(NH4)2Na3(V3 W3O19).12H2O

Yan Xu, Ji Qing Xu*, Guo Yu Yang, Tie Gang Wang, Yan Xing, Yong Hua Lin, Heng Qing Jia

*Corresponding author for this work

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Abstract

(NH4)2Na3(V3W3O 19). 12H2O, diammonium trisodium nonadecaoxo(tritungsto)trivanadate dodecahydrate, is a mixed V/W salt in which each site has an approximately equal population of V and W atoms. The centrosymmetric polyanion consists of six (V/W)O6 edge-sharing distorted octahedra and has a well established structure. Each of the three Na+ cations is surrounded by six water molecules in a distorted octahedron. The (V/W) - O distances are between 1.644 (14) and 2.2885 (10)Å.

Original languageEnglish
Pages (from-to)563-565
Number of pages3
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume54
Issue number5
DOIs
Publication statusPublished - 15 May 1998
Externally publishedYes

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Xu, Y., Xu, J. Q., Yang, G. Y., Wang, T. G., Xing, Y., Lin, Y. H., & Jia, H. Q. (1998). (NH4)2Na3(V3 W3O19).12H2O. Acta Crystallographica Section C: Crystal Structure Communications, 54(5), 563-565. https://doi.org/10.1107/S0108270197016417