cheap and easy-available carboxylic acid and hydroxylamine, allylamine compounds were synthesized by decarboxylation in one step. The reaction conditions are mild and the substrate is generally applicable. Moreover, the reaction realized the synthesis of indole.
| Translated title of the contribution | 钯催化的芳酰氧基氨基甲酸酯的分子内脱羧烯丙基胺化反应 |
|---|---|
| Original language | English |
| Pages (from-to) | 3089-3096 |
| Number of pages | 8 |
| Journal | Chinese Journal of Organic Chemistry |
| Volume | 41 |
| Issue number | 8 |
| DOIs | |
| Publication status | Published - Aug 2021 |
Keywords
- Allylamine
- Allylic amination
- Aroyloxycarbamate
- Decarboxylation
- Palladium-catalysis