[{Na(7-nitro-5-sulfonate-naphthalene-1,4-dicarboxy-acid (H 2O2)2}·H2O]n: A water-soluble 2D layer polymeric complex with microporous molecular channels

Rui Feng Wu; Tong Lai Zhang; Xiao Jing Qiao; Jian Guo Zhang; Li Yang; Shao Zong Wang

doi:10.1002/zaac.200600338

[{Na(7-nitro-5-sulfonate-naphthalene-1,4-dicarboxy-acid (H ₂O₂)₂}·H₂O]_n: A water-soluble 2D layer polymeric complex with microporous molecular channels

Rui Feng Wu, Tong Lai Zhang^*, Xiao Jing Qiao, Jian Guo Zhang, Li Yang, Shao Zong Wang

^*Corresponding author for this work

School of Mechatronical Engineering

Research output: Contribution to journal › Article › peer-review

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Abstract

The X-ray crystallographic studies are reported for a water-soluble sodium complex of organic acid, {[Na(NSNDC)(H₂O)₂]·H ₂O}_n, (NSNDC = 7-Nitro-5-sulfonate-napthalene-1,4- dicarboxy-acid). It contains layers of vertically oriented NNSDC-anions sandwiching cations and water molecules. The rows of anions are linked in a direction by sodium ions and along b by hydrogen bonding, which have microporous channels (9.410 X 3.210 Å²) along the crystallographic b-axis. Considering the Na coordination environments, π-π stacking interaction between aryl ring and hydrogen bonds, the title compound represents a stably 2D infinitely extended structure.

Original language	English
Pages (from-to)	533-535
Number of pages	3
Journal	Zeitschrift fur Anorganische und Allgemeine Chemie
Volume	633
Issue number	4
DOIs	https://doi.org/10.1002/zaac.200600338
Publication status	Published - 2007

Keywords

7-Nitro-5-sulfonate-napthalene-1,4-dicarboxy acid
Coordination polymer
Crystal structure

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10.1002/zaac.200600338

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@article{13a200af6a284a2b9a326f7bc90ae9dd,

title = "[{Na(7-nitro-5-sulfonate-naphthalene-1,4-dicarboxy-acid (H 2O2)2}·H2O]n: A water-soluble 2D layer polymeric complex with microporous molecular channels",

abstract = "The X-ray crystallographic studies are reported for a water-soluble sodium complex of organic acid, {[Na(NSNDC)(H2O)2]·H 2O}n, (NSNDC = 7-Nitro-5-sulfonate-napthalene-1,4- dicarboxy-acid). It contains layers of vertically oriented NNSDC-anions sandwiching cations and water molecules. The rows of anions are linked in a direction by sodium ions and along b by hydrogen bonding, which have microporous channels (9.410 X 3.210 {\AA}2) along the crystallographic b-axis. Considering the Na coordination environments, π-π stacking interaction between aryl ring and hydrogen bonds, the title compound represents a stably 2D infinitely extended structure.",

keywords = "7-Nitro-5-sulfonate-napthalene-1,4-dicarboxy acid, Coordination polymer, Crystal structure",

author = "Wu, {Rui Feng} and Zhang, {Tong Lai} and Qiao, {Xiao Jing} and Zhang, {Jian Guo} and Li Yang and Wang, {Shao Zong}",

year = "2007",

doi = "10.1002/zaac.200600338",

language = "English",

volume = "633",

pages = "533--535",

journal = "Zeitschrift fur Anorganische und Allgemeine Chemie",

issn = "0044-2313",

publisher = "Wiley-VCH Verlag",

number = "4",

}

TY - JOUR

T1 - [{Na(7-nitro-5-sulfonate-naphthalene-1,4-dicarboxy-acid (H 2O2)2}·H2O]n

T2 - A water-soluble 2D layer polymeric complex with microporous molecular channels

AU - Wu, Rui Feng

AU - Zhang, Tong Lai

AU - Qiao, Xiao Jing

AU - Zhang, Jian Guo

AU - Yang, Li

AU - Wang, Shao Zong

PY - 2007

Y1 - 2007

N2 - The X-ray crystallographic studies are reported for a water-soluble sodium complex of organic acid, {[Na(NSNDC)(H2O)2]·H 2O}n, (NSNDC = 7-Nitro-5-sulfonate-napthalene-1,4- dicarboxy-acid). It contains layers of vertically oriented NNSDC-anions sandwiching cations and water molecules. The rows of anions are linked in a direction by sodium ions and along b by hydrogen bonding, which have microporous channels (9.410 X 3.210 Å2) along the crystallographic b-axis. Considering the Na coordination environments, π-π stacking interaction between aryl ring and hydrogen bonds, the title compound represents a stably 2D infinitely extended structure.

AB - The X-ray crystallographic studies are reported for a water-soluble sodium complex of organic acid, {[Na(NSNDC)(H2O)2]·H 2O}n, (NSNDC = 7-Nitro-5-sulfonate-napthalene-1,4- dicarboxy-acid). It contains layers of vertically oriented NNSDC-anions sandwiching cations and water molecules. The rows of anions are linked in a direction by sodium ions and along b by hydrogen bonding, which have microporous channels (9.410 X 3.210 Å2) along the crystallographic b-axis. Considering the Na coordination environments, π-π stacking interaction between aryl ring and hydrogen bonds, the title compound represents a stably 2D infinitely extended structure.

KW - 7-Nitro-5-sulfonate-napthalene-1,4-dicarboxy acid

KW - Coordination polymer

KW - Crystal structure

UR - http://www.scopus.com/inward/record.url?scp=33947581404&partnerID=8YFLogxK

U2 - 10.1002/zaac.200600338

DO - 10.1002/zaac.200600338

M3 - Article

AN - SCOPUS:33947581404

SN - 0044-2313

VL - 633

SP - 533

EP - 535

JO - Zeitschrift fur Anorganische und Allgemeine Chemie

JF - Zeitschrift fur Anorganische und Allgemeine Chemie

IS - 4

ER -

[{Na(7-nitro-5-sulfonate-naphthalene-1,4-dicarboxy-acid (H ₂O₂)₂}·H₂O]_n: A water-soluble 2D layer polymeric complex with microporous molecular channels

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