One- and two-dimensional coordination assemblies of a novel redox-active bipyridinium dimer ligand with magnetic oxalate complexes

Yan Qiong Sun; Jie Zhang; Guo Yu Yang

doi:10.1039/b305560d

One- and two-dimensional coordination assemblies of a novel redox-active bipyridinium dimer ligand with magnetic oxalate complexes

Yan Qiong Sun, Jie Zhang^*, Guo Yu Yang

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

The synthesis of a novel redox-active bipyridinium dimer ligand, 1,4-bis(4′-pyridyl-1′-pyridinio)phthalazine (Bpyph) dichloride and its magnetic coordination assemblies [(Bpyph)Cu^IIFe^II(C₂O₄)₃]·6.5H₂O (1) and [(Bpyph)Co^II₂(C₂O₄)₃]·5.5H₂O (2) are described. X-Ray single-crystal diffraction studies confirm that compound 1 is built from [CuFe(C₂O₄)₃]²⁻ units bridged sequentially by Bpyph cations to form polymeric chains with Δ and Λ enantiomers in [Fe(C₂O₄)₃]⁴⁻. Compound 2 consists of honeycomb layers of the cobalt oxalate complex [Co₂(C₂O₄)₃]²⁻ interleaved by Bpyph cations. The magnetic susceptibility data show antiferromagnetic interaction in both compounds with Weiss constants −2.38 K for 1 and −38 K for 2.

Original language	English
Pages (from-to)	3634-3638
Number of pages	5
Journal	Journal of the Chemical Society. Dalton Transactions
Volume	3
Issue number	18
DOIs	https://doi.org/10.1039/b305560d
Publication status	Published - 3 Sept 2003
Externally published	Yes

Keywords

Cobalt
Copper
Heterocycles
Iron
Magnetic properties

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10.1039/b305560d

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title = "One- and two-dimensional coordination assemblies of a novel redox-active bipyridinium dimer ligand with magnetic oxalate complexes",

abstract = "The synthesis of a novel redox-active bipyridinium dimer ligand, 1,4-bis(4′-pyridyl-1′-pyridinio)phthalazine (Bpyph) dichloride and its magnetic coordination assemblies [(Bpyph)CuIIFeII(C2O4)3]·6.5H2O (1) and [(Bpyph)CoII2(C2O4)3]·5.5H2O (2) are described. X-Ray single-crystal diffraction studies confirm that compound 1 is built from [CuFe(C2O4)3]2− units bridged sequentially by Bpyph cations to form polymeric chains with Δ and Λ enantiomers in [Fe(C2O4)3]4−. Compound 2 consists of honeycomb layers of the cobalt oxalate complex [Co2(C2O4)3]2− interleaved by Bpyph cations. The magnetic susceptibility data show antiferromagnetic interaction in both compounds with Weiss constants −2.38 K for 1 and −38 K for 2.",

keywords = "Cobalt, Copper, Heterocycles, Iron, Magnetic properties",

author = "Sun, {Yan Qiong} and Jie Zhang and Yang, {Guo Yu}",

year = "2003",

month = sep,

day = "3",

doi = "10.1039/b305560d",

language = "English",

volume = "3",

pages = "3634--3638",

journal = "Journal of the Chemical Society. Dalton Transactions",

issn = "1470-479X",

publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - One- and two-dimensional coordination assemblies of a novel redox-active bipyridinium dimer ligand with magnetic oxalate complexes

AU - Sun, Yan Qiong

AU - Zhang, Jie

AU - Yang, Guo Yu

PY - 2003/9/3

Y1 - 2003/9/3

N2 - The synthesis of a novel redox-active bipyridinium dimer ligand, 1,4-bis(4′-pyridyl-1′-pyridinio)phthalazine (Bpyph) dichloride and its magnetic coordination assemblies [(Bpyph)CuIIFeII(C2O4)3]·6.5H2O (1) and [(Bpyph)CoII2(C2O4)3]·5.5H2O (2) are described. X-Ray single-crystal diffraction studies confirm that compound 1 is built from [CuFe(C2O4)3]2− units bridged sequentially by Bpyph cations to form polymeric chains with Δ and Λ enantiomers in [Fe(C2O4)3]4−. Compound 2 consists of honeycomb layers of the cobalt oxalate complex [Co2(C2O4)3]2− interleaved by Bpyph cations. The magnetic susceptibility data show antiferromagnetic interaction in both compounds with Weiss constants −2.38 K for 1 and −38 K for 2.

AB - The synthesis of a novel redox-active bipyridinium dimer ligand, 1,4-bis(4′-pyridyl-1′-pyridinio)phthalazine (Bpyph) dichloride and its magnetic coordination assemblies [(Bpyph)CuIIFeII(C2O4)3]·6.5H2O (1) and [(Bpyph)CoII2(C2O4)3]·5.5H2O (2) are described. X-Ray single-crystal diffraction studies confirm that compound 1 is built from [CuFe(C2O4)3]2− units bridged sequentially by Bpyph cations to form polymeric chains with Δ and Λ enantiomers in [Fe(C2O4)3]4−. Compound 2 consists of honeycomb layers of the cobalt oxalate complex [Co2(C2O4)3]2− interleaved by Bpyph cations. The magnetic susceptibility data show antiferromagnetic interaction in both compounds with Weiss constants −2.38 K for 1 and −38 K for 2.

KW - Cobalt

KW - Copper

KW - Heterocycles

KW - Iron

KW - Magnetic properties

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U2 - 10.1039/b305560d

DO - 10.1039/b305560d

M3 - Article

AN - SCOPUS:0141887298

SN - 1470-479X

VL - 3

SP - 3634

EP - 3638

JO - Journal of the Chemical Society. Dalton Transactions

JF - Journal of the Chemical Society. Dalton Transactions

IS - 18

ER -

One- and two-dimensional coordination assemblies of a novel redox-active bipyridinium dimer ligand with magnetic oxalate complexes

Abstract

Keywords

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